Syntheses and Electrochemical and EPR Studies of Porphyrins Functionalized with Bulky Aromatic Amine Donors

Syntheses and Electrochemical and EPR Studies of Porphyrins Functionalized with Bulky Aromatic Amine Donors

A series of nickel(II) porphyrins bearing one or two bulky nitrogen donors at the <i>meso</i> positions were prepared by using Ullmann methodology or more classical Buchwald–Hartwig amination reactions to create the new C-N bonds. For several new compounds, single crystals were obtained,...

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Bibliographic Details
Main Authors: Mary-Ambre Carvalho, Khalissa Merahi, Julien Haumesser, Ana Mafalda Vaz Martins Pereira, Nathalie Parizel, Jean Weiss, Maylis Orio, Vincent Maurel, Laurent Ruhlmann, Sylvie Choua, Romain Ruppert
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Molecules
Subjects:
porphyrinoids
phenothiazine
radical cation
EPR spectroscopy
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HYSCORE
Online Access:https://www.mdpi.com/1420-3049/28/11/4405

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