Mathematical Modelling of Ultrasound-Assisted Extraction Kinetics of Bioactive Compounds from Artichoke By-Products
Valorization of an artichoke by-product, rich in bioactive compounds, by ultrasound-assisted extraction, is proposed. The extraction yield curves of total phenolic content (TPC) and chlorogenic acid content (CAC) in 20% ethanol (<i>v/v</i>) with agitation (100 rpm) and ultrasound (200 an...
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| Format: | Article |
| Language: | English |
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MDPI AG
2021-04-01
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| Series: | Foods |
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| Online Access: | https://www.mdpi.com/2304-8158/10/5/931 |
| _version_ | 1797536515732013056 |
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| author | Cristina Reche Carmen Rosselló Mónica M. Umaña Valeria Eim Susana Simal |
| author_facet | Cristina Reche Carmen Rosselló Mónica M. Umaña Valeria Eim Susana Simal |
| author_sort | Cristina Reche |
| collection | DOAJ |
| description | Valorization of an artichoke by-product, rich in bioactive compounds, by ultrasound-assisted extraction, is proposed. The extraction yield curves of total phenolic content (TPC) and chlorogenic acid content (CAC) in 20% ethanol (<i>v/v</i>) with agitation (100 rpm) and ultrasound (200 and 335 W/L) were determined at 25, 40, and 60 °C. A mathematical model considering simultaneous diffusion and convection is proposed to simulate the extraction curves and to quantify both temperature and ultrasound power density effects in terms of the model parameters variation. The effective diffusion coefficient exhibited temperature dependence (72% increase for TPC from 25 °C to 60 °C), whereas the external mass transfer coefficient and the equilibrium extraction yield depended on both temperature (72% and 90% increases for TPC from 25 to 60 °C) and ultrasound power density (26 and 51% increases for TPC from 0 (agitation) to 335 W/L). The model allowed the accurate curves simulation, the average mean relative error being 5.3 ± 2.6%. Thus, the need of considering two resistances in series to satisfactorily simulate the extraction yield curves could be related to the diffusion of the bioactive compound from inside the vegetable cells toward the intercellular volume and from there, to the liquid phase. |
| first_indexed | 2024-03-10T12:01:49Z |
| format | Article |
| id | doaj.art-5f830e641f1c4018a0594106f497610b |
| institution | Directory Open Access Journal |
| issn | 2304-8158 |
| language | English |
| last_indexed | 2024-03-10T12:01:49Z |
| publishDate | 2021-04-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Foods |
| spelling | doaj.art-5f830e641f1c4018a0594106f497610b2023-11-21T16:53:59ZengMDPI AGFoods2304-81582021-04-0110593110.3390/foods10050931Mathematical Modelling of Ultrasound-Assisted Extraction Kinetics of Bioactive Compounds from Artichoke By-ProductsCristina Reche0Carmen Rosselló1Mónica M. Umaña2Valeria Eim3Susana Simal4Department of Chemistry, University of the Balearic Islands, Ctra. Valldemossa km 7.5, 07122 Palma de Mallorca, SpainDepartment of Chemistry, University of the Balearic Islands, Ctra. Valldemossa km 7.5, 07122 Palma de Mallorca, SpainDepartment of Chemistry, University of the Balearic Islands, Ctra. Valldemossa km 7.5, 07122 Palma de Mallorca, SpainDepartment of Chemistry, University of the Balearic Islands, Ctra. Valldemossa km 7.5, 07122 Palma de Mallorca, SpainDepartment of Chemistry, University of the Balearic Islands, Ctra. Valldemossa km 7.5, 07122 Palma de Mallorca, SpainValorization of an artichoke by-product, rich in bioactive compounds, by ultrasound-assisted extraction, is proposed. The extraction yield curves of total phenolic content (TPC) and chlorogenic acid content (CAC) in 20% ethanol (<i>v/v</i>) with agitation (100 rpm) and ultrasound (200 and 335 W/L) were determined at 25, 40, and 60 °C. A mathematical model considering simultaneous diffusion and convection is proposed to simulate the extraction curves and to quantify both temperature and ultrasound power density effects in terms of the model parameters variation. The effective diffusion coefficient exhibited temperature dependence (72% increase for TPC from 25 °C to 60 °C), whereas the external mass transfer coefficient and the equilibrium extraction yield depended on both temperature (72% and 90% increases for TPC from 25 to 60 °C) and ultrasound power density (26 and 51% increases for TPC from 0 (agitation) to 335 W/L). The model allowed the accurate curves simulation, the average mean relative error being 5.3 ± 2.6%. Thus, the need of considering two resistances in series to satisfactorily simulate the extraction yield curves could be related to the diffusion of the bioactive compound from inside the vegetable cells toward the intercellular volume and from there, to the liquid phase.https://www.mdpi.com/2304-8158/10/5/931artichokeby-productsultrasound-assisted extractionphenolic compoundschlorogenic aciddiffusion model |
| spellingShingle | Cristina Reche Carmen Rosselló Mónica M. Umaña Valeria Eim Susana Simal Mathematical Modelling of Ultrasound-Assisted Extraction Kinetics of Bioactive Compounds from Artichoke By-Products Foods artichoke by-products ultrasound-assisted extraction phenolic compounds chlorogenic acid diffusion model |
| title | Mathematical Modelling of Ultrasound-Assisted Extraction Kinetics of Bioactive Compounds from Artichoke By-Products |
| title_full | Mathematical Modelling of Ultrasound-Assisted Extraction Kinetics of Bioactive Compounds from Artichoke By-Products |
| title_fullStr | Mathematical Modelling of Ultrasound-Assisted Extraction Kinetics of Bioactive Compounds from Artichoke By-Products |
| title_full_unstemmed | Mathematical Modelling of Ultrasound-Assisted Extraction Kinetics of Bioactive Compounds from Artichoke By-Products |
| title_short | Mathematical Modelling of Ultrasound-Assisted Extraction Kinetics of Bioactive Compounds from Artichoke By-Products |
| title_sort | mathematical modelling of ultrasound assisted extraction kinetics of bioactive compounds from artichoke by products |
| topic | artichoke by-products ultrasound-assisted extraction phenolic compounds chlorogenic acid diffusion model |
| url | https://www.mdpi.com/2304-8158/10/5/931 |
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