19-[(E)-4-Chlorobenzylidene]-16-(4-chlorophenyl)-2-hydroxy-1,11-diazahexacyclo[15.3.1.02,10.03,8.010,17.011,15]henicosa-3(8),4,6-triene-9,18-dione
In the title compound, C32H26Cl2N2O3, the piperidone ring adopts a chair conformation and the proline and pyrrolidine rings adopt envelope conformations. The indane ring system is essentially planar with an r.m.s. deviation of 0.011 Å for the non-H atoms. The dihedral angl...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810018611 |
| _version_ | 1818906180708204544 |
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| author | Raju Suresh Kumar Hasnah Osman Aisyah Saad Abdul Rahim Madhukar Hemamalini Hoong-Kun Fun |
| author_facet | Raju Suresh Kumar Hasnah Osman Aisyah Saad Abdul Rahim Madhukar Hemamalini Hoong-Kun Fun |
| author_sort | Raju Suresh Kumar |
| collection | DOAJ |
| description | In the title compound, C32H26Cl2N2O3, the piperidone ring adopts a chair conformation and the proline and pyrrolidine rings adopt envelope conformations. The indane ring system is essentially planar with an r.m.s. deviation of 0.011 Å for the non-H atoms. The dihedral angle between the two chloro-substituted benzene rings is 63.69 (10)°. Intramolecular C—H...O and N—H...O hydrogen bonds may influence the molecular conformation. In the crystal structure, molecules are connected into layers by weak intermolecular C—H...O hydrogen bonds. |
| first_indexed | 2024-12-19T21:35:08Z |
| format | Article |
| id | doaj.art-5faa1d618600400a9eee446b5288678a |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T21:35:08Z |
| publishDate | 2010-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-5faa1d618600400a9eee446b5288678a2022-12-21T20:04:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-06-01666o1444o144510.1107/S160053681001861119-[(E)-4-Chlorobenzylidene]-16-(4-chlorophenyl)-2-hydroxy-1,11-diazahexacyclo[15.3.1.02,10.03,8.010,17.011,15]henicosa-3(8),4,6-triene-9,18-dioneRaju Suresh KumarHasnah OsmanAisyah Saad Abdul RahimMadhukar HemamaliniHoong-Kun FunIn the title compound, C32H26Cl2N2O3, the piperidone ring adopts a chair conformation and the proline and pyrrolidine rings adopt envelope conformations. The indane ring system is essentially planar with an r.m.s. deviation of 0.011 Å for the non-H atoms. The dihedral angle between the two chloro-substituted benzene rings is 63.69 (10)°. Intramolecular C—H...O and N—H...O hydrogen bonds may influence the molecular conformation. In the crystal structure, molecules are connected into layers by weak intermolecular C—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536810018611 |
| spellingShingle | Raju Suresh Kumar Hasnah Osman Aisyah Saad Abdul Rahim Madhukar Hemamalini Hoong-Kun Fun 19-[(E)-4-Chlorobenzylidene]-16-(4-chlorophenyl)-2-hydroxy-1,11-diazahexacyclo[15.3.1.02,10.03,8.010,17.011,15]henicosa-3(8),4,6-triene-9,18-dione Acta Crystallographica Section E |
| title | 19-[(E)-4-Chlorobenzylidene]-16-(4-chlorophenyl)-2-hydroxy-1,11-diazahexacyclo[15.3.1.02,10.03,8.010,17.011,15]henicosa-3(8),4,6-triene-9,18-dione |
| title_full | 19-[(E)-4-Chlorobenzylidene]-16-(4-chlorophenyl)-2-hydroxy-1,11-diazahexacyclo[15.3.1.02,10.03,8.010,17.011,15]henicosa-3(8),4,6-triene-9,18-dione |
| title_fullStr | 19-[(E)-4-Chlorobenzylidene]-16-(4-chlorophenyl)-2-hydroxy-1,11-diazahexacyclo[15.3.1.02,10.03,8.010,17.011,15]henicosa-3(8),4,6-triene-9,18-dione |
| title_full_unstemmed | 19-[(E)-4-Chlorobenzylidene]-16-(4-chlorophenyl)-2-hydroxy-1,11-diazahexacyclo[15.3.1.02,10.03,8.010,17.011,15]henicosa-3(8),4,6-triene-9,18-dione |
| title_short | 19-[(E)-4-Chlorobenzylidene]-16-(4-chlorophenyl)-2-hydroxy-1,11-diazahexacyclo[15.3.1.02,10.03,8.010,17.011,15]henicosa-3(8),4,6-triene-9,18-dione |
| title_sort | 19 e 4 chlorobenzylidene 16 4 chlorophenyl 2 hydroxy 1 11 diazahexacyclo 15 3 1 02 10 03 8 010 17 011 15 henicosa 3 8 4 6 triene 9 18 dione |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810018611 |
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