Study of Dislocations in the Minicrystallized Regions in Multicrystalline Silicon Grown by the Directional Solidification Method

Directionally solidified multicrystalline silicon (mc-Si)-based solar cells have dominated the global photovoltaic market in recent years. The photovoltaic performance of mc-Si solar cells is strongly influenced by their crystalline defects. The occurrence of minicrystallization results in much smal...

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Main Authors: Nan Chen, Shenyu Qiu, Jianhua Huang, Guoping Du, Guihua Liu
Format: Article
Language:English
Published: MDPI AG 2016-10-01
Series:Crystals
Subjects:
Online Access:http://www.mdpi.com/2073-4352/6/10/130
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author Nan Chen
Shenyu Qiu
Jianhua Huang
Guoping Du
Guihua Liu
author_facet Nan Chen
Shenyu Qiu
Jianhua Huang
Guoping Du
Guihua Liu
author_sort Nan Chen
collection DOAJ
description Directionally solidified multicrystalline silicon (mc-Si)-based solar cells have dominated the global photovoltaic market in recent years. The photovoltaic performance of mc-Si solar cells is strongly influenced by their crystalline defects. The occurrence of minicrystallization results in much smaller grain size and, therefore, a larger number of grain boundaries in mc-Si ingots. Dislocations in the minicrystallized regions have been rarely investigated in the literature. In this work, optical microscopy was used to investigate dislocations in the mincrystallized regions in mc-Si ingots grown by the directional solidification method. The distribution of dislocations was found to be highly inhomogeneous from one grain to another in the mincrystallized regions. High inhomogeneity of dislocation distribution was also observed in individual grains. Serious shunting behavior was observed in the mc-Si solar cells containing minicrystallized regions, which strongly deteriorates their photovoltaic properties. The shunting was found to be highly localized to the minicrystallized regions.
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spelling doaj.art-5fde9de62745476ab302e38d67362d932022-12-22T04:00:46ZengMDPI AGCrystals2073-43522016-10-0161013010.3390/cryst6100130cryst6100130Study of Dislocations in the Minicrystallized Regions in Multicrystalline Silicon Grown by the Directional Solidification MethodNan Chen0Shenyu Qiu1Jianhua Huang2Guoping Du3Guihua Liu4School of Materials Science and Engineering, Nanchang University, Nanchang 330031, ChinaDepartment of Science, Nanchang Institute of Technology, Nanchang 330099, ChinaSchool of Materials Science and Engineering, Nanchang University, Nanchang 330031, ChinaSchool of Materials Science and Engineering, Nanchang University, Nanchang 330031, ChinaSchool of Materials Science and Engineering, Nanchang University, Nanchang 330031, ChinaDirectionally solidified multicrystalline silicon (mc-Si)-based solar cells have dominated the global photovoltaic market in recent years. The photovoltaic performance of mc-Si solar cells is strongly influenced by their crystalline defects. The occurrence of minicrystallization results in much smaller grain size and, therefore, a larger number of grain boundaries in mc-Si ingots. Dislocations in the minicrystallized regions have been rarely investigated in the literature. In this work, optical microscopy was used to investigate dislocations in the mincrystallized regions in mc-Si ingots grown by the directional solidification method. The distribution of dislocations was found to be highly inhomogeneous from one grain to another in the mincrystallized regions. High inhomogeneity of dislocation distribution was also observed in individual grains. Serious shunting behavior was observed in the mc-Si solar cells containing minicrystallized regions, which strongly deteriorates their photovoltaic properties. The shunting was found to be highly localized to the minicrystallized regions.http://www.mdpi.com/2073-4352/6/10/130crystal dislocationmulticrystalline silicondirectional solidificationminicrystallizationsolar cell
spellingShingle Nan Chen
Shenyu Qiu
Jianhua Huang
Guoping Du
Guihua Liu
Study of Dislocations in the Minicrystallized Regions in Multicrystalline Silicon Grown by the Directional Solidification Method
Crystals
crystal dislocation
multicrystalline silicon
directional solidification
minicrystallization
solar cell
title Study of Dislocations in the Minicrystallized Regions in Multicrystalline Silicon Grown by the Directional Solidification Method
title_full Study of Dislocations in the Minicrystallized Regions in Multicrystalline Silicon Grown by the Directional Solidification Method
title_fullStr Study of Dislocations in the Minicrystallized Regions in Multicrystalline Silicon Grown by the Directional Solidification Method
title_full_unstemmed Study of Dislocations in the Minicrystallized Regions in Multicrystalline Silicon Grown by the Directional Solidification Method
title_short Study of Dislocations in the Minicrystallized Regions in Multicrystalline Silicon Grown by the Directional Solidification Method
title_sort study of dislocations in the minicrystallized regions in multicrystalline silicon grown by the directional solidification method
topic crystal dislocation
multicrystalline silicon
directional solidification
minicrystallization
solar cell
url http://www.mdpi.com/2073-4352/6/10/130
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