Investigation the Kinetics of CO2 Hydrate Formation in the Water System + CTAB + TBAF + ZnO
In this study, the kinetics of gas hydrate formation in the presence of tetra-n-butyl ammonium fluoride (TBAF) and cetyl trimethyl ammonium bromide surface active ingredient (CTAB) with zinc nano oxide (ZnO) are investigated and the most important kinetic parameters of hydrate formation such as thei...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Iranian Chemical Science and Technologies Association
2020-06-01
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| Series: | International Journal of New Chemistry |
| Subjects: | |
| Online Access: | http://www.ijnc.ir/article_38621.html |
| _version_ | 1818532291838738432 |
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| author | Esmaeil Mousavi Alireza Bozorgian |
| author_facet | Esmaeil Mousavi Alireza Bozorgian |
| author_sort | Esmaeil Mousavi |
| collection | DOAJ |
| description | In this study, the kinetics of gas hydrate formation in the presence of tetra-n-butyl ammonium fluoride (TBAF) and cetyl trimethyl ammonium bromide surface active ingredient (CTAB) with zinc nano oxide (ZnO) are investigated and the most important kinetic parameters of hydrate formation such as their induction time and storage capacity were measured. The kinetic experiments were carried out in a constant volume temperature method in a high pressure reactor. The storage capacity of carbon dioxide hydrate in water in the presence of ZnO and surfactants at different temperatures, pressures and concentrations of TBAF and CTAB additives was calculated and measured using time induction measurements. The results show that with increasing pressure and decreasing temperature, the storage capacity of CO2 in hydrate increases. Finally, statistical analysis of the parameters affecting the induction time of hydrate formation showed that zinc oxide can reduce the induction time of hydrate formation compared to other additives. |
| first_indexed | 2024-12-11T17:43:35Z |
| format | Article |
| id | doaj.art-5ffda9f54c634fef8edfa53662e523e7 |
| institution | Directory Open Access Journal |
| issn | 2645-7237 2383-188X |
| language | English |
| last_indexed | 2024-12-11T17:43:35Z |
| publishDate | 2020-06-01 |
| publisher | Iranian Chemical Science and Technologies Association |
| record_format | Article |
| series | International Journal of New Chemistry |
| spelling | doaj.art-5ffda9f54c634fef8edfa53662e523e72022-12-22T00:56:26ZengIranian Chemical Science and Technologies AssociationInternational Journal of New Chemistry2645-72372383-188X2020-06-017319521910.22034/ijnc.2020.121743.109638621Investigation the Kinetics of CO2 Hydrate Formation in the Water System + CTAB + TBAF + ZnOEsmaeil Mousavi 0Alireza Bozorgian1Department of Chemical Engineering, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran Department of Chemical Engineering, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran In this study, the kinetics of gas hydrate formation in the presence of tetra-n-butyl ammonium fluoride (TBAF) and cetyl trimethyl ammonium bromide surface active ingredient (CTAB) with zinc nano oxide (ZnO) are investigated and the most important kinetic parameters of hydrate formation such as their induction time and storage capacity were measured. The kinetic experiments were carried out in a constant volume temperature method in a high pressure reactor. The storage capacity of carbon dioxide hydrate in water in the presence of ZnO and surfactants at different temperatures, pressures and concentrations of TBAF and CTAB additives was calculated and measured using time induction measurements. The results show that with increasing pressure and decreasing temperature, the storage capacity of CO2 in hydrate increases. Finally, statistical analysis of the parameters affecting the induction time of hydrate formation showed that zinc oxide can reduce the induction time of hydrate formation compared to other additives.http://www.ijnc.ir/article_38621.htmlbutyl ammonium fluoride ; zinc nano oxide ; storage ; hydrate |
| spellingShingle | Esmaeil Mousavi Alireza Bozorgian Investigation the Kinetics of CO2 Hydrate Formation in the Water System + CTAB + TBAF + ZnO International Journal of New Chemistry butyl ammonium fluoride ; zinc nano oxide ; storage ; hydrate |
| title | Investigation the Kinetics of CO2 Hydrate Formation in the Water System + CTAB + TBAF + ZnO |
| title_full | Investigation the Kinetics of CO2 Hydrate Formation in the Water System + CTAB + TBAF + ZnO |
| title_fullStr | Investigation the Kinetics of CO2 Hydrate Formation in the Water System + CTAB + TBAF + ZnO |
| title_full_unstemmed | Investigation the Kinetics of CO2 Hydrate Formation in the Water System + CTAB + TBAF + ZnO |
| title_short | Investigation the Kinetics of CO2 Hydrate Formation in the Water System + CTAB + TBAF + ZnO |
| title_sort | investigation the kinetics of co2 hydrate formation in the water system ctab tbaf zno |
| topic | butyl ammonium fluoride ; zinc nano oxide ; storage ; hydrate |
| url | http://www.ijnc.ir/article_38621.html |
| work_keys_str_mv | AT esmaeilmousavi investigationthekineticsofco2hydrateformationinthewatersystemctabtbafzno AT alirezabozorgian investigationthekineticsofco2hydrateformationinthewatersystemctabtbafzno |