Changes of refractive indices in ternary mixtures containing chlorobenzene + n-hexane + (n-heptane or n-octane) at 298.15 K
The refractive indices of ternary mixtures of chlorobenzene + n-hexane + (n-heptane or n-octane) have been measured at 298.15 K and at atmospheric pressure over the whole composition diagram. Parameters of polynomial equations which represent the composition dependence of physical and derived proper...
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2004-06-01
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| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.shd.org.yu/HtDocs/SHD/Vol69/No6/V69-No6-06.pdf |
| _version_ | 1828470317954105344 |
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| author | M. IGLESIAS G. MARINO V. MORENO M. HERVELLO A. TOURINO |
| author_facet | M. IGLESIAS G. MARINO V. MORENO M. HERVELLO A. TOURINO |
| author_sort | M. IGLESIAS |
| collection | DOAJ |
| description | The refractive indices of ternary mixtures of chlorobenzene + n-hexane + (n-heptane or n-octane) have been measured at 298.15 K and at atmospheric pressure over the whole composition diagram. Parameters of polynomial equations which represent the composition dependence of physical and derived properties are gathered. The experimental refractive indices and the ternary derived properties are compared with the data obtained using several predictive semi-empirical models. The use of the SoaveRedlichKwong (SRK) and the PengRobinson (PR) cubic equations of state with the Van der Waals one-fluid mixing rule, which incorporate different combining rules to predict refractive indices on mixing, are tested against the measured results, good agrement being obtained. |
| first_indexed | 2024-12-11T04:52:23Z |
| format | Article |
| id | doaj.art-600da3eede334324bf3e8765e618718b |
| institution | Directory Open Access Journal |
| issn | 0352-5139 |
| language | English |
| last_indexed | 2024-12-11T04:52:23Z |
| publishDate | 2004-06-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-600da3eede334324bf3e8765e618718b2022-12-22T01:20:22ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392004-06-01696461475Changes of refractive indices in ternary mixtures containing chlorobenzene + n-hexane + (n-heptane or n-octane) at 298.15 KM. IGLESIASG. MARINOV. MORENOM. HERVELLOA. TOURINOThe refractive indices of ternary mixtures of chlorobenzene + n-hexane + (n-heptane or n-octane) have been measured at 298.15 K and at atmospheric pressure over the whole composition diagram. Parameters of polynomial equations which represent the composition dependence of physical and derived properties are gathered. The experimental refractive indices and the ternary derived properties are compared with the data obtained using several predictive semi-empirical models. The use of the SoaveRedlichKwong (SRK) and the PengRobinson (PR) cubic equations of state with the Van der Waals one-fluid mixing rule, which incorporate different combining rules to predict refractive indices on mixing, are tested against the measured results, good agrement being obtained.http://www.shd.org.yu/HtDocs/SHD/Vol69/No6/V69-No6-06.pdfrefractive indexchlorobenzenealkanescubic equation of state |
| spellingShingle | M. IGLESIAS G. MARINO V. MORENO M. HERVELLO A. TOURINO Changes of refractive indices in ternary mixtures containing chlorobenzene + n-hexane + (n-heptane or n-octane) at 298.15 K Journal of the Serbian Chemical Society refractive index chlorobenzene alkanes cubic equation of state |
| title | Changes of refractive indices in ternary mixtures containing chlorobenzene + n-hexane + (n-heptane or n-octane) at 298.15 K |
| title_full | Changes of refractive indices in ternary mixtures containing chlorobenzene + n-hexane + (n-heptane or n-octane) at 298.15 K |
| title_fullStr | Changes of refractive indices in ternary mixtures containing chlorobenzene + n-hexane + (n-heptane or n-octane) at 298.15 K |
| title_full_unstemmed | Changes of refractive indices in ternary mixtures containing chlorobenzene + n-hexane + (n-heptane or n-octane) at 298.15 K |
| title_short | Changes of refractive indices in ternary mixtures containing chlorobenzene + n-hexane + (n-heptane or n-octane) at 298.15 K |
| title_sort | changes of refractive indices in ternary mixtures containing chlorobenzene n hexane n heptane or n octane at 298 15 k |
| topic | refractive index chlorobenzene alkanes cubic equation of state |
| url | http://www.shd.org.yu/HtDocs/SHD/Vol69/No6/V69-No6-06.pdf |
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