Theoretical validation of ground-based microwave ozone observations

Ground-based microwave measurements of the diurnal and seasonal variations of ozoneat 42±4.5 and 55±8 km are validated by comparing with results from a zero-dimensional photochemical model and a two-dimensional (2D) chemical/radiative/dynamical model, respectively. O<sub>3</sub> diur...

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Main Authors: P. Ricaud, G. Brasseur, J. Brillet, J. de La Noë, J.-P. Parisot, M. Pirre
Format: Article
Language:English
Published: Copernicus Publications 1994-06-01
Series:Annales Geophysicae
Online Access:https://www.ann-geophys.net/12/664/1994/angeo-12-664-1994.pdf
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author P. Ricaud
G. Brasseur
J. Brillet
J. de La Noë
J.-P. Parisot
M. Pirre
author_facet P. Ricaud
G. Brasseur
J. Brillet
J. de La Noë
J.-P. Parisot
M. Pirre
author_sort P. Ricaud
collection DOAJ
description Ground-based microwave measurements of the diurnal and seasonal variations of ozoneat 42±4.5 and 55±8 km are validated by comparing with results from a zero-dimensional photochemical model and a two-dimensional (2D) chemical/radiative/dynamical model, respectively. O<sub>3</sub> diurnal amplitudes measured in Bordeaux are shown to be in agreement with theory to within 5%. For the seasonal analysis of O<sub>3</sub> variation, at 42±4.5 km, the 2D model underestimates the yearly averaged ozone concentration compared with the measurements. A double maximum oscillation (~3.5%) is measured in Bordeaux with an extended maximum in September and a maximum in February, whilst the 2D model predicts only a single large maximum (17%) in August and a pronounced minimum in January. Evidence suggests that dynamical transport causes the winter O<sub>3</sub> maximum by propagation of planetary waves, phenomena which are not explicitly reproduced by the 2D model. At 55±8 km, the modeled yearly averaged O<sub>3</sub> concentration is in very good agreement with the measured yearly average. A strong annual oscillation is both measured and modeled with differences in the amplitude shown to be exclusively linked to temperature fields.
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spelling doaj.art-60201b1b381b46c5ad6c1e1aeaaa6e9e2022-12-21T18:47:59ZengCopernicus PublicationsAnnales Geophysicae0992-76891432-05761994-06-011266467310.1007/s00585-994-0664-5Theoretical validation of ground-based microwave ozone observationsP. RicaudG. BrasseurJ. BrilletJ. de La NoëJ.-P. ParisotM. PirreGround-based microwave measurements of the diurnal and seasonal variations of ozoneat 42±4.5 and 55±8 km are validated by comparing with results from a zero-dimensional photochemical model and a two-dimensional (2D) chemical/radiative/dynamical model, respectively. O<sub>3</sub> diurnal amplitudes measured in Bordeaux are shown to be in agreement with theory to within 5%. For the seasonal analysis of O<sub>3</sub> variation, at 42±4.5 km, the 2D model underestimates the yearly averaged ozone concentration compared with the measurements. A double maximum oscillation (~3.5%) is measured in Bordeaux with an extended maximum in September and a maximum in February, whilst the 2D model predicts only a single large maximum (17%) in August and a pronounced minimum in January. Evidence suggests that dynamical transport causes the winter O<sub>3</sub> maximum by propagation of planetary waves, phenomena which are not explicitly reproduced by the 2D model. At 55±8 km, the modeled yearly averaged O<sub>3</sub> concentration is in very good agreement with the measured yearly average. A strong annual oscillation is both measured and modeled with differences in the amplitude shown to be exclusively linked to temperature fields.https://www.ann-geophys.net/12/664/1994/angeo-12-664-1994.pdf
spellingShingle P. Ricaud
G. Brasseur
J. Brillet
J. de La Noë
J.-P. Parisot
M. Pirre
Theoretical validation of ground-based microwave ozone observations
Annales Geophysicae
title Theoretical validation of ground-based microwave ozone observations
title_full Theoretical validation of ground-based microwave ozone observations
title_fullStr Theoretical validation of ground-based microwave ozone observations
title_full_unstemmed Theoretical validation of ground-based microwave ozone observations
title_short Theoretical validation of ground-based microwave ozone observations
title_sort theoretical validation of ground based microwave ozone observations
url https://www.ann-geophys.net/12/664/1994/angeo-12-664-1994.pdf
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