Aquatrichlorido(1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane-κN4)copper(II) monohydrate

The asymmetric unit of the title compound, [CuCl3(C8H14N3)(H2O)]·H2O, comprises a neutral complex and a molecule of free water. The complex contains coordinated CuII ions, with Cu—Cl distances ranging from 2.3471 (8) to 2.4011 (8) ...

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Bibliographic Details
Main Authors: Qinqin Zhou, Yi Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2012-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812017205
Description
Summary:The asymmetric unit of the title compound, [CuCl3(C8H14N3)(H2O)]·H2O, comprises a neutral complex and a molecule of free water. The complex contains coordinated CuII ions, with Cu—Cl distances ranging from 2.3471 (8) to 2.4011 (8) Å, and with Cu—N and Cu—O distances of 2.0775 (19) and 2.0048 (18) Å, respectively. The resulting coordination polyhedron is a trigonal bipyramid with the Cl atoms in the equatorial plane. In the crystal, O—H...Cl and O—H...O hydrogen bonds link the molecules into a three-dimensional structure.
ISSN:1600-5368