Aquatrichlorido(1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane-κN4)copper(II) monohydrate
The asymmetric unit of the title compound, [CuCl3(C8H14N3)(H2O)]·H2O, comprises a neutral complex and a molecule of free water. The complex contains coordinated CuII ions, with Cu—Cl distances ranging from 2.3471 (8) to 2.4011 (8) ...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812017205 |
| _version_ | 1830342580149157888 |
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| author | Qinqin Zhou Yi Zhang |
| author_facet | Qinqin Zhou Yi Zhang |
| author_sort | Qinqin Zhou |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [CuCl3(C8H14N3)(H2O)]·H2O, comprises a neutral complex and a molecule of free water. The complex contains coordinated CuII ions, with Cu—Cl distances ranging from 2.3471 (8) to 2.4011 (8) Å, and with Cu—N and Cu—O distances of 2.0775 (19) and 2.0048 (18) Å, respectively. The resulting coordination polyhedron is a trigonal bipyramid with the Cl atoms in the equatorial plane. In the crystal, O—H...Cl and O—H...O hydrogen bonds link the molecules into a three-dimensional structure. |
| first_indexed | 2024-12-19T21:53:10Z |
| format | Article |
| id | doaj.art-60214eb3e45d4b78985bbe0b78b932b4 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T21:53:10Z |
| publishDate | 2012-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-60214eb3e45d4b78985bbe0b78b932b42022-12-21T20:04:21ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685m674m67410.1107/S1600536812017205Aquatrichlorido(1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane-κN4)copper(II) monohydrateQinqin ZhouYi ZhangThe asymmetric unit of the title compound, [CuCl3(C8H14N3)(H2O)]·H2O, comprises a neutral complex and a molecule of free water. The complex contains coordinated CuII ions, with Cu—Cl distances ranging from 2.3471 (8) to 2.4011 (8) Å, and with Cu—N and Cu—O distances of 2.0775 (19) and 2.0048 (18) Å, respectively. The resulting coordination polyhedron is a trigonal bipyramid with the Cl atoms in the equatorial plane. In the crystal, O—H...Cl and O—H...O hydrogen bonds link the molecules into a three-dimensional structure.http://scripts.iucr.org/cgi-bin/paper?S1600536812017205 |
| spellingShingle | Qinqin Zhou Yi Zhang Aquatrichlorido(1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane-κN4)copper(II) monohydrate Acta Crystallographica Section E |
| title | Aquatrichlorido(1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane-κN4)copper(II) monohydrate |
| title_full | Aquatrichlorido(1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane-κN4)copper(II) monohydrate |
| title_fullStr | Aquatrichlorido(1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane-κN4)copper(II) monohydrate |
| title_full_unstemmed | Aquatrichlorido(1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane-κN4)copper(II) monohydrate |
| title_short | Aquatrichlorido(1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane-κN4)copper(II) monohydrate |
| title_sort | aquatrichlorido 1 cyanomethyl 4 aza 1 azoniabicyclo 2 2 2 octane amp 954 n4 copper ii monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812017205 |
| work_keys_str_mv | AT qinqinzhou aquatrichlorido1cyanomethyl4aza1azoniabicyclo222octaneamp954n4copperiimonohydrate AT yizhang aquatrichlorido1cyanomethyl4aza1azoniabicyclo222octaneamp954n4copperiimonohydrate |