Excited-state tris(pentafluorophenyl)borane as a strong single-electron oxidant: Photophysical properties and catalysis

Excited-state tris(pentafluorophenyl)borane as a strong single-electron oxidant: Photophysical properties and catalysis

The photophysical properties and photocatalysis of tris(pentafluorophenyl)borane [B(C6F5)3], known as a strong Lewis acid, were revealed. The excited-state B(C6F5)3 exerts single-electron oxidation capability with an oxidation potential (Ered* = 2.02 V vs SCE) close to those of electronically unbias...

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Bibliographic Details
Main Authors:	Yoshitaka Aramaki, Yuki Uchida, Ryo Ishikawa, Takashi Ooi
Format:	Article
Language:	English
Published:	Elsevier 2023-12-01
Series:	Journal of Photochemistry and Photobiology
Subjects:	Photooxidant Borane Radical cation Transient absorption spectroscopy Carbon-carbon bond formation
Online Access:	http://www.sciencedirect.com/science/article/pii/S2666469023000477

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