trans-Carbonylchloridobis[diphenyl(4-vinylphenyl)phosphane-κP]rhodium(I)
In the title compound, trans-[RhCl(C20H17P)2(CO)], the RhI atom is situated on a center of symmetry, resulting in a statistical 1:1 disorder of the chloride [Rh—Cl = 2.383 (2) Å] and carbonyl [Rh—C = 1.752 (7)&...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812013669 |
| _version_ | 1819350341868584960 |
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| author | Reinout Meijboom Hezron Ogutu Leo Kirsten |
| author_facet | Reinout Meijboom Hezron Ogutu Leo Kirsten |
| author_sort | Reinout Meijboom |
| collection | DOAJ |
| description | In the title compound, trans-[RhCl(C20H17P)2(CO)], the RhI atom is situated on a center of symmetry, resulting in a statistical 1:1 disorder of the chloride [Rh—Cl = 2.383 (2) Å] and carbonyl [Rh—C = 1.752 (7) Å] ligands. The distorted trans square-planar environment is completed by two P atoms [Rh—P = 2.3251 (4) Å] from two diphenyl(4-vinylphenyl)phosphane ligands. The vinyl group is disordered over two sets of sites in a 0.668 (10):0.332 (10) ratio. The crystal packing exhibits weak C—H...Cl and C—H...O hydrogen bonds and π–π interactions between the phenyl rings of neighbouring molecules, with a centroid–centroid distance of 3.682 (2) Å. |
| first_indexed | 2024-12-24T19:14:53Z |
| format | Article |
| id | doaj.art-604bd53844034d009479c8b1498231a1 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T19:14:53Z |
| publishDate | 2012-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-604bd53844034d009479c8b1498231a12022-12-21T16:42:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685m545m54510.1107/S1600536812013669trans-Carbonylchloridobis[diphenyl(4-vinylphenyl)phosphane-κP]rhodium(I)Reinout MeijboomHezron OgutuLeo KirstenIn the title compound, trans-[RhCl(C20H17P)2(CO)], the RhI atom is situated on a center of symmetry, resulting in a statistical 1:1 disorder of the chloride [Rh—Cl = 2.383 (2) Å] and carbonyl [Rh—C = 1.752 (7) Å] ligands. The distorted trans square-planar environment is completed by two P atoms [Rh—P = 2.3251 (4) Å] from two diphenyl(4-vinylphenyl)phosphane ligands. The vinyl group is disordered over two sets of sites in a 0.668 (10):0.332 (10) ratio. The crystal packing exhibits weak C—H...Cl and C—H...O hydrogen bonds and π–π interactions between the phenyl rings of neighbouring molecules, with a centroid–centroid distance of 3.682 (2) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536812013669 |
| spellingShingle | Reinout Meijboom Hezron Ogutu Leo Kirsten trans-Carbonylchloridobis[diphenyl(4-vinylphenyl)phosphane-κP]rhodium(I) Acta Crystallographica Section E |
| title | trans-Carbonylchloridobis[diphenyl(4-vinylphenyl)phosphane-κP]rhodium(I) |
| title_full | trans-Carbonylchloridobis[diphenyl(4-vinylphenyl)phosphane-κP]rhodium(I) |
| title_fullStr | trans-Carbonylchloridobis[diphenyl(4-vinylphenyl)phosphane-κP]rhodium(I) |
| title_full_unstemmed | trans-Carbonylchloridobis[diphenyl(4-vinylphenyl)phosphane-κP]rhodium(I) |
| title_short | trans-Carbonylchloridobis[diphenyl(4-vinylphenyl)phosphane-κP]rhodium(I) |
| title_sort | trans carbonylchloridobis diphenyl 4 vinylphenyl phosphane amp 954 p rhodium i |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812013669 |
| work_keys_str_mv | AT reinoutmeijboom transcarbonylchloridobisdiphenyl4vinylphenylphosphaneamp954prhodiumi AT hezronogutu transcarbonylchloridobisdiphenyl4vinylphenylphosphaneamp954prhodiumi AT leokirsten transcarbonylchloridobisdiphenyl4vinylphenylphosphaneamp954prhodiumi |