Acid–hydrolysed furfural production from rice straw bio-waste: Process synthesis, simulation, and optimisation

Finding a way to efficiently utilize this bio-waste resource is a great challenge due to the depletion of traditional fossil fuels and the environmental impact associated to their use. Rice straw is considered as one of the main cereal straws. It is produced in many countries every year in substanti...

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Main Authors: Nourhan Sherif, Mamdouh Gadalla, Dina Kamel
Format: Article
Language:English
Published: Elsevier 2021-10-01
Series:South African Journal of Chemical Engineering
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1026918521000469
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author Nourhan Sherif
Mamdouh Gadalla
Dina Kamel
author_facet Nourhan Sherif
Mamdouh Gadalla
Dina Kamel
author_sort Nourhan Sherif
collection DOAJ
description Finding a way to efficiently utilize this bio-waste resource is a great challenge due to the depletion of traditional fossil fuels and the environmental impact associated to their use. Rice straw is considered as one of the main cereal straws. It is produced in many countries every year in substantial amounts and it has a high ash content and low protein content. Usually, rice straw is burned by farmers causing many adverse effects on the environment and public health. This research investigates the process synthesis of furfural production through the acid-hydrolysis of rice straws. Furfural is a strategic bio-renewable chemical and has gained attention due to its possibility to produce biofuels and bio chemicals. Aspen Plus® simulation package is employed for process simulation, sizing, and analysis. Results of simulations are validated against an experimental work. Optimization through manipulation of several parameters including acid concentration, reaction temperature, acid/rice straw ratio, catalyst concentration, and type of acid to maximize the furfural yield and reaction conversion. A complete flow sheet is synthesized and sensitivity analysis is studied to reach an optimum process concerning environment and economics. The amount of furfural obtained as a final product from the process represents a yield of 73% per 100 kg/hr of rice straw processed.
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spelling doaj.art-605026bed98e45b5af46ae90e626806a2022-12-21T19:29:43ZengElsevierSouth African Journal of Chemical Engineering1026-91852021-10-01383440Acid–hydrolysed furfural production from rice straw bio-waste: Process synthesis, simulation, and optimisationNourhan Sherif0Mamdouh Gadalla1Dina Kamel2The British University in Egypt, Department of Chemical Engineering, 11837, Cairo, EgyptThe British University in Egypt, Department of Chemical Engineering, 11837, Cairo, Egypt; Port Said University, Department of Chemical Engineering, 42526, Port Said, EgyptThe British University in Egypt, Department of Chemical Engineering, 11837, Cairo, Egypt; Corresponding author.Finding a way to efficiently utilize this bio-waste resource is a great challenge due to the depletion of traditional fossil fuels and the environmental impact associated to their use. Rice straw is considered as one of the main cereal straws. It is produced in many countries every year in substantial amounts and it has a high ash content and low protein content. Usually, rice straw is burned by farmers causing many adverse effects on the environment and public health. This research investigates the process synthesis of furfural production through the acid-hydrolysis of rice straws. Furfural is a strategic bio-renewable chemical and has gained attention due to its possibility to produce biofuels and bio chemicals. Aspen Plus® simulation package is employed for process simulation, sizing, and analysis. Results of simulations are validated against an experimental work. Optimization through manipulation of several parameters including acid concentration, reaction temperature, acid/rice straw ratio, catalyst concentration, and type of acid to maximize the furfural yield and reaction conversion. A complete flow sheet is synthesized and sensitivity analysis is studied to reach an optimum process concerning environment and economics. The amount of furfural obtained as a final product from the process represents a yield of 73% per 100 kg/hr of rice straw processed.http://www.sciencedirect.com/science/article/pii/S1026918521000469Acid hydrolysisBio-energyFuransLiquid-liquid extractionRice strawProcess simulation
spellingShingle Nourhan Sherif
Mamdouh Gadalla
Dina Kamel
Acid–hydrolysed furfural production from rice straw bio-waste: Process synthesis, simulation, and optimisation
South African Journal of Chemical Engineering
Acid hydrolysis
Bio-energy
Furans
Liquid-liquid extraction
Rice straw
Process simulation
title Acid–hydrolysed furfural production from rice straw bio-waste: Process synthesis, simulation, and optimisation
title_full Acid–hydrolysed furfural production from rice straw bio-waste: Process synthesis, simulation, and optimisation
title_fullStr Acid–hydrolysed furfural production from rice straw bio-waste: Process synthesis, simulation, and optimisation
title_full_unstemmed Acid–hydrolysed furfural production from rice straw bio-waste: Process synthesis, simulation, and optimisation
title_short Acid–hydrolysed furfural production from rice straw bio-waste: Process synthesis, simulation, and optimisation
title_sort acid hydrolysed furfural production from rice straw bio waste process synthesis simulation and optimisation
topic Acid hydrolysis
Bio-energy
Furans
Liquid-liquid extraction
Rice straw
Process simulation
url http://www.sciencedirect.com/science/article/pii/S1026918521000469
work_keys_str_mv AT nourhansherif acidhydrolysedfurfuralproductionfromricestrawbiowasteprocesssynthesissimulationandoptimisation
AT mamdouhgadalla acidhydrolysedfurfuralproductionfromricestrawbiowasteprocesssynthesissimulationandoptimisation
AT dinakamel acidhydrolysedfurfuralproductionfromricestrawbiowasteprocesssynthesissimulationandoptimisation