Pd-Catalyzed Intermolecular Dehydrogenative Heck Reactions of Five-Membered Heteroarenes
The Pd-mediated cross-coupling of (hetero)arenes with alkenes may be an effective method for the formation of a C–C bond from two C–H bonds. Discovered by Fujiwara and co-workers in 1967, this reaction led to a number of reports that we firstly highlighted in 2011 (review with references till June 2...
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MDPI AG
2020-05-01
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| Series: | Catalysts |
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| Online Access: | https://www.mdpi.com/2073-4344/10/5/571 |
| _version_ | 1797567564384043008 |
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| author | Jean Le Bras Jacques Muzart |
| author_facet | Jean Le Bras Jacques Muzart |
| author_sort | Jean Le Bras |
| collection | DOAJ |
| description | The Pd-mediated cross-coupling of (hetero)arenes with alkenes may be an effective method for the formation of a C–C bond from two C–H bonds. Discovered by Fujiwara and co-workers in 1967, this reaction led to a number of reports that we firstly highlighted in 2011 (review with references till June 2010) and for which, we retained the name “dehydrogenative Heck reaction”. The topic, especially the reactions of five-membered heteroarenes, has been the subject of intensive research over the last ten years. The present review is limited to these dehydrogenative Heck reactions published since 2010, underlining the progress of the procedures. |
| first_indexed | 2024-03-10T19:43:46Z |
| format | Article |
| id | doaj.art-606fa7f3f4df483ea02ac27380cecdd1 |
| institution | Directory Open Access Journal |
| issn | 2073-4344 |
| language | English |
| last_indexed | 2024-03-10T19:43:46Z |
| publishDate | 2020-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Catalysts |
| spelling | doaj.art-606fa7f3f4df483ea02ac27380cecdd12023-11-20T00:58:35ZengMDPI AGCatalysts2073-43442020-05-0110557110.3390/catal10050571Pd-Catalyzed Intermolecular Dehydrogenative Heck Reactions of Five-Membered HeteroarenesJean Le Bras0Jacques Muzart1Institut de Chimie Moléculaire de Reims, UMR 7312 CNRS—Université de Reims Champagne-Ardenne, BP 1039, CEDEX 2, 51687 Reims, FranceInstitut de Chimie Moléculaire de Reims, UMR 7312 CNRS—Université de Reims Champagne-Ardenne, BP 1039, CEDEX 2, 51687 Reims, FranceThe Pd-mediated cross-coupling of (hetero)arenes with alkenes may be an effective method for the formation of a C–C bond from two C–H bonds. Discovered by Fujiwara and co-workers in 1967, this reaction led to a number of reports that we firstly highlighted in 2011 (review with references till June 2010) and for which, we retained the name “dehydrogenative Heck reaction”. The topic, especially the reactions of five-membered heteroarenes, has been the subject of intensive research over the last ten years. The present review is limited to these dehydrogenative Heck reactions published since 2010, underlining the progress of the procedures.https://www.mdpi.com/2073-4344/10/5/571palladiumheteroarenesdehydrogenative cross-couplingsC–H activation |
| spellingShingle | Jean Le Bras Jacques Muzart Pd-Catalyzed Intermolecular Dehydrogenative Heck Reactions of Five-Membered Heteroarenes Catalysts palladium heteroarenes dehydrogenative cross-couplings C–H activation |
| title | Pd-Catalyzed Intermolecular Dehydrogenative Heck Reactions of Five-Membered Heteroarenes |
| title_full | Pd-Catalyzed Intermolecular Dehydrogenative Heck Reactions of Five-Membered Heteroarenes |
| title_fullStr | Pd-Catalyzed Intermolecular Dehydrogenative Heck Reactions of Five-Membered Heteroarenes |
| title_full_unstemmed | Pd-Catalyzed Intermolecular Dehydrogenative Heck Reactions of Five-Membered Heteroarenes |
| title_short | Pd-Catalyzed Intermolecular Dehydrogenative Heck Reactions of Five-Membered Heteroarenes |
| title_sort | pd catalyzed intermolecular dehydrogenative heck reactions of five membered heteroarenes |
| topic | palladium heteroarenes dehydrogenative cross-couplings C–H activation |
| url | https://www.mdpi.com/2073-4344/10/5/571 |
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