Recent Advances in the Preparation and Performance of Porous Titanium-Based Anode Materials for Sodium-Ion Batteries
Sodium-ion batteries (SIBs) are among the most cost-effective and environmentally benign electrical energy storage devices required to match the needs of commercialized stationary and automotive applications. Because of its excellent chemical characteristics, infinite abundance, and low cost, the SI...
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MDPI AG
2022-12-01
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| author | Athinarayanan Balasankar Sathya Elango Arthiya Subramaniyan Ramasundaram Paramasivam Sumathi Selvaraj Arokiyaraj Taehwan Oh Kanakaraj Aruchamy Ganesan Sriram Mahaveer D. Kurkuri |
| author_facet | Athinarayanan Balasankar Sathya Elango Arthiya Subramaniyan Ramasundaram Paramasivam Sumathi Selvaraj Arokiyaraj Taehwan Oh Kanakaraj Aruchamy Ganesan Sriram Mahaveer D. Kurkuri |
| author_sort | Athinarayanan Balasankar |
| collection | DOAJ |
| description | Sodium-ion batteries (SIBs) are among the most cost-effective and environmentally benign electrical energy storage devices required to match the needs of commercialized stationary and automotive applications. Because of its excellent chemical characteristics, infinite abundance, and low cost, the SIB is an excellent technology for grid energy storage compared with others. When used as anodes, titanium compounds based on the Ti<sup>4+</sup>/Ti<sup>3+</sup> redox couple have a potential of typically 0.5–1.0 V, which is far from the potential of dangerous sodium plating (0.0–0.1 V). This ensures the operational safety of large-scale SIBs. Low lattice strain, usually associated with Ti-based materials, is also helpful for the longevity of the cycling of SIBs. Numerous Ti-based anode materials are being developed for use in SIBs. In particular, due to adequate electrode–electrolyte interaction and rapid charge transportation, hierarchical porous (HP) Ti-based anode materials were reported as having high specific capacity, current density, and cycling stability. HPTi-based anode materials for SIBs have the potential to be used in automobiles and portable, flexible, and wearable electronic devices. This review addresses recent developments in HPTiO<sub>2</sub>-based SIBs and their preparation, properties, performance, and challenges. |
| first_indexed | 2024-03-09T16:53:45Z |
| format | Article |
| id | doaj.art-60841d7ecc174d179af22ca16f0c297f |
| institution | Directory Open Access Journal |
| issn | 1996-1073 |
| language | English |
| last_indexed | 2024-03-09T16:53:45Z |
| publishDate | 2022-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Energies |
| spelling | doaj.art-60841d7ecc174d179af22ca16f0c297f2023-11-24T14:37:59ZengMDPI AGEnergies1996-10732022-12-011524949510.3390/en15249495Recent Advances in the Preparation and Performance of Porous Titanium-Based Anode Materials for Sodium-Ion BatteriesAthinarayanan Balasankar0Sathya Elango Arthiya1Subramaniyan Ramasundaram2Paramasivam Sumathi3Selvaraj Arokiyaraj4Taehwan Oh5Kanakaraj Aruchamy6Ganesan Sriram7Mahaveer D. Kurkuri8Department of Physics, Gobi Arts & Science College, Gobichettipalayam, Erode 638 453, Tamilnadu, IndiaCentre for Nano Sciences & Technology, Madanjeet School of Green Energy Technologies, Pondicherry University (A Central University), Puducherry 605 014, IndiaSchool of Chemical Engineering, Yeungnam University, Gyeongsan 38541, Republic of KoreaDepartment of Chemistry, Gobi Arts & Science College, Gobichettipalayam, Erode 638 453, Tamilnadu, IndiaDepartment of Food Science & Biotechnology, Sejong University, Seoul 05006, Republic of KoreaSchool of Chemical Engineering, Yeungnam University, Gyeongsan 38541, Republic of KoreaSchool of Chemical Engineering, Yeungnam University, Gyeongsan 38541, Republic of KoreaSchool of Chemical Engineering, Yeungnam University, Gyeongsan 38541, Republic of KoreaCentre for Research in Functional Materials (CRFM), Jain Global Campus, JAIN University, Bengaluru 562112, Karnataka, IndiaSodium-ion batteries (SIBs) are among the most cost-effective and environmentally benign electrical energy storage devices required to match the needs of commercialized stationary and automotive applications. Because of its excellent chemical characteristics, infinite abundance, and low cost, the SIB is an excellent technology for grid energy storage compared with others. When used as anodes, titanium compounds based on the Ti<sup>4+</sup>/Ti<sup>3+</sup> redox couple have a potential of typically 0.5–1.0 V, which is far from the potential of dangerous sodium plating (0.0–0.1 V). This ensures the operational safety of large-scale SIBs. Low lattice strain, usually associated with Ti-based materials, is also helpful for the longevity of the cycling of SIBs. Numerous Ti-based anode materials are being developed for use in SIBs. In particular, due to adequate electrode–electrolyte interaction and rapid charge transportation, hierarchical porous (HP) Ti-based anode materials were reported as having high specific capacity, current density, and cycling stability. HPTi-based anode materials for SIBs have the potential to be used in automobiles and portable, flexible, and wearable electronic devices. This review addresses recent developments in HPTiO<sub>2</sub>-based SIBs and their preparation, properties, performance, and challenges.https://www.mdpi.com/1996-1073/15/24/9495sodium-ion batterieshierarchically porous TiO<sub>2</sub>titanium dioxideanode materialsTi nanomaterials |
| spellingShingle | Athinarayanan Balasankar Sathya Elango Arthiya Subramaniyan Ramasundaram Paramasivam Sumathi Selvaraj Arokiyaraj Taehwan Oh Kanakaraj Aruchamy Ganesan Sriram Mahaveer D. Kurkuri Recent Advances in the Preparation and Performance of Porous Titanium-Based Anode Materials for Sodium-Ion Batteries Energies sodium-ion batteries hierarchically porous TiO<sub>2</sub> titanium dioxide anode materials Ti nanomaterials |
| title | Recent Advances in the Preparation and Performance of Porous Titanium-Based Anode Materials for Sodium-Ion Batteries |
| title_full | Recent Advances in the Preparation and Performance of Porous Titanium-Based Anode Materials for Sodium-Ion Batteries |
| title_fullStr | Recent Advances in the Preparation and Performance of Porous Titanium-Based Anode Materials for Sodium-Ion Batteries |
| title_full_unstemmed | Recent Advances in the Preparation and Performance of Porous Titanium-Based Anode Materials for Sodium-Ion Batteries |
| title_short | Recent Advances in the Preparation and Performance of Porous Titanium-Based Anode Materials for Sodium-Ion Batteries |
| title_sort | recent advances in the preparation and performance of porous titanium based anode materials for sodium ion batteries |
| topic | sodium-ion batteries hierarchically porous TiO<sub>2</sub> titanium dioxide anode materials Ti nanomaterials |
| url | https://www.mdpi.com/1996-1073/15/24/9495 |
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