Tetra(phenylethynyl)tin Is a New Reagent for Solvent-Free Alkynylation of Imines
The first ZnCl<sub>2</sub>-catalyzed alkynylation of aldimines with tetra(phenylethynyl)tin was achieved under solvent-free conditions. The present methodology provides propargylamines in 38–62% yields.
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-12-01
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| Series: | Molbank |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1422-8599/2023/1/M1534 |
| _version_ | 1797609996866813952 |
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| author | Andrey S. Levashov Elena V. Dvirnaya Dzhamilay N. Konshina Valery V. Konshin |
| author_facet | Andrey S. Levashov Elena V. Dvirnaya Dzhamilay N. Konshina Valery V. Konshin |
| author_sort | Andrey S. Levashov |
| collection | DOAJ |
| description | The first ZnCl<sub>2</sub>-catalyzed alkynylation of aldimines with tetra(phenylethynyl)tin was achieved under solvent-free conditions. The present methodology provides propargylamines in 38–62% yields. |
| first_indexed | 2024-03-11T06:08:16Z |
| format | Article |
| id | doaj.art-60b510b568204b29afaca29756f4cea6 |
| institution | Directory Open Access Journal |
| issn | 1422-8599 |
| language | English |
| last_indexed | 2024-03-11T06:08:16Z |
| publishDate | 2022-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj.art-60b510b568204b29afaca29756f4cea62023-11-17T12:49:04ZengMDPI AGMolbank1422-85992022-12-0120231M153410.3390/M1534Tetra(phenylethynyl)tin Is a New Reagent for Solvent-Free Alkynylation of IminesAndrey S. Levashov0Elena V. Dvirnaya1Dzhamilay N. Konshina2Valery V. Konshin3Department of Chemistry and High Technology, Kuban State University, Stavropolskaya st 149, 350040 Krasnodar, RussiaDepartment of Chemistry and High Technology, Kuban State University, Stavropolskaya st 149, 350040 Krasnodar, RussiaDepartment of Chemistry and High Technology, Kuban State University, Stavropolskaya st 149, 350040 Krasnodar, RussiaDepartment of Chemistry and High Technology, Kuban State University, Stavropolskaya st 149, 350040 Krasnodar, RussiaThe first ZnCl<sub>2</sub>-catalyzed alkynylation of aldimines with tetra(phenylethynyl)tin was achieved under solvent-free conditions. The present methodology provides propargylamines in 38–62% yields.https://www.mdpi.com/1422-8599/2023/1/M1534tetraalkynyltinalkynylationLewis acidiminespropargylamines |
| spellingShingle | Andrey S. Levashov Elena V. Dvirnaya Dzhamilay N. Konshina Valery V. Konshin Tetra(phenylethynyl)tin Is a New Reagent for Solvent-Free Alkynylation of Imines Molbank tetraalkynyltin alkynylation Lewis acid imines propargylamines |
| title | Tetra(phenylethynyl)tin Is a New Reagent for Solvent-Free Alkynylation of Imines |
| title_full | Tetra(phenylethynyl)tin Is a New Reagent for Solvent-Free Alkynylation of Imines |
| title_fullStr | Tetra(phenylethynyl)tin Is a New Reagent for Solvent-Free Alkynylation of Imines |
| title_full_unstemmed | Tetra(phenylethynyl)tin Is a New Reagent for Solvent-Free Alkynylation of Imines |
| title_short | Tetra(phenylethynyl)tin Is a New Reagent for Solvent-Free Alkynylation of Imines |
| title_sort | tetra phenylethynyl tin is a new reagent for solvent free alkynylation of imines |
| topic | tetraalkynyltin alkynylation Lewis acid imines propargylamines |
| url | https://www.mdpi.com/1422-8599/2023/1/M1534 |
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