Cellular Polyolefin Composites as Piezoelectric Materials: Properties and Applications

Piezoelectric polymers characterized by flexibility are sought for applications in microelectronics, medicine, telecommunications, and everyday devices. The objective of this work was to obtain piezoelectric polymeric composites with a cellular structure and to evaluate their usefulness in practice....

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Main Authors: Ewa Klimiec, Halina Kaczmarek, Bogusław Królikowski, Grzegorz Kołaszczyński
Format: Article
Language:English
Published: MDPI AG 2020-11-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/12/11/2698
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author Ewa Klimiec
Halina Kaczmarek
Bogusław Królikowski
Grzegorz Kołaszczyński
author_facet Ewa Klimiec
Halina Kaczmarek
Bogusław Królikowski
Grzegorz Kołaszczyński
author_sort Ewa Klimiec
collection DOAJ
description Piezoelectric polymers characterized by flexibility are sought for applications in microelectronics, medicine, telecommunications, and everyday devices. The objective of this work was to obtain piezoelectric polymeric composites with a cellular structure and to evaluate their usefulness in practice. Composites based on polyolefins (isotactic-polypropylene and polyethylene) with the addition of aluminosilicate fillers were manufactured by extrusion, and then polarized in a constant electric field at 100 V/µm. The content of mineral fillers up to 10 wt% in the polymer matrix enhances its electric stability and mechanical strength. The value of the piezoelectric coefficient d<sub>33</sub> attained ~150 pC/N in the range of lower stresses and ~80 pC/N in the range of higher stresses, i.e., at ~120 kPa. The materials exhibited high durability in time, therefore, they can be used as transducers of mechanical energy of the human motion into electric energy. It was demonstrated that one shoe insert generates an energy of 1.1 mJ after a person walks for 300 s. The miniaturized integrated circuits based on polyolefin composites may be applied for the power supply of portable electronics. Due to their high sensitivity, they can be recommended for measuring the blood pulse.
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spelling doaj.art-60b698d76fdd4a4ea535a38607dd53392023-11-20T21:07:13ZengMDPI AGPolymers2073-43602020-11-011211269810.3390/polym12112698Cellular Polyolefin Composites as Piezoelectric Materials: Properties and ApplicationsEwa Klimiec0Halina Kaczmarek1Bogusław Królikowski2Grzegorz Kołaszczyński3Lukasiewicz Research Network—Institute of Microelectronics and Photonics, Zabłocie 39, 30-701 Kraków, PolandDepartment of Biomedical Chemistry and Polymers, Faculty of Chemistry, Nicolaus Copernicus University, Gagarina 7, 87-100 Toruń, PolandŁukasiewicz Research Network—Institute for Engineering of Polymer Materials and Dyes—Toruń Division, M. Skłodowskiej-Curie 55, 87-100 Toruń, PolandLukasiewicz Research Network—Institute of Microelectronics and Photonics, Zabłocie 39, 30-701 Kraków, PolandPiezoelectric polymers characterized by flexibility are sought for applications in microelectronics, medicine, telecommunications, and everyday devices. The objective of this work was to obtain piezoelectric polymeric composites with a cellular structure and to evaluate their usefulness in practice. Composites based on polyolefins (isotactic-polypropylene and polyethylene) with the addition of aluminosilicate fillers were manufactured by extrusion, and then polarized in a constant electric field at 100 V/µm. The content of mineral fillers up to 10 wt% in the polymer matrix enhances its electric stability and mechanical strength. The value of the piezoelectric coefficient d<sub>33</sub> attained ~150 pC/N in the range of lower stresses and ~80 pC/N in the range of higher stresses, i.e., at ~120 kPa. The materials exhibited high durability in time, therefore, they can be used as transducers of mechanical energy of the human motion into electric energy. It was demonstrated that one shoe insert generates an energy of 1.1 mJ after a person walks for 300 s. The miniaturized integrated circuits based on polyolefin composites may be applied for the power supply of portable electronics. Due to their high sensitivity, they can be recommended for measuring the blood pulse.https://www.mdpi.com/2073-4360/12/11/2698piezoelectric compositespolypropylenepolyethylenecellular structurepiezoelectric sensorsenergy harvesters
spellingShingle Ewa Klimiec
Halina Kaczmarek
Bogusław Królikowski
Grzegorz Kołaszczyński
Cellular Polyolefin Composites as Piezoelectric Materials: Properties and Applications
Polymers
piezoelectric composites
polypropylene
polyethylene
cellular structure
piezoelectric sensors
energy harvesters
title Cellular Polyolefin Composites as Piezoelectric Materials: Properties and Applications
title_full Cellular Polyolefin Composites as Piezoelectric Materials: Properties and Applications
title_fullStr Cellular Polyolefin Composites as Piezoelectric Materials: Properties and Applications
title_full_unstemmed Cellular Polyolefin Composites as Piezoelectric Materials: Properties and Applications
title_short Cellular Polyolefin Composites as Piezoelectric Materials: Properties and Applications
title_sort cellular polyolefin composites as piezoelectric materials properties and applications
topic piezoelectric composites
polypropylene
polyethylene
cellular structure
piezoelectric sensors
energy harvesters
url https://www.mdpi.com/2073-4360/12/11/2698
work_keys_str_mv AT ewaklimiec cellularpolyolefincompositesaspiezoelectricmaterialspropertiesandapplications
AT halinakaczmarek cellularpolyolefincompositesaspiezoelectricmaterialspropertiesandapplications
AT bogusławkrolikowski cellularpolyolefincompositesaspiezoelectricmaterialspropertiesandapplications
AT grzegorzkołaszczynski cellularpolyolefincompositesaspiezoelectricmaterialspropertiesandapplications