Static Adsorption, by Activated Carbons, of Vapour Mixtures Corresponding to Immiscible Liquids
It is shown that the static adsorption of benzene and water vapours by a typical industrial active carbon can be described by the model of independent co-adsorption proposed for compounds which are not miscible in the liquid state. The model assumes that the vapours are adsorbed according to their r...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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SAGE Publications
1999-10-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1177/026361749901700906 |
| _version_ | 1797280443229274112 |
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| author | D. Wintgens A. Lavanchy F. Stoeckli |
| author_facet | D. Wintgens A. Lavanchy F. Stoeckli |
| author_sort | D. Wintgens |
| collection | DOAJ |
| description | It is shown that the static adsorption of benzene and water vapours by a typical industrial active carbon can be described by the model of independent co-adsorption proposed for compounds which are not miscible in the liquid state. The model assumes that the vapours are adsorbed according to their respective DA isotherms, each component using the micropore volume left unoccupied by the other. A good agreement is found between the calculated and the experimental adsorption, but in the case of water the model must take into account the decrease of the characteristic energy E(H 2 O) with increasing co-adsorption of benzene. This behaviour is confirmed by earlier studies of water adsorption and of immersion calorimetry into water, following variable pre-adsorption of n-nonane. |
| first_indexed | 2024-03-07T16:41:17Z |
| format | Article |
| id | doaj.art-60bb2e1995b74622898965eb230a5315 |
| institution | Directory Open Access Journal |
| issn | 0263-6174 2048-4038 |
| language | English |
| last_indexed | 2024-03-07T16:41:17Z |
| publishDate | 1999-10-01 |
| publisher | SAGE Publications |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj.art-60bb2e1995b74622898965eb230a53152024-03-03T08:19:38ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40381999-10-011710.1177/026361749901700906Static Adsorption, by Activated Carbons, of Vapour Mixtures Corresponding to Immiscible LiquidsD. Wintgens0A. Lavanchy1F. Stoeckli2 Chemistry Department of the University, Avenue de Bellevaux 51, CH-2000 Neuchâtel, Switzerland NC-Laboratory, 3700 Spiez, Switzerland Chemistry Department of the University, Avenue de Bellevaux 51, CH-2000 Neuchâtel, SwitzerlandIt is shown that the static adsorption of benzene and water vapours by a typical industrial active carbon can be described by the model of independent co-adsorption proposed for compounds which are not miscible in the liquid state. The model assumes that the vapours are adsorbed according to their respective DA isotherms, each component using the micropore volume left unoccupied by the other. A good agreement is found between the calculated and the experimental adsorption, but in the case of water the model must take into account the decrease of the characteristic energy E(H 2 O) with increasing co-adsorption of benzene. This behaviour is confirmed by earlier studies of water adsorption and of immersion calorimetry into water, following variable pre-adsorption of n-nonane.https://doi.org/10.1177/026361749901700906 |
| spellingShingle | D. Wintgens A. Lavanchy F. Stoeckli Static Adsorption, by Activated Carbons, of Vapour Mixtures Corresponding to Immiscible Liquids Adsorption Science & Technology |
| title | Static Adsorption, by Activated Carbons, of Vapour Mixtures Corresponding to Immiscible Liquids |
| title_full | Static Adsorption, by Activated Carbons, of Vapour Mixtures Corresponding to Immiscible Liquids |
| title_fullStr | Static Adsorption, by Activated Carbons, of Vapour Mixtures Corresponding to Immiscible Liquids |
| title_full_unstemmed | Static Adsorption, by Activated Carbons, of Vapour Mixtures Corresponding to Immiscible Liquids |
| title_short | Static Adsorption, by Activated Carbons, of Vapour Mixtures Corresponding to Immiscible Liquids |
| title_sort | static adsorption by activated carbons of vapour mixtures corresponding to immiscible liquids |
| url | https://doi.org/10.1177/026361749901700906 |
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