Subsurface nickel boosts the low-temperature performance of a boron oxide overlayer in propane oxidative dehydrogenation

The working temperature of boron-based catalysts reduces their thermodynamic advantages in the oxidative dehydrogenation of propane (ODHP). Here the authors demonstrate encapsulated Ni nanoparticles as effective subsurface promoters to enhance the low temperature activity and selectivity of the boro...

Full description

Bibliographic Details
Main Authors: Xiaofeng Gao, Ling Zhu, Feng Yang, Lei Zhang, Wenhao Xu, Xian Zhou, Yongkang Huang, Houhong Song, Lili Lin, Xiaodong Wen, Ding Ma, Siyu Yao
Format: Article
Language:English
Published: Nature Portfolio 2023-03-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-023-37261-x
_version_ 1797864143755149312
author Xiaofeng Gao
Ling Zhu
Feng Yang
Lei Zhang
Wenhao Xu
Xian Zhou
Yongkang Huang
Houhong Song
Lili Lin
Xiaodong Wen
Ding Ma
Siyu Yao
author_facet Xiaofeng Gao
Ling Zhu
Feng Yang
Lei Zhang
Wenhao Xu
Xian Zhou
Yongkang Huang
Houhong Song
Lili Lin
Xiaodong Wen
Ding Ma
Siyu Yao
author_sort Xiaofeng Gao
collection DOAJ
description The working temperature of boron-based catalysts reduces their thermodynamic advantages in the oxidative dehydrogenation of propane (ODHP). Here the authors demonstrate encapsulated Ni nanoparticles as effective subsurface promoters to enhance the low temperature activity and selectivity of the boron oxide overlayer in ODHP.
first_indexed 2024-04-09T22:46:56Z
format Article
id doaj.art-60d579693bba484a869caf3e3a3e5069
institution Directory Open Access Journal
issn 2041-1723
language English
last_indexed 2024-04-09T22:46:56Z
publishDate 2023-03-01
publisher Nature Portfolio
record_format Article
series Nature Communications
spelling doaj.art-60d579693bba484a869caf3e3a3e50692023-03-22T11:47:08ZengNature PortfolioNature Communications2041-17232023-03-011411910.1038/s41467-023-37261-xSubsurface nickel boosts the low-temperature performance of a boron oxide overlayer in propane oxidative dehydrogenationXiaofeng Gao0Ling Zhu1Feng Yang2Lei Zhang3Wenhao Xu4Xian Zhou5Yongkang Huang6Houhong Song7Lili Lin8Xiaodong Wen9Ding Ma10Siyu Yao11Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang UniversityState Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of SciencesDepartment of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and TechnologyDepartment of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and TechnologyKey Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang UniversityKey Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang UniversityKey Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang UniversityKey Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang UniversityInstitute of Industrial Catalysis, State Key Laboratory of Green Chemistry Synthesis Technology, College of Chemical Engineering, Zhejiang University of TechnologyState Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of SciencesBeijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering and College of Engineering, Peking UniversityKey Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang UniversityThe working temperature of boron-based catalysts reduces their thermodynamic advantages in the oxidative dehydrogenation of propane (ODHP). Here the authors demonstrate encapsulated Ni nanoparticles as effective subsurface promoters to enhance the low temperature activity and selectivity of the boron oxide overlayer in ODHP.https://doi.org/10.1038/s41467-023-37261-x
spellingShingle Xiaofeng Gao
Ling Zhu
Feng Yang
Lei Zhang
Wenhao Xu
Xian Zhou
Yongkang Huang
Houhong Song
Lili Lin
Xiaodong Wen
Ding Ma
Siyu Yao
Subsurface nickel boosts the low-temperature performance of a boron oxide overlayer in propane oxidative dehydrogenation
Nature Communications
title Subsurface nickel boosts the low-temperature performance of a boron oxide overlayer in propane oxidative dehydrogenation
title_full Subsurface nickel boosts the low-temperature performance of a boron oxide overlayer in propane oxidative dehydrogenation
title_fullStr Subsurface nickel boosts the low-temperature performance of a boron oxide overlayer in propane oxidative dehydrogenation
title_full_unstemmed Subsurface nickel boosts the low-temperature performance of a boron oxide overlayer in propane oxidative dehydrogenation
title_short Subsurface nickel boosts the low-temperature performance of a boron oxide overlayer in propane oxidative dehydrogenation
title_sort subsurface nickel boosts the low temperature performance of a boron oxide overlayer in propane oxidative dehydrogenation
url https://doi.org/10.1038/s41467-023-37261-x
work_keys_str_mv AT xiaofenggao subsurfacenickelbooststhelowtemperatureperformanceofaboronoxideoverlayerinpropaneoxidativedehydrogenation
AT lingzhu subsurfacenickelbooststhelowtemperatureperformanceofaboronoxideoverlayerinpropaneoxidativedehydrogenation
AT fengyang subsurfacenickelbooststhelowtemperatureperformanceofaboronoxideoverlayerinpropaneoxidativedehydrogenation
AT leizhang subsurfacenickelbooststhelowtemperatureperformanceofaboronoxideoverlayerinpropaneoxidativedehydrogenation
AT wenhaoxu subsurfacenickelbooststhelowtemperatureperformanceofaboronoxideoverlayerinpropaneoxidativedehydrogenation
AT xianzhou subsurfacenickelbooststhelowtemperatureperformanceofaboronoxideoverlayerinpropaneoxidativedehydrogenation
AT yongkanghuang subsurfacenickelbooststhelowtemperatureperformanceofaboronoxideoverlayerinpropaneoxidativedehydrogenation
AT houhongsong subsurfacenickelbooststhelowtemperatureperformanceofaboronoxideoverlayerinpropaneoxidativedehydrogenation
AT lililin subsurfacenickelbooststhelowtemperatureperformanceofaboronoxideoverlayerinpropaneoxidativedehydrogenation
AT xiaodongwen subsurfacenickelbooststhelowtemperatureperformanceofaboronoxideoverlayerinpropaneoxidativedehydrogenation
AT dingma subsurfacenickelbooststhelowtemperatureperformanceofaboronoxideoverlayerinpropaneoxidativedehydrogenation
AT siyuyao subsurfacenickelbooststhelowtemperatureperformanceofaboronoxideoverlayerinpropaneoxidativedehydrogenation