Bu4NSO4SnPh3•Ph3PO: SYNTHESIS AND SPECTROSCOPIC STUDIES

On allowing Bu4NSO4SnPh3 to react with Ph3PO, the adduct Bu4NSO4SnPh3•Ph3PO is obtained. The IR and Mössbauer data allow to conclude to the cleavage of the Bu4NSO4SnPh3 chain and the coordination of Ph3PO to the tin (IV) centre leading to discrete ionic structure containing a trans bipyramidal trigo...

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Main Authors: Bernard Mahieu, Libasse Diop, Serge Renamy
Format: Article
Language:English
Published: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2011-02-01
Series:Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
Subjects:
Online Access:http://pubs.ub.ro/dwnl.php?id=CSCC6201112V01S01A0014
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author Bernard Mahieu
Libasse Diop
Serge Renamy
author_facet Bernard Mahieu
Libasse Diop
Serge Renamy
author_sort Bernard Mahieu
collection DOAJ
description On allowing Bu4NSO4SnPh3 to react with Ph3PO, the adduct Bu4NSO4SnPh3•Ph3PO is obtained. The IR and Mössbauer data allow to conclude to the cleavage of the Bu4NSO4SnPh3 chain and the coordination of Ph3PO to the tin (IV) centre leading to discrete ionic structure containing a trans bipyramidal trigonal SnC3O2 arrangement with SO42- and Ph3PO being in an apical positions.
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language English
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publishDate 2011-02-01
publisher Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
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series Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
spelling doaj.art-60e4e6271bc7415d9c231260a267e1a82022-12-22T02:17:09ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X2011-02-011218587Bu4NSO4SnPh3•Ph3PO: SYNTHESIS AND SPECTROSCOPIC STUDIESBernard MahieuLibasse DiopSerge RenamyOn allowing Bu4NSO4SnPh3 to react with Ph3PO, the adduct Bu4NSO4SnPh3•Ph3PO is obtained. The IR and Mössbauer data allow to conclude to the cleavage of the Bu4NSO4SnPh3 chain and the coordination of Ph3PO to the tin (IV) centre leading to discrete ionic structure containing a trans bipyramidal trigonal SnC3O2 arrangement with SO42- and Ph3PO being in an apical positions.http://pubs.ub.ro/dwnl.php?id=CSCC6201112V01S01A0014coordinating Ph3PO sulphateIRMössbauertrans coordinated SnPh3 residue
spellingShingle Bernard Mahieu
Libasse Diop
Serge Renamy
Bu4NSO4SnPh3•Ph3PO: SYNTHESIS AND SPECTROSCOPIC STUDIES
Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
coordinating Ph3PO sulphate
IR
Mössbauer
trans coordinated SnPh3 residue
title Bu4NSO4SnPh3•Ph3PO: SYNTHESIS AND SPECTROSCOPIC STUDIES
title_full Bu4NSO4SnPh3•Ph3PO: SYNTHESIS AND SPECTROSCOPIC STUDIES
title_fullStr Bu4NSO4SnPh3•Ph3PO: SYNTHESIS AND SPECTROSCOPIC STUDIES
title_full_unstemmed Bu4NSO4SnPh3•Ph3PO: SYNTHESIS AND SPECTROSCOPIC STUDIES
title_short Bu4NSO4SnPh3•Ph3PO: SYNTHESIS AND SPECTROSCOPIC STUDIES
title_sort bu4nso4snph3•ph3po synthesis and spectroscopic studies
topic coordinating Ph3PO sulphate
IR
Mössbauer
trans coordinated SnPh3 residue
url http://pubs.ub.ro/dwnl.php?id=CSCC6201112V01S01A0014
work_keys_str_mv AT bernardmahieu bu4nso4snph3ph3posynthesisandspectroscopicstudies
AT libassediop bu4nso4snph3ph3posynthesisandspectroscopicstudies
AT sergerenamy bu4nso4snph3ph3posynthesisandspectroscopicstudies