Bu4NSO4SnPh3•Ph3PO: SYNTHESIS AND SPECTROSCOPIC STUDIES
On allowing Bu4NSO4SnPh3 to react with Ph3PO, the adduct Bu4NSO4SnPh3•Ph3PO is obtained. The IR and Mössbauer data allow to conclude to the cleavage of the Bu4NSO4SnPh3 chain and the coordination of Ph3PO to the tin (IV) centre leading to discrete ionic structure containing a trans bipyramidal trigo...
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Format: | Article |
Language: | English |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2011-02-01
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Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
Subjects: | |
Online Access: | http://pubs.ub.ro/dwnl.php?id=CSCC6201112V01S01A0014 |
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author | Bernard Mahieu Libasse Diop Serge Renamy |
author_facet | Bernard Mahieu Libasse Diop Serge Renamy |
author_sort | Bernard Mahieu |
collection | DOAJ |
description | On allowing Bu4NSO4SnPh3 to react with Ph3PO, the adduct Bu4NSO4SnPh3•Ph3PO is obtained. The IR and Mössbauer data allow to conclude to the cleavage of the Bu4NSO4SnPh3 chain and the coordination of Ph3PO to the tin (IV) centre leading to discrete ionic structure containing a trans bipyramidal trigonal SnC3O2 arrangement with SO42- and Ph3PO being in an apical positions. |
first_indexed | 2024-04-14T02:40:00Z |
format | Article |
id | doaj.art-60e4e6271bc7415d9c231260a267e1a8 |
institution | Directory Open Access Journal |
issn | 1582-540X |
language | English |
last_indexed | 2024-04-14T02:40:00Z |
publishDate | 2011-02-01 |
publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
record_format | Article |
series | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
spelling | doaj.art-60e4e6271bc7415d9c231260a267e1a82022-12-22T02:17:09ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X2011-02-011218587Bu4NSO4SnPh3•Ph3PO: SYNTHESIS AND SPECTROSCOPIC STUDIESBernard MahieuLibasse DiopSerge RenamyOn allowing Bu4NSO4SnPh3 to react with Ph3PO, the adduct Bu4NSO4SnPh3•Ph3PO is obtained. The IR and Mössbauer data allow to conclude to the cleavage of the Bu4NSO4SnPh3 chain and the coordination of Ph3PO to the tin (IV) centre leading to discrete ionic structure containing a trans bipyramidal trigonal SnC3O2 arrangement with SO42- and Ph3PO being in an apical positions.http://pubs.ub.ro/dwnl.php?id=CSCC6201112V01S01A0014coordinating Ph3PO sulphateIRMössbauertrans coordinated SnPh3 residue |
spellingShingle | Bernard Mahieu Libasse Diop Serge Renamy Bu4NSO4SnPh3•Ph3PO: SYNTHESIS AND SPECTROSCOPIC STUDIES Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry coordinating Ph3PO sulphate IR Mössbauer trans coordinated SnPh3 residue |
title | Bu4NSO4SnPh3•Ph3PO: SYNTHESIS AND SPECTROSCOPIC STUDIES |
title_full | Bu4NSO4SnPh3•Ph3PO: SYNTHESIS AND SPECTROSCOPIC STUDIES |
title_fullStr | Bu4NSO4SnPh3•Ph3PO: SYNTHESIS AND SPECTROSCOPIC STUDIES |
title_full_unstemmed | Bu4NSO4SnPh3•Ph3PO: SYNTHESIS AND SPECTROSCOPIC STUDIES |
title_short | Bu4NSO4SnPh3•Ph3PO: SYNTHESIS AND SPECTROSCOPIC STUDIES |
title_sort | bu4nso4snph3•ph3po synthesis and spectroscopic studies |
topic | coordinating Ph3PO sulphate IR Mössbauer trans coordinated SnPh3 residue |
url | http://pubs.ub.ro/dwnl.php?id=CSCC6201112V01S01A0014 |
work_keys_str_mv | AT bernardmahieu bu4nso4snph3ph3posynthesisandspectroscopicstudies AT libassediop bu4nso4snph3ph3posynthesisandspectroscopicstudies AT sergerenamy bu4nso4snph3ph3posynthesisandspectroscopicstudies |