Studies on the Migration of Sulphur and Chlorine in the Pyrolysis Products of Floor and Furniture Joinery

This article discusses research on the low-temperature pyrolysis of waste floor and furniture joinery as an example of chemical recycling. Pyrolysis was carried out at 425 °C to obtain solid, liquid, and gaseous products. In line with the circular economy concept, the waste was transformed into econ...

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Main Authors: Małgorzata Kajda-Szcześniak, Waldemar Ścierski
Format: Article
Language:English
Published: MDPI AG 2023-11-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/16/21/7446
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author Małgorzata Kajda-Szcześniak
Waldemar Ścierski
author_facet Małgorzata Kajda-Szcześniak
Waldemar Ścierski
author_sort Małgorzata Kajda-Szcześniak
collection DOAJ
description This article discusses research on the low-temperature pyrolysis of waste floor and furniture joinery as an example of chemical recycling. Pyrolysis was carried out at 425 °C to obtain solid, liquid, and gaseous products. In line with the circular economy concept, the waste was transformed into economical and environmentally friendly raw materials suitable for application. Research results related to the chemical composition and properties of pyrolysis products are shown, with particular emphasis on the migration process of acidic impurities, i.e., sulphur and chlorine. In some processes, the presence of such substances can be a problem. Research has shown the high potential for sulphur and chlorine migration in pyrolysis products. It was shown that for woodwork, the most sulphur was discharged with the pyrolysis gas and the least was immobilised in the oil fraction. For vinyl panels, more than 50% of the sulphur was immobilised in the char. Chlorine was immobilised mainly in the char and pyrolysis gas. A high chlorine content of 12.55% was found in the vinyl panel. At the same time, a high chlorine content was also found in the pyrolysis products of these panels. This value is several times higher than in wood-based waste.
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spelling doaj.art-60f7465788954ef4abf25630154d378f2023-11-10T15:02:34ZengMDPI AGEnergies1996-10732023-11-011621744610.3390/en16217446Studies on the Migration of Sulphur and Chlorine in the Pyrolysis Products of Floor and Furniture JoineryMałgorzata Kajda-Szcześniak0Waldemar Ścierski1Department of Technologies and Installations for Waste Management, Faculty of Energy and Environmental Engineering, The Silesian University of Technology, Konarskiego 18, 44-100 Gliwice, PolandDepartment of Technologies and Installations for Waste Management, Faculty of Energy and Environmental Engineering, The Silesian University of Technology, Konarskiego 18, 44-100 Gliwice, PolandThis article discusses research on the low-temperature pyrolysis of waste floor and furniture joinery as an example of chemical recycling. Pyrolysis was carried out at 425 °C to obtain solid, liquid, and gaseous products. In line with the circular economy concept, the waste was transformed into economical and environmentally friendly raw materials suitable for application. Research results related to the chemical composition and properties of pyrolysis products are shown, with particular emphasis on the migration process of acidic impurities, i.e., sulphur and chlorine. In some processes, the presence of such substances can be a problem. Research has shown the high potential for sulphur and chlorine migration in pyrolysis products. It was shown that for woodwork, the most sulphur was discharged with the pyrolysis gas and the least was immobilised in the oil fraction. For vinyl panels, more than 50% of the sulphur was immobilised in the char. Chlorine was immobilised mainly in the char and pyrolysis gas. A high chlorine content of 12.55% was found in the vinyl panel. At the same time, a high chlorine content was also found in the pyrolysis products of these panels. This value is several times higher than in wood-based waste.https://www.mdpi.com/1996-1073/16/21/7446low-temperature pyrolysischlorine migrationsulphur migrationchemical recycling
spellingShingle Małgorzata Kajda-Szcześniak
Waldemar Ścierski
Studies on the Migration of Sulphur and Chlorine in the Pyrolysis Products of Floor and Furniture Joinery
Energies
low-temperature pyrolysis
chlorine migration
sulphur migration
chemical recycling
title Studies on the Migration of Sulphur and Chlorine in the Pyrolysis Products of Floor and Furniture Joinery
title_full Studies on the Migration of Sulphur and Chlorine in the Pyrolysis Products of Floor and Furniture Joinery
title_fullStr Studies on the Migration of Sulphur and Chlorine in the Pyrolysis Products of Floor and Furniture Joinery
title_full_unstemmed Studies on the Migration of Sulphur and Chlorine in the Pyrolysis Products of Floor and Furniture Joinery
title_short Studies on the Migration of Sulphur and Chlorine in the Pyrolysis Products of Floor and Furniture Joinery
title_sort studies on the migration of sulphur and chlorine in the pyrolysis products of floor and furniture joinery
topic low-temperature pyrolysis
chlorine migration
sulphur migration
chemical recycling
url https://www.mdpi.com/1996-1073/16/21/7446
work_keys_str_mv AT małgorzatakajdaszczesniak studiesonthemigrationofsulphurandchlorineinthepyrolysisproductsoffloorandfurniturejoinery
AT waldemarscierski studiesonthemigrationofsulphurandchlorineinthepyrolysisproductsoffloorandfurniturejoinery