The crystal structure of Iridium Complex with Thiocarbamide
By interaction of water solutions of K3[IrCl6] and Thiocarbamide (Thio, SC(NH2)2) at heating the complex of the composition [Ir(Thio)3Cl3] was synthesized. By the method of X-ray diffraction that the compound crystallizes in the monoclinic crystal system with space group C2/c, a = 13.492(3) Å, b = 8...
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| Format: | Article |
| Language: | Russian |
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MIREA - Russian Technological University
2008-10-01
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| Series: | Тонкие химические технологии |
| Subjects: | |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/1532 |
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| author | T. M. Buslaeva E. V. Kopylova V. V. Kravchenko G. A. Fedorova |
| author_facet | T. M. Buslaeva E. V. Kopylova V. V. Kravchenko G. A. Fedorova |
| author_sort | T. M. Buslaeva |
| collection | DOAJ |
| description | By interaction of water solutions of K3[IrCl6] and Thiocarbamide (Thio, SC(NH2)2) at heating the complex of the composition [Ir(Thio)3Cl3] was synthesized. By the method of X-ray diffraction that the compound crystallizes in the monoclinic crystal system with space group C2/c, a = 13.492(3) Å, b = 8.264(2) Å, c = 24.979(5) Å, β = 92.79(3), V = 2782.00(1) Å3 , Z = 8. The compound has a structure with two crystallographically independent iridium atoms: the coordination sphere of the Ir(1) atom involves two Cl atoms and four S atom, whereas the coordination sphere of the Ir(2) atom consists four Cl atoms and two S atom. Coordination of molecules Thio to the Iridium is realized though the sulfur atom. |
| first_indexed | 2024-04-10T03:31:55Z |
| format | Article |
| id | doaj.art-6111ace6652349aa9c9b24be729f0460 |
| institution | Directory Open Access Journal |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| last_indexed | 2025-03-14T10:43:06Z |
| publishDate | 2008-10-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj.art-6111ace6652349aa9c9b24be729f04602025-03-02T10:57:24ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752008-10-013557611527The crystal structure of Iridium Complex with ThiocarbamideT. M. Buslaeva0E. V. Kopylova1V. V. Kravchenko2G. A. Fedorova3M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571By interaction of water solutions of K3[IrCl6] and Thiocarbamide (Thio, SC(NH2)2) at heating the complex of the composition [Ir(Thio)3Cl3] was synthesized. By the method of X-ray diffraction that the compound crystallizes in the monoclinic crystal system with space group C2/c, a = 13.492(3) Å, b = 8.264(2) Å, c = 24.979(5) Å, β = 92.79(3), V = 2782.00(1) Å3 , Z = 8. The compound has a structure with two crystallographically independent iridium atoms: the coordination sphere of the Ir(1) atom involves two Cl atoms and four S atom, whereas the coordination sphere of the Ir(2) atom consists four Cl atoms and two S atom. Coordination of molecules Thio to the Iridium is realized though the sulfur atom.https://www.finechem-mirea.ru/jour/article/view/1532иридий, тиомочевина, комплекс, синтез, структура |
| spellingShingle | T. M. Buslaeva E. V. Kopylova V. V. Kravchenko G. A. Fedorova The crystal structure of Iridium Complex with Thiocarbamide Тонкие химические технологии иридий, тиомочевина, комплекс, синтез, структура |
| title | The crystal structure of Iridium Complex with Thiocarbamide |
| title_full | The crystal structure of Iridium Complex with Thiocarbamide |
| title_fullStr | The crystal structure of Iridium Complex with Thiocarbamide |
| title_full_unstemmed | The crystal structure of Iridium Complex with Thiocarbamide |
| title_short | The crystal structure of Iridium Complex with Thiocarbamide |
| title_sort | crystal structure of iridium complex with thiocarbamide |
| topic | иридий, тиомочевина, комплекс, синтез, структура |
| url | https://www.finechem-mirea.ru/jour/article/view/1532 |
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