Effect of Amine Compounds on the Self-Polymerisation of Methyl Methacrylate
This work is the result of the experimental analysis of the effect of different alkyl anilines (accelerators) on the self-polymerisation of methyl methacrylate. The state of the art before this study suggested that there should have been no significant increase in the rate of polymerisation reaction...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
AIDIC Servizi S.r.l.
2014-04-01
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| Series: | Chemical Engineering Transactions |
| Online Access: | https://www.cetjournal.it/index.php/cet/article/view/5862 |
| _version_ | 1818415742910988288 |
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| author | V. Casson T. Snee G. Maschio |
| author_facet | V. Casson T. Snee G. Maschio |
| author_sort | V. Casson |
| collection | DOAJ |
| description | This work is the result of the experimental analysis of the effect of different alkyl anilines (accelerators) on the self-polymerisation of methyl methacrylate. The state of the art before this study suggested that there should have been no significant increase in the rate of polymerisation reaction until the initiator (typically a peroxide) is added to the stabilised mixture of monomer and accelerator. All the experimental results found during this investigation indicated instead that the accelerators can affect the rate of polymerisation even if no peroxide is present in the system. Different kinds of alkyl anilines in methyl methacrylate have been tested by differential scanning calorimetry and adiabatic calorimetry. The experimental data allowed us to define safety ranges for the polymerisation reaction. |
| first_indexed | 2024-12-14T11:39:50Z |
| format | Article |
| id | doaj.art-611abaa4dc8c43bcaad2320e245b264f |
| institution | Directory Open Access Journal |
| issn | 2283-9216 |
| language | English |
| last_indexed | 2024-12-14T11:39:50Z |
| publishDate | 2014-04-01 |
| publisher | AIDIC Servizi S.r.l. |
| record_format | Article |
| series | Chemical Engineering Transactions |
| spelling | doaj.art-611abaa4dc8c43bcaad2320e245b264f2022-12-21T23:02:53ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162014-04-013610.3303/CET1436019Effect of Amine Compounds on the Self-Polymerisation of Methyl MethacrylateV. CassonT. SneeG. MaschioThis work is the result of the experimental analysis of the effect of different alkyl anilines (accelerators) on the self-polymerisation of methyl methacrylate. The state of the art before this study suggested that there should have been no significant increase in the rate of polymerisation reaction until the initiator (typically a peroxide) is added to the stabilised mixture of monomer and accelerator. All the experimental results found during this investigation indicated instead that the accelerators can affect the rate of polymerisation even if no peroxide is present in the system. Different kinds of alkyl anilines in methyl methacrylate have been tested by differential scanning calorimetry and adiabatic calorimetry. The experimental data allowed us to define safety ranges for the polymerisation reaction.https://www.cetjournal.it/index.php/cet/article/view/5862 |
| spellingShingle | V. Casson T. Snee G. Maschio Effect of Amine Compounds on the Self-Polymerisation of Methyl Methacrylate Chemical Engineering Transactions |
| title | Effect of Amine Compounds on the Self-Polymerisation of Methyl Methacrylate |
| title_full | Effect of Amine Compounds on the Self-Polymerisation of Methyl Methacrylate |
| title_fullStr | Effect of Amine Compounds on the Self-Polymerisation of Methyl Methacrylate |
| title_full_unstemmed | Effect of Amine Compounds on the Self-Polymerisation of Methyl Methacrylate |
| title_short | Effect of Amine Compounds on the Self-Polymerisation of Methyl Methacrylate |
| title_sort | effect of amine compounds on the self polymerisation of methyl methacrylate |
| url | https://www.cetjournal.it/index.php/cet/article/view/5862 |
| work_keys_str_mv | AT vcasson effectofaminecompoundsontheselfpolymerisationofmethylmethacrylate AT tsnee effectofaminecompoundsontheselfpolymerisationofmethylmethacrylate AT gmaschio effectofaminecompoundsontheselfpolymerisationofmethylmethacrylate |