Bis[μ-2-(3-pyridylmethyl)-2H-benzotriazole]bis[nitratosilver(I)]
In the title centrosymmetric binuclear AgI complex, [Ag2(NO3)2(C12H10N4)2], each AgI center is coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 2-(3-pyridylmethyl)-2H-benzotriazole (L) ligands, and an O atom of a coordinated NO3− anion in a distorted...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680803479X |
| _version_ | 1798024472809177088 |
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| author | Min Hu Song-Tao Ma Liang-Qi Guo Guang-Hui Sun Shao-Ming Fang |
| author_facet | Min Hu Song-Tao Ma Liang-Qi Guo Guang-Hui Sun Shao-Ming Fang |
| author_sort | Min Hu |
| collection | DOAJ |
| description | In the title centrosymmetric binuclear AgI complex, [Ag2(NO3)2(C12H10N4)2], each AgI center is coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 2-(3-pyridylmethyl)-2H-benzotriazole (L) ligands, and an O atom of a coordinated NO3− anion in a distorted T-shaped geometry. This forms a unique box-like cyclic dimer with an intramolecular non-bonding Ag...Ag separation of 6.327 (2) Å. Weak intermolecular Ag...O(nitrate) interactions [2.728 (4) and 2.646 (3) Å] link the binuclear units, forming a two-dimensional network parallel to (100). Intermolecular C—H...O hydrogen-bonding interactions, involving the L ligands and the coordinated NO3− anions, link the sheets, forming a three-dimensional framework. |
| first_indexed | 2024-04-11T18:03:00Z |
| format | Article |
| id | doaj.art-611d69b88c3e476d8dbb5ead6a02c4f6 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:03:00Z |
| publishDate | 2008-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-611d69b88c3e476d8dbb5ead6a02c4f62022-12-22T04:10:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-11-016411m1473m147410.1107/S160053680803479XBis[μ-2-(3-pyridylmethyl)-2H-benzotriazole]bis[nitratosilver(I)]Min HuSong-Tao MaLiang-Qi GuoGuang-Hui SunShao-Ming FangIn the title centrosymmetric binuclear AgI complex, [Ag2(NO3)2(C12H10N4)2], each AgI center is coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 2-(3-pyridylmethyl)-2H-benzotriazole (L) ligands, and an O atom of a coordinated NO3− anion in a distorted T-shaped geometry. This forms a unique box-like cyclic dimer with an intramolecular non-bonding Ag...Ag separation of 6.327 (2) Å. Weak intermolecular Ag...O(nitrate) interactions [2.728 (4) and 2.646 (3) Å] link the binuclear units, forming a two-dimensional network parallel to (100). Intermolecular C—H...O hydrogen-bonding interactions, involving the L ligands and the coordinated NO3− anions, link the sheets, forming a three-dimensional framework.http://scripts.iucr.org/cgi-bin/paper?S160053680803479X |
| spellingShingle | Min Hu Song-Tao Ma Liang-Qi Guo Guang-Hui Sun Shao-Ming Fang Bis[μ-2-(3-pyridylmethyl)-2H-benzotriazole]bis[nitratosilver(I)] Acta Crystallographica Section E |
| title | Bis[μ-2-(3-pyridylmethyl)-2H-benzotriazole]bis[nitratosilver(I)] |
| title_full | Bis[μ-2-(3-pyridylmethyl)-2H-benzotriazole]bis[nitratosilver(I)] |
| title_fullStr | Bis[μ-2-(3-pyridylmethyl)-2H-benzotriazole]bis[nitratosilver(I)] |
| title_full_unstemmed | Bis[μ-2-(3-pyridylmethyl)-2H-benzotriazole]bis[nitratosilver(I)] |
| title_short | Bis[μ-2-(3-pyridylmethyl)-2H-benzotriazole]bis[nitratosilver(I)] |
| title_sort | bis 956 2 3 pyridylmethyl 2h benzotriazole bis nitratosilver i |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053680803479X |
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