Crystal structure of 2,2′-({[2-(tritylsulfanyl)benzyl]azanediyl}bis(ethane-2,1-diyl))bis(isoindoline-1,3-dione)
In the structure of the title compound, C46H37N3O4S, the planes of the two isoindoline units make a dihedral angle of 77.86 (3)°. The dihedral angles between the benzyl plane and the isoindoline units are 79.56 (4) and 3.74 (9)°. The geometry at the S atom shows a short [1.7748 (17) Å] S—Cbenzyl and...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-09-01
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| Series: | Acta Crystallographica Section E |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814015554 |
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| author | Ulrich Flörke Adam Neuba Jochen Ortmeyer Gerald Henkel |
| author_facet | Ulrich Flörke Adam Neuba Jochen Ortmeyer Gerald Henkel |
| author_sort | Ulrich Flörke |
| collection | DOAJ |
| description | In the structure of the title compound, C46H37N3O4S, the planes of the two isoindoline units make a dihedral angle of 77.86 (3)°. The dihedral angles between the benzyl plane and the isoindoline units are 79.56 (4) and 3.74 (9)°. The geometry at the S atom shows a short [1.7748 (17) Å] S—Cbenzyl and a long [1.8820 (15) Å] S—Ctrityl bond and the C—S—C angle is 108.40 (7)°. N—C bond lengths around the azane N atom are in the range 1.454 (2)–1.463 (2) Å. he crystal packing exhibts two rather `non-classical' C—H...O hydrogen bonds that result in stacking of the molecules along the a as well as the b axis and give rise to columnar sub-structures. |
| first_indexed | 2024-12-13T10:39:00Z |
| format | Article |
| id | doaj.art-614b9632b7704d8c90f7d221022a9384 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:39:00Z |
| publishDate | 2014-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-614b9632b7704d8c90f7d221022a93842022-12-21T23:50:38ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-09-01709o895o89610.1107/S1600536814015554bt6987Crystal structure of 2,2′-({[2-(tritylsulfanyl)benzyl]azanediyl}bis(ethane-2,1-diyl))bis(isoindoline-1,3-dione)Ulrich Flörke0Adam Neuba1Jochen Ortmeyer2Gerald Henkel3Universität Paderborn, Warburger Strasse 100, 33098 Paderborn, GermanyUniversität Paderborn, Warburger Strasse 100, 33098 Paderborn, GermanyUniversität Paderborn, Warburger Strasse 100, 33098 Paderborn, GermanyUniversität Paderborn, Warburger Strasse 100, 33098 Paderborn, GermanyIn the structure of the title compound, C46H37N3O4S, the planes of the two isoindoline units make a dihedral angle of 77.86 (3)°. The dihedral angles between the benzyl plane and the isoindoline units are 79.56 (4) and 3.74 (9)°. The geometry at the S atom shows a short [1.7748 (17) Å] S—Cbenzyl and a long [1.8820 (15) Å] S—Ctrityl bond and the C—S—C angle is 108.40 (7)°. N—C bond lengths around the azane N atom are in the range 1.454 (2)–1.463 (2) Å. he crystal packing exhibts two rather `non-classical' C—H...O hydrogen bonds that result in stacking of the molecules along the a as well as the b axis and give rise to columnar sub-structures.http://scripts.iucr.org/cgi-bin/paper?S1600536814015554crystal structuretripodal ligandsphthalimidehydrogen bonding |
| spellingShingle | Ulrich Flörke Adam Neuba Jochen Ortmeyer Gerald Henkel Crystal structure of 2,2′-({[2-(tritylsulfanyl)benzyl]azanediyl}bis(ethane-2,1-diyl))bis(isoindoline-1,3-dione) Acta Crystallographica Section E crystal structure tripodal ligands phthalimide hydrogen bonding |
| title | Crystal structure of 2,2′-({[2-(tritylsulfanyl)benzyl]azanediyl}bis(ethane-2,1-diyl))bis(isoindoline-1,3-dione) |
| title_full | Crystal structure of 2,2′-({[2-(tritylsulfanyl)benzyl]azanediyl}bis(ethane-2,1-diyl))bis(isoindoline-1,3-dione) |
| title_fullStr | Crystal structure of 2,2′-({[2-(tritylsulfanyl)benzyl]azanediyl}bis(ethane-2,1-diyl))bis(isoindoline-1,3-dione) |
| title_full_unstemmed | Crystal structure of 2,2′-({[2-(tritylsulfanyl)benzyl]azanediyl}bis(ethane-2,1-diyl))bis(isoindoline-1,3-dione) |
| title_short | Crystal structure of 2,2′-({[2-(tritylsulfanyl)benzyl]azanediyl}bis(ethane-2,1-diyl))bis(isoindoline-1,3-dione) |
| title_sort | crystal structure of 2 2 2 tritylsulfanyl benzyl azanediyl bis ethane 2 1 diyl bis isoindoline 1 3 dione |
| topic | crystal structure tripodal ligands phthalimide hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814015554 |
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