Synthesis, crystal structure and Hirshfeld surface analysis of di-μ2-iodido-bis[(2,2′-biquinoline-κ2N,N′)copper(I)]
The molecular and crystal structures of the title compound, [Cu2I2(C18H12N2)2], were examined by single-crystal X-ray diffraction and Hirshfeld surface analysis. The Cu atom is coordinated in a distorted tetrahedral geometry by two N atoms from the 2,2′-biquinoline ligands and the two μ2-bridging io...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2023-03-01
|
| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989023000634 |
| _version_ | 1811158129151311872 |
|---|---|
| author | Ayalew W. Temesgen Anton P. Novikov Alexander G. Tskhovrebov Ekaterina K. Kultyshkina Tuan Anh Le |
| author_facet | Ayalew W. Temesgen Anton P. Novikov Alexander G. Tskhovrebov Ekaterina K. Kultyshkina Tuan Anh Le |
| author_sort | Ayalew W. Temesgen |
| collection | DOAJ |
| description | The molecular and crystal structures of the title compound, [Cu2I2(C18H12N2)2], were examined by single-crystal X-ray diffraction and Hirshfeld surface analysis. The Cu atom is coordinated in a distorted tetrahedral geometry by two N atoms from the 2,2′-biquinoline ligands and the two μ2-bridging iodide ligands. The molecules are in contact via π–π-stacking interactions. Hirshfeld surface analysis showed that the most important contributions to the intermolecular interactions are H...H (39.7%), H...I/I...H (17.8%), C...H/H...C (17.5%), C...C (16.5%), N...C/C...N (3.9%) and N...H/H...N (3.5%). |
| first_indexed | 2024-04-10T05:18:05Z |
| format | Article |
| id | doaj.art-615e1c8a130444e9b087e46dd0e01650 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-10T05:18:05Z |
| publishDate | 2023-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-615e1c8a130444e9b087e46dd0e016502023-03-08T12:49:03ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902023-03-0179313213510.1107/S2056989023000634dj2055Synthesis, crystal structure and Hirshfeld surface analysis of di-μ2-iodido-bis[(2,2′-biquinoline-κ2N,N′)copper(I)]Ayalew W. Temesgen0Anton P. Novikov1Alexander G. Tskhovrebov2Ekaterina K. Kultyshkina3Tuan Anh Le4Department of Chemistry, College of Natural and Computational Science, University of Gondar, Gondar 196, EthiopiaPeoples' Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya, St, 117198, Moscow, Russian FederationPeoples' Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya, St, 117198, Moscow, Russian FederationPeoples' Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya, St, 117198, Moscow, Russian FederationUniversity of Science, Vietnam National University, Hanoi, 334 Nguyen Trai, Thanh Xuan, 100000, Hanoi, VietnamThe molecular and crystal structures of the title compound, [Cu2I2(C18H12N2)2], were examined by single-crystal X-ray diffraction and Hirshfeld surface analysis. The Cu atom is coordinated in a distorted tetrahedral geometry by two N atoms from the 2,2′-biquinoline ligands and the two μ2-bridging iodide ligands. The molecules are in contact via π–π-stacking interactions. Hirshfeld surface analysis showed that the most important contributions to the intermolecular interactions are H...H (39.7%), H...I/I...H (17.8%), C...H/H...C (17.5%), C...C (16.5%), N...C/C...N (3.9%) and N...H/H...N (3.5%).http://scripts.iucr.org/cgi-bin/paper?S2056989023000634crystal structurehirshfeld surface analysisπ–π stackingbiquinolinecopper complex |
| spellingShingle | Ayalew W. Temesgen Anton P. Novikov Alexander G. Tskhovrebov Ekaterina K. Kultyshkina Tuan Anh Le Synthesis, crystal structure and Hirshfeld surface analysis of di-μ2-iodido-bis[(2,2′-biquinoline-κ2N,N′)copper(I)] Acta Crystallographica Section E: Crystallographic Communications crystal structure hirshfeld surface analysis π–π stacking biquinoline copper complex |
| title | Synthesis, crystal structure and Hirshfeld surface analysis of di-μ2-iodido-bis[(2,2′-biquinoline-κ2N,N′)copper(I)] |
| title_full | Synthesis, crystal structure and Hirshfeld surface analysis of di-μ2-iodido-bis[(2,2′-biquinoline-κ2N,N′)copper(I)] |
| title_fullStr | Synthesis, crystal structure and Hirshfeld surface analysis of di-μ2-iodido-bis[(2,2′-biquinoline-κ2N,N′)copper(I)] |
| title_full_unstemmed | Synthesis, crystal structure and Hirshfeld surface analysis of di-μ2-iodido-bis[(2,2′-biquinoline-κ2N,N′)copper(I)] |
| title_short | Synthesis, crystal structure and Hirshfeld surface analysis of di-μ2-iodido-bis[(2,2′-biquinoline-κ2N,N′)copper(I)] |
| title_sort | synthesis crystal structure and hirshfeld surface analysis of di μ2 iodido bis 2 2 biquinoline κ2n n copper i |
| topic | crystal structure hirshfeld surface analysis π–π stacking biquinoline copper complex |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989023000634 |
| work_keys_str_mv | AT ayalewwtemesgen synthesiscrystalstructureandhirshfeldsurfaceanalysisofdim2iodidobis22biquinolinek2nncopperi AT antonpnovikov synthesiscrystalstructureandhirshfeldsurfaceanalysisofdim2iodidobis22biquinolinek2nncopperi AT alexandergtskhovrebov synthesiscrystalstructureandhirshfeldsurfaceanalysisofdim2iodidobis22biquinolinek2nncopperi AT ekaterinakkultyshkina synthesiscrystalstructureandhirshfeldsurfaceanalysisofdim2iodidobis22biquinolinek2nncopperi AT tuananhle synthesiscrystalstructureandhirshfeldsurfaceanalysisofdim2iodidobis22biquinolinek2nncopperi |