Split-ring resonator with interdigital Split electrodes as detector for liquid and ion chromatography

The analysis of food and drugs as well as the monitoring of chemical processes and bioreactors by high-performance liquid chromatography and ion chromatography requires universal, cost-effective, and sensitive detectors. Therefore, this work presents a split-ring resonator that detects changes in th...

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Main Authors: Kirsten J. Dehning, Moritz Hitzemann, Stefan Zimmermann
Format: Article
Language:English
Published: Elsevier 2024-06-01
Series:Sensing and Bio-Sensing Research
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2214180424000278
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author Kirsten J. Dehning
Moritz Hitzemann
Stefan Zimmermann
author_facet Kirsten J. Dehning
Moritz Hitzemann
Stefan Zimmermann
author_sort Kirsten J. Dehning
collection DOAJ
description The analysis of food and drugs as well as the monitoring of chemical processes and bioreactors by high-performance liquid chromatography and ion chromatography requires universal, cost-effective, and sensitive detectors. Therefore, this work presents a split-ring resonator that detects changes in the electrical and dielectric properties of the eluate from liquid chromatography or ion chromatography by monitoring the amplitude of the transmitted signal using an envelope detector. The used split-ring resonator consists of a simple printed circuit board featuring two microstrip lines. One is formed to a ring with interdigital split electrodes. The interdigital split electrodes forming the sensitive area significantly enhance the sensitivity to changes in relative permittivity, dielectric losses and electrical conductivity of the eluate In addition, the split-ring resonator is a small, inexpensive and easy-to-use detector that uses several dielectric parameters simultaneously for the measurement. Furthermore, the split-ring resonator measures these parameters at a significantly lower frequency than optical detectors and therefore measures different changes in frequency-dependent permittivity. For demonstrating feasibility of a split-ring resonator as a detector for high-performance liquid chromatography and ion chromatography, various anion and cation standards, basic and acidic amino acids, sugars, as well as sugar alcohols were separated and detected. A conductivity detector for ion chromatography and a refractive index detector for high-performance liquid chromatography were used as reference detectors.
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spelling doaj.art-61b658b6b4634da4bbc61a0be0828d0c2024-04-13T04:21:20ZengElsevierSensing and Bio-Sensing Research2214-18042024-06-0144100645Split-ring resonator with interdigital Split electrodes as detector for liquid and ion chromatographyKirsten J. Dehning0Moritz Hitzemann1Stefan Zimmermann2Leibniz University Hannover, Institute of Electrical Engineering and Measurement Technology, Department of Sensors and Measurement Technology, Appelstr. 9A, Hannover 30167, GermanyCorresponding author.; Leibniz University Hannover, Institute of Electrical Engineering and Measurement Technology, Department of Sensors and Measurement Technology, Appelstr. 9A, Hannover 30167, GermanyLeibniz University Hannover, Institute of Electrical Engineering and Measurement Technology, Department of Sensors and Measurement Technology, Appelstr. 9A, Hannover 30167, GermanyThe analysis of food and drugs as well as the monitoring of chemical processes and bioreactors by high-performance liquid chromatography and ion chromatography requires universal, cost-effective, and sensitive detectors. Therefore, this work presents a split-ring resonator that detects changes in the electrical and dielectric properties of the eluate from liquid chromatography or ion chromatography by monitoring the amplitude of the transmitted signal using an envelope detector. The used split-ring resonator consists of a simple printed circuit board featuring two microstrip lines. One is formed to a ring with interdigital split electrodes. The interdigital split electrodes forming the sensitive area significantly enhance the sensitivity to changes in relative permittivity, dielectric losses and electrical conductivity of the eluate In addition, the split-ring resonator is a small, inexpensive and easy-to-use detector that uses several dielectric parameters simultaneously for the measurement. Furthermore, the split-ring resonator measures these parameters at a significantly lower frequency than optical detectors and therefore measures different changes in frequency-dependent permittivity. For demonstrating feasibility of a split-ring resonator as a detector for high-performance liquid chromatography and ion chromatography, various anion and cation standards, basic and acidic amino acids, sugars, as well as sugar alcohols were separated and detected. A conductivity detector for ion chromatography and a refractive index detector for high-performance liquid chromatography were used as reference detectors.http://www.sciencedirect.com/science/article/pii/S2214180424000278Split-ring resonatorEquivalent circuitLiquid chromatographyIon chromatography
spellingShingle Kirsten J. Dehning
Moritz Hitzemann
Stefan Zimmermann
Split-ring resonator with interdigital Split electrodes as detector for liquid and ion chromatography
Sensing and Bio-Sensing Research
Split-ring resonator
Equivalent circuit
Liquid chromatography
Ion chromatography
title Split-ring resonator with interdigital Split electrodes as detector for liquid and ion chromatography
title_full Split-ring resonator with interdigital Split electrodes as detector for liquid and ion chromatography
title_fullStr Split-ring resonator with interdigital Split electrodes as detector for liquid and ion chromatography
title_full_unstemmed Split-ring resonator with interdigital Split electrodes as detector for liquid and ion chromatography
title_short Split-ring resonator with interdigital Split electrodes as detector for liquid and ion chromatography
title_sort split ring resonator with interdigital split electrodes as detector for liquid and ion chromatography
topic Split-ring resonator
Equivalent circuit
Liquid chromatography
Ion chromatography
url http://www.sciencedirect.com/science/article/pii/S2214180424000278
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AT moritzhitzemann splitringresonatorwithinterdigitalsplitelectrodesasdetectorforliquidandionchromatography
AT stefanzimmermann splitringresonatorwithinterdigitalsplitelectrodesasdetectorforliquidandionchromatography