Degradation of patent blue V using cavity-bubble oxidation reactor induced by glass balls
A cavity-bubble oxidation reactor was used to study the degradation of patent blue V. The generation of cavity-bubbles by glass balls and flow-rate-induced jet were the degradation mechanisms used in this reactor. Initially, basic operating parameters were optimized by varying the initial concentrat...
Main Authors: | , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Iranian Research Organization for Science and Technology (IROST)
2023-01-01
|
Series: | Advances in Environmental Technology |
Subjects: | |
Online Access: | https://aet.irost.ir/article_1225_8adfd29b164f566a83413d601d75a47a.pdf |
_version_ | 1797789983410487296 |
---|---|
author | Manisha Bagal Mayur Malusare Kunal Ranjane Ashish Mohod |
author_facet | Manisha Bagal Mayur Malusare Kunal Ranjane Ashish Mohod |
author_sort | Manisha Bagal |
collection | DOAJ |
description | A cavity-bubble oxidation reactor was used to study the degradation of patent blue V. The generation of cavity-bubbles by glass balls and flow-rate-induced jet were the degradation mechanisms used in this reactor. Initially, basic operating parameters were optimized by varying the initial concentration (10–40 ppm) and solution pH 2–12. The extent of degradation (22.6%) at 20 ppm was reduced to 11.4% when the initial concentration was increased to 40 ppm. Following that, combined treatment strategies for process intensification of the degradation process were investigated. It was found that lower initial concentrations and acidic conditions favored the degradation of patent blue V. Under the optimal conditions of a concentration of 20 ppm and a pH of 2, the combined effect of the cavity-bubble oxidation reactor and chemical oxidation processes, such as hydrogen peroxide, gave a 95.38% extent of degradation at optimum H2O2 loading (2.5 g/L), which was 4.5 times greater than that obtained using cavity bubble oxidation reactors alone. The highest degree of degradation (98.48%) was achieved with a cavity-bubble oxidation reactor coupled with an optimum loading of the Fenton reagent (0.125 g/L FeSO4 and 2.5 g/L hydrogen peroxide). With the exception of the Fenton process, the kinetic analysis revealed that the degradation of patent blue V followed first-order reaction kinetics in all cases. |
first_indexed | 2024-03-13T01:58:18Z |
format | Article |
id | doaj.art-61cb9694b6ce4fb791e5099f730b15b6 |
institution | Directory Open Access Journal |
issn | 2476-6674 2476-4779 |
language | English |
last_indexed | 2024-03-13T01:58:18Z |
publishDate | 2023-01-01 |
publisher | Iranian Research Organization for Science and Technology (IROST) |
record_format | Article |
series | Advances in Environmental Technology |
spelling | doaj.art-61cb9694b6ce4fb791e5099f730b15b62023-07-02T08:57:43ZengIranian Research Organization for Science and Technology (IROST)Advances in Environmental Technology2476-66742476-47792023-01-0191173110.22104/aet.2022.5701.15561225Degradation of patent blue V using cavity-bubble oxidation reactor induced by glass ballsManisha Bagal0Mayur Malusare1Kunal Ranjane2Ashish Mohod3Department of Chemical Engineering, Bharati Vidyapeeth College of Engineering, Navi Mumbai, IndiaDepartment of Chemical Engineering, AISSMS College of Engineering, Maharashtra, IndiaDepartment of Chemical Engineering, AISSMS College of Engineering, Maharashtra, IndiaDepartment of Chemical Engineering, AISSMS College of Engineering, Maharashtra, IndiaA cavity-bubble oxidation reactor was used to study the degradation of patent blue V. The generation of cavity-bubbles by glass balls and flow-rate-induced jet were the degradation mechanisms used in this reactor. Initially, basic operating parameters were optimized by varying the initial concentration (10–40 ppm) and solution pH 2–12. The extent of degradation (22.6%) at 20 ppm was reduced to 11.4% when the initial concentration was increased to 40 ppm. Following that, combined treatment strategies for process intensification of the degradation process were investigated. It was found that lower initial concentrations and acidic conditions favored the degradation of patent blue V. Under the optimal conditions of a concentration of 20 ppm and a pH of 2, the combined effect of the cavity-bubble oxidation reactor and chemical oxidation processes, such as hydrogen peroxide, gave a 95.38% extent of degradation at optimum H2O2 loading (2.5 g/L), which was 4.5 times greater than that obtained using cavity bubble oxidation reactors alone. The highest degree of degradation (98.48%) was achieved with a cavity-bubble oxidation reactor coupled with an optimum loading of the Fenton reagent (0.125 g/L FeSO4 and 2.5 g/L hydrogen peroxide). With the exception of the Fenton process, the kinetic analysis revealed that the degradation of patent blue V followed first-order reaction kinetics in all cases.https://aet.irost.ir/article_1225_8adfd29b164f566a83413d601d75a47a.pdffentoncavitationpatent blue vprocess intensificationadvanced oxidation process |
spellingShingle | Manisha Bagal Mayur Malusare Kunal Ranjane Ashish Mohod Degradation of patent blue V using cavity-bubble oxidation reactor induced by glass balls Advances in Environmental Technology fenton cavitation patent blue v process intensification advanced oxidation process |
title | Degradation of patent blue V using cavity-bubble oxidation reactor induced by glass balls |
title_full | Degradation of patent blue V using cavity-bubble oxidation reactor induced by glass balls |
title_fullStr | Degradation of patent blue V using cavity-bubble oxidation reactor induced by glass balls |
title_full_unstemmed | Degradation of patent blue V using cavity-bubble oxidation reactor induced by glass balls |
title_short | Degradation of patent blue V using cavity-bubble oxidation reactor induced by glass balls |
title_sort | degradation of patent blue v using cavity bubble oxidation reactor induced by glass balls |
topic | fenton cavitation patent blue v process intensification advanced oxidation process |
url | https://aet.irost.ir/article_1225_8adfd29b164f566a83413d601d75a47a.pdf |
work_keys_str_mv | AT manishabagal degradationofpatentbluevusingcavitybubbleoxidationreactorinducedbyglassballs AT mayurmalusare degradationofpatentbluevusingcavitybubbleoxidationreactorinducedbyglassballs AT kunalranjane degradationofpatentbluevusingcavitybubbleoxidationreactorinducedbyglassballs AT ashishmohod degradationofpatentbluevusingcavitybubbleoxidationreactorinducedbyglassballs |