SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTC
Ni-BTC (BTC = 1,3,5-benzene tricarboxylate) metal organic framework (MOF) was synthesized using different solvent conditions. Solvent mixtures of water/N,N-dimethylformamide (DMF), water/ethanol, and water/ethanol/DMF were used for the reactions with or without a variety of bases at 160 ºC for 48 ho...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Sociedade Brasileira de Química
2016-07-01
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| Series: | Química Nova |
| Subjects: | |
| Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422016000600669&lng=en&tlng=en |
| _version_ | 1811232479453904896 |
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| author | Farrukh Israr Duk Kyung Kim Yeongmin Kim Wongee Chun |
| author_facet | Farrukh Israr Duk Kyung Kim Yeongmin Kim Wongee Chun |
| author_sort | Farrukh Israr |
| collection | DOAJ |
| description | Ni-BTC (BTC = 1,3,5-benzene tricarboxylate) metal organic framework (MOF) was synthesized using different solvent conditions. Solvent mixtures of water/N,N-dimethylformamide (DMF), water/ethanol, and water/ethanol/DMF were used for the reactions with or without a variety of bases at 160 ºC for 48 hours. Even with same green crystals, prepared MOFs show all different BET surface areas and different XRD patterns. The highest BET surface area of the crystals was 850 m2/g obtained from water/DMF solvent with NH4OH as a base. The measured surface areas of the crystals follows the order of Ni-BTC(water/DMF-NH4OH) > Ni-BTC(water/DMF-TMA) > Ni-BTC(water/DMF) > Ni-BTC(water/DMF-Pyridine)> Ni-BTC(water/ethanol)> Ni-BTC(water/DMF-aniline)> Ni-BTC(water/DMF-NaOH). |
| first_indexed | 2024-04-12T11:03:28Z |
| format | Article |
| id | doaj.art-61e5ec001ccd4499aa9394ff7f86ca83 |
| institution | Directory Open Access Journal |
| issn | 1678-7064 |
| language | English |
| last_indexed | 2024-04-12T11:03:28Z |
| publishDate | 2016-07-01 |
| publisher | Sociedade Brasileira de Química |
| record_format | Article |
| series | Química Nova |
| spelling | doaj.art-61e5ec001ccd4499aa9394ff7f86ca832022-12-22T03:35:51ZengSociedade Brasileira de QuímicaQuímica Nova1678-70642016-07-0139666967510.5935/0100-4042.20160068S0100-40422016000600669SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTCFarrukh IsrarDuk Kyung KimYeongmin KimWongee ChunNi-BTC (BTC = 1,3,5-benzene tricarboxylate) metal organic framework (MOF) was synthesized using different solvent conditions. Solvent mixtures of water/N,N-dimethylformamide (DMF), water/ethanol, and water/ethanol/DMF were used for the reactions with or without a variety of bases at 160 ºC for 48 hours. Even with same green crystals, prepared MOFs show all different BET surface areas and different XRD patterns. The highest BET surface area of the crystals was 850 m2/g obtained from water/DMF solvent with NH4OH as a base. The measured surface areas of the crystals follows the order of Ni-BTC(water/DMF-NH4OH) > Ni-BTC(water/DMF-TMA) > Ni-BTC(water/DMF) > Ni-BTC(water/DMF-Pyridine)> Ni-BTC(water/ethanol)> Ni-BTC(water/DMF-aniline)> Ni-BTC(water/DMF-NaOH).http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422016000600669&lng=en&tlng=enNi-BTC MOFdifferent solvent conditionsbasesdifferent BETs |
| spellingShingle | Farrukh Israr Duk Kyung Kim Yeongmin Kim Wongee Chun SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTC Química Nova Ni-BTC MOF different solvent conditions bases different BETs |
| title | SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTC |
| title_full | SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTC |
| title_fullStr | SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTC |
| title_full_unstemmed | SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTC |
| title_short | SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTC |
| title_sort | scope of various solvents and their effects on solvothermal synthesis of ni btc |
| topic | Ni-BTC MOF different solvent conditions bases different BETs |
| url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422016000600669&lng=en&tlng=en |
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