Parameterizations of US wildfire and prescribed fire emission ratios and emission factors based on FIREX-AQ aircraft measurements

Parameterizations of US wildfire and prescribed fire emission ratios and emission factors based on FIREX-AQ aircraft measurements

<p>Extensive airborne measurements of non-methane organic gases (NMOGs), methane, nitrogen oxides, reduced nitrogen species, and aerosol emissions from US wild and prescribed fires were conducted during the 2019 NOAA/NASA Fire Influence on Regional to Global Environments and Air Quality campai...

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Main Authors: G. I. Gkatzelis, M. M. Coggon, C. E. Stockwell, R. S. Hornbrook, H. Allen, E. C. Apel, M. M. Bela, D. R. Blake, I. Bourgeois, S. S. Brown, P. Campuzano-Jost, J. M. St. Clair, J. H. Crawford, J. D. Crounse, D. A. Day, J. P. DiGangi, G. S. Diskin, A. Fried, J. B. Gilman, H. Guo, J. W. Hair, H. S. Halliday, T. F. Hanisco, R. Hannun, A. Hills, L. G. Huey, J. L. Jimenez, J. M. Katich, A. Lamplugh, Y. R. Lee, J. Liao, J. Lindaas, S. A. McKeen, T. Mikoviny, B. A. Nault, J. A. Neuman, J. B. Nowak, D. Pagonis, J. Peischl, A. E. Perring, F. Piel, P. S. Rickly, M. A. Robinson, A. W. Rollins, T. B. Ryerson, M. K. Schueneman, R. H. Schwantes, J. P. Schwarz, K. Sekimoto, V. Selimovic, T. Shingler, D. J. Tanner, L. Tomsche, K. T. Vasquez, P. R. Veres, R. Washenfelder, P. Weibring, P. O. Wennberg, A. Wisthaler, G. M. Wolfe, C. C. Womack, L. Xu, K. Ball, R. J. Yokelson, C. Warneke
Format: Article
Language:English
Published: Copernicus Publications 2024-01-01
Series:Atmospheric Chemistry and Physics
Online Access:https://acp.copernicus.org/articles/24/929/2024/acp-24-929-2024.pdf
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Summary:<p>Extensive airborne measurements of non-methane organic gases (NMOGs), methane, nitrogen oxides, reduced nitrogen species, and aerosol emissions from US wild and prescribed fires were conducted during the 2019 NOAA/NASA Fire Influence on Regional to Global Environments and Air Quality campaign (FIREX-AQ). Here, we report the atmospheric enhancement ratios (ERs) and inferred emission factors (EFs) for compounds measured on board the NASA DC-8 research aircraft for nine wildfires and one prescribed fire, which encompass a range of vegetation types.</p> <p>We use photochemical proxies to identify young smoke and reduce the effects of chemical degradation on our emissions calculations. ERs and EFs calculated from FIREX-AQ observations agree within a factor of 2, with values reported from previous laboratory and field studies for more than 80 % of the carbon- and nitrogen-containing species. Wildfire emissions are parameterized based on correlations of the sum of NMOGs with reactive nitrogen oxides (NO<span class="inline-formula"><sub><i>y</i></sub></span>) to modified combustion efficiency (MCE) as well as other chemical signatures indicative of flaming/smoldering combustion, including carbon monoxide (CO), nitrogen dioxide (NO<span class="inline-formula"><sub>2</sub></span>), and black carbon aerosol. The sum of primary NMOG EFs correlates to MCE with an <span class="inline-formula"><i>R</i><sup>2</sup></span> of 0.68 and a slope of <span class="inline-formula">−</span>296 <span class="inline-formula">±</span> 51 g kg<span class="inline-formula"><sup>−1</sup></span>, consistent with previous studies. The sum of the NMOG mixing ratios correlates well with CO with an <span class="inline-formula"><i>R</i><sup>2</sup></span> of 0.98 and a slope of 137 <span class="inline-formula">±</span> 4 ppbv of NMOGs per parts per million by volume (ppmv) of CO, demonstrating that primary NMOG emissions can be estimated from CO. Individual nitrogen-containing species correlate better with NO<span class="inline-formula"><sub>2</sub></span>, NO<span class="inline-formula"><sub><i>y</i></sub></span>, and black carbon than with CO. More than half of the NO<span class="inline-formula"><sub><i>y</i></sub></span> in fresh plumes is NO<span class="inline-formula"><sub>2</sub></span> with an <span class="inline-formula"><i>R</i><sup>2</sup></span> of 0.95 and a ratio of NO<span class="inline-formula"><sub>2</sub></span> to NO<span class="inline-formula"><sub><i>y</i></sub></span> of 0.55 <span class="inline-formula">±</span> 0.05 ppbv ppbv<span class="inline-formula"><sup>−1</sup></span>, highlighting that fast photochemistry had already occurred in the sampled fire plumes. The ratio of NO<span class="inline-formula"><sub><i>y</i></sub></span> to the sum of NMOGs follows trends observed in laboratory experiments and increases exponentially with MCE, due to increased emission of key nitrogen species and reduced emission of NMOGs at higher MCE during flaming combustion. These parameterizations will provide more accurate boundary conditions for modeling and satellite studies of fire plume chemistry and evolution to predict the downwind formation of secondary pollutants, including ozone and secondary organic aerosol.</p>
ISSN:1680-7316
1680-7324

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