Bis(nitrato-κO)tetrakis[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one]copper(II)
In the title complex, [Cu(NO3)2(C11H11N3O)4], the CuII atom is situated on a centre of inversion and is coordinated by two O atoms from two nitrate anions and four N atoms from four monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands in a distorted octahedral geometry. Weak intermolec...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681103529X |
| _version_ | 1819278254372028416 |
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| author | Yao Wu Jian-Gang Li Ying Guo Hua Cai |
| author_facet | Yao Wu Jian-Gang Li Ying Guo Hua Cai |
| author_sort | Yao Wu |
| collection | DOAJ |
| description | In the title complex, [Cu(NO3)2(C11H11N3O)4], the CuII atom is situated on a centre of inversion and is coordinated by two O atoms from two nitrate anions and four N atoms from four monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands in a distorted octahedral geometry. Weak intermolecular C—H...O and C—H...N hydrogen bonds result in a supramolecular layer parallel to (101). These layers are connected by π–π interactions between the benzene rings [centroid–centroid distance = 3.891 (2) Å]. |
| first_indexed | 2024-12-24T00:09:05Z |
| format | Article |
| id | doaj.art-61f93595545b409e9b5500d4b2031431 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:09:05Z |
| publishDate | 2011-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-61f93595545b409e9b5500d4b20314312022-12-21T17:24:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-10-016710m1385m138510.1107/S160053681103529XBis(nitrato-κO)tetrakis[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one]copper(II)Yao WuJian-Gang LiYing GuoHua CaiIn the title complex, [Cu(NO3)2(C11H11N3O)4], the CuII atom is situated on a centre of inversion and is coordinated by two O atoms from two nitrate anions and four N atoms from four monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands in a distorted octahedral geometry. Weak intermolecular C—H...O and C—H...N hydrogen bonds result in a supramolecular layer parallel to (101). These layers are connected by π–π interactions between the benzene rings [centroid–centroid distance = 3.891 (2) Å].http://scripts.iucr.org/cgi-bin/paper?S160053681103529X |
| spellingShingle | Yao Wu Jian-Gang Li Ying Guo Hua Cai Bis(nitrato-κO)tetrakis[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one]copper(II) Acta Crystallographica Section E |
| title | Bis(nitrato-κO)tetrakis[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one]copper(II) |
| title_full | Bis(nitrato-κO)tetrakis[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one]copper(II) |
| title_fullStr | Bis(nitrato-κO)tetrakis[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one]copper(II) |
| title_full_unstemmed | Bis(nitrato-κO)tetrakis[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one]copper(II) |
| title_short | Bis(nitrato-κO)tetrakis[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one]copper(II) |
| title_sort | bis nitrato amp 954 o tetrakis 1 phenyl 3 1h 1 2 4 triazol 1 yl propan 1 one copper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681103529X |
| work_keys_str_mv | AT yaowu bisnitratoamp954otetrakis1phenyl31h124triazol1ylpropan1onecopperii AT jiangangli bisnitratoamp954otetrakis1phenyl31h124triazol1ylpropan1onecopperii AT yingguo bisnitratoamp954otetrakis1phenyl31h124triazol1ylpropan1onecopperii AT huacai bisnitratoamp954otetrakis1phenyl31h124triazol1ylpropan1onecopperii |