(S)-Alanine–(S)-2-phenoxypropionic acid (1/1)
In the title co-crystal, C3H7NO2·C9H10O3, the (S)-alanine molecule exists in the zwitterionic form stabilized by two pairs of N+—H...O− hydrogen bonds and an electrostatic interaction between the ammonium center and the carboxylate anion, forming a sheet alon...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812020727 |
| _version_ | 1828425745140023296 |
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| author | Kiichi Amimoto Yuma Nishioka |
| author_facet | Kiichi Amimoto Yuma Nishioka |
| author_sort | Kiichi Amimoto |
| collection | DOAJ |
| description | In the title co-crystal, C3H7NO2·C9H10O3, the (S)-alanine molecule exists in the zwitterionic form stabilized by two pairs of N+—H...O− hydrogen bonds and an electrostatic interaction between the ammonium center and the carboxylate anion, forming a sheet along the ab plane. The carboxyl group of the (S)-2-phenoxypropionic acid molecule is connected to the top and bottom of the sheet via N+—H...O=C and O—H...O− [R22(7) graph set] hydrogen bonds, giving an (S,S)-homochiral layer, in which both methyl groups of (S)-alanine and the phenyl rings of (S)-2-phenoxypropionic acid are oriented in the same direction along the b axis. |
| first_indexed | 2024-12-10T16:35:46Z |
| format | Article |
| id | doaj.art-620c095dab674510917a10afcceff643 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T16:35:46Z |
| publishDate | 2012-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-620c095dab674510917a10afcceff6432022-12-22T01:41:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686o1720o172010.1107/S1600536812020727(S)-Alanine–(S)-2-phenoxypropionic acid (1/1)Kiichi AmimotoYuma NishiokaIn the title co-crystal, C3H7NO2·C9H10O3, the (S)-alanine molecule exists in the zwitterionic form stabilized by two pairs of N+—H...O− hydrogen bonds and an electrostatic interaction between the ammonium center and the carboxylate anion, forming a sheet along the ab plane. The carboxyl group of the (S)-2-phenoxypropionic acid molecule is connected to the top and bottom of the sheet via N+—H...O=C and O—H...O− [R22(7) graph set] hydrogen bonds, giving an (S,S)-homochiral layer, in which both methyl groups of (S)-alanine and the phenyl rings of (S)-2-phenoxypropionic acid are oriented in the same direction along the b axis.http://scripts.iucr.org/cgi-bin/paper?S1600536812020727 |
| spellingShingle | Kiichi Amimoto Yuma Nishioka (S)-Alanine–(S)-2-phenoxypropionic acid (1/1) Acta Crystallographica Section E |
| title | (S)-Alanine–(S)-2-phenoxypropionic acid (1/1) |
| title_full | (S)-Alanine–(S)-2-phenoxypropionic acid (1/1) |
| title_fullStr | (S)-Alanine–(S)-2-phenoxypropionic acid (1/1) |
| title_full_unstemmed | (S)-Alanine–(S)-2-phenoxypropionic acid (1/1) |
| title_short | (S)-Alanine–(S)-2-phenoxypropionic acid (1/1) |
| title_sort | s alanine amp 8211 s 2 phenoxypropionic acid 1 1 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812020727 |
| work_keys_str_mv | AT kiichiamimoto salanineamp8211s2phenoxypropionicacid11 AT yumanishioka salanineamp8211s2phenoxypropionicacid11 |