Solid and liquid supramolecular complexes by solid-solid mechanosynthesis
Green mechanosynthesis, free solvent, has been used for preparing a series of supramolecular complexes. Through directional hydrogen bonds and π-cation interaction can be prepared complexes with different states of aggregation of matter, where stoichiometry plays an essential role. When the stoichio...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2019-12-01
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| Series: | Arabian Journal of Chemistry |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S1878535216301289 |
| _version_ | 1819084188646637568 |
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| author | Ricardo Cerón-Camacho Rodolfo Cisneros-Dévora Enrique Soto-Castruita Mirna Pons-Jiménez Hiram I. Beltrán José-Manuel Martínez-Magadán Luis S. Zamudio-Rivera |
| author_facet | Ricardo Cerón-Camacho Rodolfo Cisneros-Dévora Enrique Soto-Castruita Mirna Pons-Jiménez Hiram I. Beltrán José-Manuel Martínez-Magadán Luis S. Zamudio-Rivera |
| author_sort | Ricardo Cerón-Camacho |
| collection | DOAJ |
| description | Green mechanosynthesis, free solvent, has been used for preparing a series of supramolecular complexes. Through directional hydrogen bonds and π-cation interaction can be prepared complexes with different states of aggregation of matter, where stoichiometry plays an essential role. When the stoichiometric ratio between the two compounds was 1:1, a solid product is obtained. But, when the ratio is higher, products are obtained as gel or paste to reach low viscosity liquids. Also, the structure of such complexes that form three-dimensional aggregates between C12TAC and phenol derivatives can explain the different aggregation states for final products and this may be the key to understand the viscosity reduction mechanism. Keywords: Supramolecular complex, Mechanosynthesis, Hydrogen bond, Π-cation interactions, Change of physical state |
| first_indexed | 2024-12-21T20:44:30Z |
| format | Article |
| id | doaj.art-622ba319df9c40969140c4a5f864c621 |
| institution | Directory Open Access Journal |
| issn | 1878-5352 |
| language | English |
| last_indexed | 2024-12-21T20:44:30Z |
| publishDate | 2019-12-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Arabian Journal of Chemistry |
| spelling | doaj.art-622ba319df9c40969140c4a5f864c6212022-12-21T18:50:51ZengElsevierArabian Journal of Chemistry1878-53522019-12-0112846644674Solid and liquid supramolecular complexes by solid-solid mechanosynthesisRicardo Cerón-Camacho0Rodolfo Cisneros-Dévora1Enrique Soto-Castruita2Mirna Pons-Jiménez3Hiram I. Beltrán4José-Manuel Martínez-Magadán5Luis S. Zamudio-Rivera6CONACYT – Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas 152, Col. San Bartolo Atepehuacan, D.F. 07730, Mexico; Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas 152, Col. San Bartolo Atepehuacan, Mexico City 07730, Mexico; Corresponding authors at: Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas 152, Col. San Bartolo Atepehuacan, Mexico City 07730, Mexico (R. Cerón-Camacho).CONACYT – Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas 152, Col. San Bartolo Atepehuacan, D.F. 07730, Mexico; Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas 152, Col. San Bartolo Atepehuacan, Mexico City 07730, MexicoCONACYT – Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas 152, Col. San Bartolo Atepehuacan, D.F. 07730, Mexico; Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas 152, Col. San Bartolo Atepehuacan, Mexico City 07730, MexicoDivisión Académica de Ciencias Básicas e Ingeniería, Universidad Popular de la Chontalpa, Carretera Cárdenas-Huimanguillo Km. 2, Ranchería Paso y Playa, Heróica Cárdenas, Tabasco 86500, MexicoDepartamento de Ciencias Naturales, Universidad Autónoma Metropolitana Cuajimalpa, Av. Vasco de Quiroga 4871, Col. Santa Fe Cuajimalpa, Cuajimalpa de Morelos, D. F. 05300, MexicoInstituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas 152, Col. San Bartolo Atepehuacan, Mexico City 07730, MexicoInstituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas 152, Col. San Bartolo Atepehuacan, Mexico City 07730, Mexico; Corresponding authors at: Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas 152, Col. San Bartolo Atepehuacan, Mexico City 07730, Mexico (R. Cerón-Camacho).Green mechanosynthesis, free solvent, has been used for preparing a series of supramolecular complexes. Through directional hydrogen bonds and π-cation interaction can be prepared complexes with different states of aggregation of matter, where stoichiometry plays an essential role. When the stoichiometric ratio between the two compounds was 1:1, a solid product is obtained. But, when the ratio is higher, products are obtained as gel or paste to reach low viscosity liquids. Also, the structure of such complexes that form three-dimensional aggregates between C12TAC and phenol derivatives can explain the different aggregation states for final products and this may be the key to understand the viscosity reduction mechanism. Keywords: Supramolecular complex, Mechanosynthesis, Hydrogen bond, Π-cation interactions, Change of physical statehttp://www.sciencedirect.com/science/article/pii/S1878535216301289 |
| spellingShingle | Ricardo Cerón-Camacho Rodolfo Cisneros-Dévora Enrique Soto-Castruita Mirna Pons-Jiménez Hiram I. Beltrán José-Manuel Martínez-Magadán Luis S. Zamudio-Rivera Solid and liquid supramolecular complexes by solid-solid mechanosynthesis Arabian Journal of Chemistry |
| title | Solid and liquid supramolecular complexes by solid-solid mechanosynthesis |
| title_full | Solid and liquid supramolecular complexes by solid-solid mechanosynthesis |
| title_fullStr | Solid and liquid supramolecular complexes by solid-solid mechanosynthesis |
| title_full_unstemmed | Solid and liquid supramolecular complexes by solid-solid mechanosynthesis |
| title_short | Solid and liquid supramolecular complexes by solid-solid mechanosynthesis |
| title_sort | solid and liquid supramolecular complexes by solid solid mechanosynthesis |
| url | http://www.sciencedirect.com/science/article/pii/S1878535216301289 |
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