3,5-Bis(3-butylimidazolium-1-ylmethyl)toluene bis(hexafluorophosphate)
In the title compound [systematic name: 3,3′-Dibutyl-1,1′-(5-methyl-m-phenylenedimethylene)diimidazol-1-ium bis(hexafluoridophosphate)], C23H34N42+·2PF6−, the imidazole rings are inclined at angles of 68.06 (7) and 75.05&#8...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810040055 |
| _version_ | 1819281242020904960 |
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| author | Rosenani A. Haque Abbas Washeel Siang Guan Teoh Ching Kheng Quah Hoong-Kun Fun |
| author_facet | Rosenani A. Haque Abbas Washeel Siang Guan Teoh Ching Kheng Quah Hoong-Kun Fun |
| author_sort | Rosenani A. Haque |
| collection | DOAJ |
| description | In the title compound [systematic name: 3,3′-Dibutyl-1,1′-(5-methyl-m-phenylenedimethylene)diimidazol-1-ium bis(hexafluoridophosphate)], C23H34N42+·2PF6−, the imidazole rings are inclined at angles of 68.06 (7) and 75.05 (8)° with respect to the central benzene ring. In the crystal, molecules are linked into one-dimensional columns along [010] via weak intermolecular C—H...F hydrogen bonds. The crystal structure is further consolidated by weak C—H...π(arene) interactions. One of the n-butyl groups is disordered over two sites with refined occupancies of 0.694 (5) and 0.306 (5). In addition, four of the F atoms of one of the PF6− cations are disordered over two sites with occupancies of 0.64 (3) and 0.36 (3). |
| first_indexed | 2024-12-24T00:56:34Z |
| format | Article |
| id | doaj.art-62340812bbb14bbfa44979ead33521d8 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:56:34Z |
| publishDate | 2010-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-62340812bbb14bbfa44979ead33521d82022-12-21T17:23:28ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-11-016611o2797o279810.1107/S16005368100400553,5-Bis(3-butylimidazolium-1-ylmethyl)toluene bis(hexafluorophosphate)Rosenani A. HaqueAbbas WasheelSiang Guan TeohChing Kheng QuahHoong-Kun FunIn the title compound [systematic name: 3,3′-Dibutyl-1,1′-(5-methyl-m-phenylenedimethylene)diimidazol-1-ium bis(hexafluoridophosphate)], C23H34N42+·2PF6−, the imidazole rings are inclined at angles of 68.06 (7) and 75.05 (8)° with respect to the central benzene ring. In the crystal, molecules are linked into one-dimensional columns along [010] via weak intermolecular C—H...F hydrogen bonds. The crystal structure is further consolidated by weak C—H...π(arene) interactions. One of the n-butyl groups is disordered over two sites with refined occupancies of 0.694 (5) and 0.306 (5). In addition, four of the F atoms of one of the PF6− cations are disordered over two sites with occupancies of 0.64 (3) and 0.36 (3).http://scripts.iucr.org/cgi-bin/paper?S1600536810040055 |
| spellingShingle | Rosenani A. Haque Abbas Washeel Siang Guan Teoh Ching Kheng Quah Hoong-Kun Fun 3,5-Bis(3-butylimidazolium-1-ylmethyl)toluene bis(hexafluorophosphate) Acta Crystallographica Section E |
| title | 3,5-Bis(3-butylimidazolium-1-ylmethyl)toluene bis(hexafluorophosphate) |
| title_full | 3,5-Bis(3-butylimidazolium-1-ylmethyl)toluene bis(hexafluorophosphate) |
| title_fullStr | 3,5-Bis(3-butylimidazolium-1-ylmethyl)toluene bis(hexafluorophosphate) |
| title_full_unstemmed | 3,5-Bis(3-butylimidazolium-1-ylmethyl)toluene bis(hexafluorophosphate) |
| title_short | 3,5-Bis(3-butylimidazolium-1-ylmethyl)toluene bis(hexafluorophosphate) |
| title_sort | 3 5 bis 3 butylimidazolium 1 ylmethyl toluene bis hexafluorophosphate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810040055 |
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