Challenging the Kauzmann paradox using an ultra-stable perfluoropolymer glass with a fictive temperature below the dynamic VFT temperature
Abstract Ultra-stable fluoropolymer glasses were created using vacuum pyrolysis deposition that show large fictive temperature Tf reductions relative to the glass transition temperature Tg of the rejuvenated material. Tf was also found to be 11.4 K below the dynamic VFT temperature TVFT. Glass films...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2023-03-01
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| Series: | Scientific Reports |
| Online Access: | https://doi.org/10.1038/s41598-023-31074-0 |