Efficient Fluoride Wastewater Treatment Using Eco-Friendly Synthesized AlOOH

Fluoride ion is essential for health in small amounts, but excessive intake can be toxic. Meeting safety regulations for managing fluoride ion emissions from industrial facilities with both cost-effective and eco-friendly approaches is challenging. This study presents a solution through a chemical-f...

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Main Authors: Wan-Tae Kim, Joo-Won Lee, Hong-Eun An, So-Hye Cho, Sohee Jeong
Format: Article
Language:English
Published: MDPI AG 2023-10-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/13/21/2838
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author Wan-Tae Kim
Joo-Won Lee
Hong-Eun An
So-Hye Cho
Sohee Jeong
author_facet Wan-Tae Kim
Joo-Won Lee
Hong-Eun An
So-Hye Cho
Sohee Jeong
author_sort Wan-Tae Kim
collection DOAJ
description Fluoride ion is essential for health in small amounts, but excessive intake can be toxic. Meeting safety regulations for managing fluoride ion emissions from industrial facilities with both cost-effective and eco-friendly approaches is challenging. This study presents a solution through a chemical-free process, producing a boehmite (AlOOH) adsorbent on aluminum sheets. Utilizing cost-effective Al foil and DI water, rather than typical precursors, yields a substantial cost advantage. The optimized AlOOH adsorbent demonstrated a high fluoride ion removal rate of 91.0% in simulated wastewater with fluoride ion concentrations below 20 ppm and displayed a similar performance in industrial wastewater. Furthermore, the AlOOH adsorbent exhibited excellent reusability through a simple regeneration process and maintained stable performance across a wide pH range of 4 to 11, demonstrating its capability to adsorb fluoride ions under diverse conditions. The efficiency of the AlOOH adsorbent was validated by a high fluoride ion removal efficiency of 90.9% in a semi-batch mode flow cell, highlighting its potential applicability in engineered water treatment systems. Overall, the AlOOH adsorbent developed in this study offers a cost-effective, eco-friendly, and sustainable solution for effectively removing fluoride ion from surface waters and industrial wastewaters.
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spelling doaj.art-627f2f32c3f243b4ba656e8f47aaec132023-11-10T15:09:07ZengMDPI AGNanomaterials2079-49912023-10-011321283810.3390/nano13212838Efficient Fluoride Wastewater Treatment Using Eco-Friendly Synthesized AlOOHWan-Tae Kim0Joo-Won Lee1Hong-Eun An2So-Hye Cho3Sohee Jeong4Materials Architecturing Research Center, Korea Institute of Science and Technology, Seoul 02792, Republic of KoreaMaterials Architecturing Research Center, Korea Institute of Science and Technology, Seoul 02792, Republic of KoreaMaterials Architecturing Research Center, Korea Institute of Science and Technology, Seoul 02792, Republic of KoreaMaterials Architecturing Research Center, Korea Institute of Science and Technology, Seoul 02792, Republic of KoreaMaterials Architecturing Research Center, Korea Institute of Science and Technology, Seoul 02792, Republic of KoreaFluoride ion is essential for health in small amounts, but excessive intake can be toxic. Meeting safety regulations for managing fluoride ion emissions from industrial facilities with both cost-effective and eco-friendly approaches is challenging. This study presents a solution through a chemical-free process, producing a boehmite (AlOOH) adsorbent on aluminum sheets. Utilizing cost-effective Al foil and DI water, rather than typical precursors, yields a substantial cost advantage. The optimized AlOOH adsorbent demonstrated a high fluoride ion removal rate of 91.0% in simulated wastewater with fluoride ion concentrations below 20 ppm and displayed a similar performance in industrial wastewater. Furthermore, the AlOOH adsorbent exhibited excellent reusability through a simple regeneration process and maintained stable performance across a wide pH range of 4 to 11, demonstrating its capability to adsorb fluoride ions under diverse conditions. The efficiency of the AlOOH adsorbent was validated by a high fluoride ion removal efficiency of 90.9% in a semi-batch mode flow cell, highlighting its potential applicability in engineered water treatment systems. Overall, the AlOOH adsorbent developed in this study offers a cost-effective, eco-friendly, and sustainable solution for effectively removing fluoride ion from surface waters and industrial wastewaters.https://www.mdpi.com/2079-4991/13/21/2838AlOOHwastewaterfluoride ion removal
spellingShingle Wan-Tae Kim
Joo-Won Lee
Hong-Eun An
So-Hye Cho
Sohee Jeong
Efficient Fluoride Wastewater Treatment Using Eco-Friendly Synthesized AlOOH
Nanomaterials
AlOOH
wastewater
fluoride ion removal
title Efficient Fluoride Wastewater Treatment Using Eco-Friendly Synthesized AlOOH
title_full Efficient Fluoride Wastewater Treatment Using Eco-Friendly Synthesized AlOOH
title_fullStr Efficient Fluoride Wastewater Treatment Using Eco-Friendly Synthesized AlOOH
title_full_unstemmed Efficient Fluoride Wastewater Treatment Using Eco-Friendly Synthesized AlOOH
title_short Efficient Fluoride Wastewater Treatment Using Eco-Friendly Synthesized AlOOH
title_sort efficient fluoride wastewater treatment using eco friendly synthesized alooh
topic AlOOH
wastewater
fluoride ion removal
url https://www.mdpi.com/2079-4991/13/21/2838
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AT sohyecho efficientfluoridewastewatertreatmentusingecofriendlysynthesizedalooh
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