A modular approach to neutral P,N-ligands: synthesis and coordination chemistry
We report the modular synthesis of three different types of neutral κ2-P,N-ligands comprising an imine and a phosphine binding site. These ligands were reacted with rhodium, iridium and palladium metal precursors and the structures of the resulting complexes were elucidated by means of X-ray crystal...
| 主要な著者: | , , , , , |
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| フォーマット: | 論文 |
| 言語: | English |
| 出版事項: |
Beilstein-Institut
2016-04-01
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| シリーズ: | Beilstein Journal of Organic Chemistry |
| 主題: | |
| オンライン･アクセス: | https://doi.org/10.3762/bjoc.12.83 |
| 要約: | We report the modular synthesis of three different types of neutral κ2-P,N-ligands comprising an imine and a phosphine binding site. These ligands were reacted with rhodium, iridium and palladium metal precursors and the structures of the resulting complexes were elucidated by means of X-ray crystallography. We observed that subtle changes of the ligand backbone have a significant influence on the binding geometry und coordination properties of these bidentate P,N-donors. |
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| ISSN: | 1860-5397 |