Dibromo–Isonitrile and N-acyclic Carbene Complexes of Platinum(II): Synthesis and Reactivity
A series of dibromo-N-acyclic (NAC) carbene complexes of platinum(II) were synthesized, starting from <i>trans-</i>[Pt(μ-Br)Br(PPh<sub>3</sub>)]<sub>2</sub> and according to a protocol previously optimized for the preparation of analogous chlorinated compounds. In...
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| Format: | Article |
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MDPI AG
2023-03-01
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| Series: | Inorganics |
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| Online Access: | https://www.mdpi.com/2304-6740/11/4/137 |
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| author | Anna Farasat Francesca Nerli Luca Labella Marco Taddei Simona Samaritani |
| author_facet | Anna Farasat Francesca Nerli Luca Labella Marco Taddei Simona Samaritani |
| author_sort | Anna Farasat |
| collection | DOAJ |
| description | A series of dibromo-N-acyclic (NAC) carbene complexes of platinum(II) were synthesized, starting from <i>trans-</i>[Pt(μ-Br)Br(PPh<sub>3</sub>)]<sub>2</sub> and according to a protocol previously optimized for the preparation of analogous chlorinated compounds. In the first step of the synthesis, the ring opening of the dinuclear precursor was carried out using suitable isonitrile ligands, while the following step consisted of the addition of <i>N</i>,<i>N</i>-diethylamine to the products obtained in the first step. The two reactions were separately investigated, and attention was given to the differences between brominated and chlorinated systems. |
| first_indexed | 2024-03-11T04:55:06Z |
| format | Article |
| id | doaj.art-62ae03d1ade94ed681760290c416a68c |
| institution | Directory Open Access Journal |
| issn | 2304-6740 |
| language | English |
| last_indexed | 2024-03-11T04:55:06Z |
| publishDate | 2023-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Inorganics |
| spelling | doaj.art-62ae03d1ade94ed681760290c416a68c2023-11-17T19:45:07ZengMDPI AGInorganics2304-67402023-03-0111413710.3390/inorganics11040137Dibromo–Isonitrile and N-acyclic Carbene Complexes of Platinum(II): Synthesis and ReactivityAnna Farasat0Francesca Nerli1Luca Labella2Marco Taddei3Simona Samaritani4Department of Chemistry and Industrial Chemistry, University of Pisa, Via Giuseppe Moruzzi 13, 56124 Pisa, ItalyDepartment of Chemistry and Industrial Chemistry, University of Pisa, Via Giuseppe Moruzzi 13, 56124 Pisa, ItalyDepartment of Chemistry and Industrial Chemistry, University of Pisa, Via Giuseppe Moruzzi 13, 56124 Pisa, ItalyDepartment of Chemistry and Industrial Chemistry, University of Pisa, Via Giuseppe Moruzzi 13, 56124 Pisa, ItalyDepartment of Chemistry and Industrial Chemistry, University of Pisa, Via Giuseppe Moruzzi 13, 56124 Pisa, ItalyA series of dibromo-N-acyclic (NAC) carbene complexes of platinum(II) were synthesized, starting from <i>trans-</i>[Pt(μ-Br)Br(PPh<sub>3</sub>)]<sub>2</sub> and according to a protocol previously optimized for the preparation of analogous chlorinated compounds. In the first step of the synthesis, the ring opening of the dinuclear precursor was carried out using suitable isonitrile ligands, while the following step consisted of the addition of <i>N</i>,<i>N</i>-diethylamine to the products obtained in the first step. The two reactions were separately investigated, and attention was given to the differences between brominated and chlorinated systems.https://www.mdpi.com/2304-6740/11/4/137platinum(II) bromocomplexesisocyanide ligandscarbene ligandstriphenylphosphine |
| spellingShingle | Anna Farasat Francesca Nerli Luca Labella Marco Taddei Simona Samaritani Dibromo–Isonitrile and N-acyclic Carbene Complexes of Platinum(II): Synthesis and Reactivity Inorganics platinum(II) bromocomplexes isocyanide ligands carbene ligands triphenylphosphine |
| title | Dibromo–Isonitrile and N-acyclic Carbene Complexes of Platinum(II): Synthesis and Reactivity |
| title_full | Dibromo–Isonitrile and N-acyclic Carbene Complexes of Platinum(II): Synthesis and Reactivity |
| title_fullStr | Dibromo–Isonitrile and N-acyclic Carbene Complexes of Platinum(II): Synthesis and Reactivity |
| title_full_unstemmed | Dibromo–Isonitrile and N-acyclic Carbene Complexes of Platinum(II): Synthesis and Reactivity |
| title_short | Dibromo–Isonitrile and N-acyclic Carbene Complexes of Platinum(II): Synthesis and Reactivity |
| title_sort | dibromo isonitrile and n acyclic carbene complexes of platinum ii synthesis and reactivity |
| topic | platinum(II) bromocomplexes isocyanide ligands carbene ligands triphenylphosphine |
| url | https://www.mdpi.com/2304-6740/11/4/137 |
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