Recent Advances in Phthalocyanine and Porphyrin-Based Materials as Active Layers for Nitric Oxide Chemical Sensors

Nitric oxide (NO) is a highly reactive toxic gas that forms as an intermediate compound during the oxidation of ammonia and is used for the manufacture of hydroxylamine in the chemical industry. Moreover, NO is a signaling molecule in many physiological and pathological processes in mammals, as well...

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Main Authors: Darya Klyamer, Roman Shutilov, Tamara Basova
Format: Article
Language:English
Published: MDPI AG 2022-01-01
Series:Sensors
Subjects:
Online Access:https://www.mdpi.com/1424-8220/22/3/895
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author Darya Klyamer
Roman Shutilov
Tamara Basova
author_facet Darya Klyamer
Roman Shutilov
Tamara Basova
author_sort Darya Klyamer
collection DOAJ
description Nitric oxide (NO) is a highly reactive toxic gas that forms as an intermediate compound during the oxidation of ammonia and is used for the manufacture of hydroxylamine in the chemical industry. Moreover, NO is a signaling molecule in many physiological and pathological processes in mammals, as well as a biomarker indicating the course of inflammatory processes in the respiratory tract. For this reason, the detection of NO both in the gas phase and in the aqueous media is an important task. This review analyzes the state of research over the past ten years in the field of applications of phthalocyanines, porphyrins and their hybrid materials as active layers of chemical sensors for the detection of NO, with a primary focus on chemiresistive and electrochemical ones. The first part of the review is devoted to the study of phthalocyanines and porphyrins, as well as their hybrids for the NO detection in aqueous solutions and biological media. The second part presents an analysis of works describing the latest achievements in the field of studied materials as active layers of sensors for the determination of gaseous NO. It is expected that this review will further increase the interest of researchers who are engaged in the current level of evaluation and selection of modern materials for use in the chemical sensing of nitric oxide.
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spelling doaj.art-62c234b954144f49b207d440b28c02782023-11-23T17:47:09ZengMDPI AGSensors1424-82202022-01-0122389510.3390/s22030895Recent Advances in Phthalocyanine and Porphyrin-Based Materials as Active Layers for Nitric Oxide Chemical SensorsDarya Klyamer0Roman Shutilov1Tamara Basova2Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Lavrentiev Pr., 630090 Novosibirsk, RussiaNikolaev Institute of Inorganic Chemistry SB RAS, 3 Lavrentiev Pr., 630090 Novosibirsk, RussiaNikolaev Institute of Inorganic Chemistry SB RAS, 3 Lavrentiev Pr., 630090 Novosibirsk, RussiaNitric oxide (NO) is a highly reactive toxic gas that forms as an intermediate compound during the oxidation of ammonia and is used for the manufacture of hydroxylamine in the chemical industry. Moreover, NO is a signaling molecule in many physiological and pathological processes in mammals, as well as a biomarker indicating the course of inflammatory processes in the respiratory tract. For this reason, the detection of NO both in the gas phase and in the aqueous media is an important task. This review analyzes the state of research over the past ten years in the field of applications of phthalocyanines, porphyrins and their hybrid materials as active layers of chemical sensors for the detection of NO, with a primary focus on chemiresistive and electrochemical ones. The first part of the review is devoted to the study of phthalocyanines and porphyrins, as well as their hybrids for the NO detection in aqueous solutions and biological media. The second part presents an analysis of works describing the latest achievements in the field of studied materials as active layers of sensors for the determination of gaseous NO. It is expected that this review will further increase the interest of researchers who are engaged in the current level of evaluation and selection of modern materials for use in the chemical sensing of nitric oxide.https://www.mdpi.com/1424-8220/22/3/895chemical sensorschemiresistive sensorselectrochemical sensorsphthalocyaninesporphyrinsnitric oxide
spellingShingle Darya Klyamer
Roman Shutilov
Tamara Basova
Recent Advances in Phthalocyanine and Porphyrin-Based Materials as Active Layers for Nitric Oxide Chemical Sensors
Sensors
chemical sensors
chemiresistive sensors
electrochemical sensors
phthalocyanines
porphyrins
nitric oxide
title Recent Advances in Phthalocyanine and Porphyrin-Based Materials as Active Layers for Nitric Oxide Chemical Sensors
title_full Recent Advances in Phthalocyanine and Porphyrin-Based Materials as Active Layers for Nitric Oxide Chemical Sensors
title_fullStr Recent Advances in Phthalocyanine and Porphyrin-Based Materials as Active Layers for Nitric Oxide Chemical Sensors
title_full_unstemmed Recent Advances in Phthalocyanine and Porphyrin-Based Materials as Active Layers for Nitric Oxide Chemical Sensors
title_short Recent Advances in Phthalocyanine and Porphyrin-Based Materials as Active Layers for Nitric Oxide Chemical Sensors
title_sort recent advances in phthalocyanine and porphyrin based materials as active layers for nitric oxide chemical sensors
topic chemical sensors
chemiresistive sensors
electrochemical sensors
phthalocyanines
porphyrins
nitric oxide
url https://www.mdpi.com/1424-8220/22/3/895
work_keys_str_mv AT daryaklyamer recentadvancesinphthalocyanineandporphyrinbasedmaterialsasactivelayersfornitricoxidechemicalsensors
AT romanshutilov recentadvancesinphthalocyanineandporphyrinbasedmaterialsasactivelayersfornitricoxidechemicalsensors
AT tamarabasova recentadvancesinphthalocyanineandporphyrinbasedmaterialsasactivelayersfornitricoxidechemicalsensors