Diagenesis of the Sedimentary Fe–Ni Deposits of Euboea: Evidence Based on Phyllosilicate Mineralogy

A set of samples with different textures from the sedimentary Fe–Ni deposits of Central Euboea, Greece, were studied with XRD and SEM-EDS to investigate the relationships between phyllosilicates present. The deposits are characterized by the coexistence of smectite, corrensite, R0 mixed-layer chlori...

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Main Authors: Spyros Cheliotis-Chatzidimitriou, Georgios E. Christidis, Ioannis Marantos
Format: Article
Language:English
Published: MDPI AG 2021-12-01
Series:Materials Proceedings
Subjects:
Online Access:https://www.mdpi.com/2673-4605/5/1/73
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author Spyros Cheliotis-Chatzidimitriou
Georgios E. Christidis
Ioannis Marantos
author_facet Spyros Cheliotis-Chatzidimitriou
Georgios E. Christidis
Ioannis Marantos
author_sort Spyros Cheliotis-Chatzidimitriou
collection DOAJ
description A set of samples with different textures from the sedimentary Fe–Ni deposits of Central Euboea, Greece, were studied with XRD and SEM-EDS to investigate the relationships between phyllosilicates present. The deposits are characterized by the coexistence of smectite, corrensite, R0 mixed-layer chlorite-smectite and discrete chlorite, which indicates disequilibrium conditions. It is suggested that chlorite, the main Ni-host in the deposits, formed by conversion of smectite (nontronite and possibly stevensite), via corrensite and R0 Chl-Sme during diagenesis. This is the first report for chloritization of Fe-rich dioctahedral smectite during diagenesis.
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spelling doaj.art-62e36d0319ab4dbbb032cd8836fb72242023-11-17T12:24:42ZengMDPI AGMaterials Proceedings2673-46052021-12-01517310.3390/materproc2021005073Diagenesis of the Sedimentary Fe–Ni Deposits of Euboea: Evidence Based on Phyllosilicate MineralogySpyros Cheliotis-Chatzidimitriou0Georgios E. Christidis1Ioannis Marantos2School of Mineral Resources Engineering, Technical University of Crete, 73100 Chania, GreeceSchool of Mineral Resources Engineering, Technical University of Crete, 73100 Chania, GreeceHellenic Survey of Geology and Mineral Exploration (H.S.G.M.E.), 13677 Acharnae, GreeceA set of samples with different textures from the sedimentary Fe–Ni deposits of Central Euboea, Greece, were studied with XRD and SEM-EDS to investigate the relationships between phyllosilicates present. The deposits are characterized by the coexistence of smectite, corrensite, R0 mixed-layer chlorite-smectite and discrete chlorite, which indicates disequilibrium conditions. It is suggested that chlorite, the main Ni-host in the deposits, formed by conversion of smectite (nontronite and possibly stevensite), via corrensite and R0 Chl-Sme during diagenesis. This is the first report for chloritization of Fe-rich dioctahedral smectite during diagenesis.https://www.mdpi.com/2673-4605/5/1/73sedimentary Fe–Ni depositsmixed layer chlorite-smectitecorrensiteserpentinesmectitechlorite
spellingShingle Spyros Cheliotis-Chatzidimitriou
Georgios E. Christidis
Ioannis Marantos
Diagenesis of the Sedimentary Fe–Ni Deposits of Euboea: Evidence Based on Phyllosilicate Mineralogy
Materials Proceedings
sedimentary Fe–Ni deposits
mixed layer chlorite-smectite
corrensite
serpentine
smectite
chlorite
title Diagenesis of the Sedimentary Fe–Ni Deposits of Euboea: Evidence Based on Phyllosilicate Mineralogy
title_full Diagenesis of the Sedimentary Fe–Ni Deposits of Euboea: Evidence Based on Phyllosilicate Mineralogy
title_fullStr Diagenesis of the Sedimentary Fe–Ni Deposits of Euboea: Evidence Based on Phyllosilicate Mineralogy
title_full_unstemmed Diagenesis of the Sedimentary Fe–Ni Deposits of Euboea: Evidence Based on Phyllosilicate Mineralogy
title_short Diagenesis of the Sedimentary Fe–Ni Deposits of Euboea: Evidence Based on Phyllosilicate Mineralogy
title_sort diagenesis of the sedimentary fe ni deposits of euboea evidence based on phyllosilicate mineralogy
topic sedimentary Fe–Ni deposits
mixed layer chlorite-smectite
corrensite
serpentine
smectite
chlorite
url https://www.mdpi.com/2673-4605/5/1/73
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AT georgiosechristidis diagenesisofthesedimentaryfenidepositsofeuboeaevidencebasedonphyllosilicatemineralogy
AT ioannismarantos diagenesisofthesedimentaryfenidepositsofeuboeaevidencebasedonphyllosilicatemineralogy