Thermal, chemical, and structural investigation of the usability of Cs/nHAp-ZnO/Glutaraldehyde polymer matrix composite in potential biomaterial applications

Nano-HAp and ZnO-containing particles in the main chitosan matrix that can be used as a scaffold composite or surface coating in dental and medical implants to improve infection and biocompatibility processes have been developed. After adding chitosan/HAp-ZnO biopolymer, a cross-linked triple absorb...

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Main Author: Oktay Yigit
Format: Article
Language:English
Published: Elsevier 2023-07-01
Series:Arabian Journal of Chemistry
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1878535223003003
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author Oktay Yigit
author_facet Oktay Yigit
author_sort Oktay Yigit
collection DOAJ
description Nano-HAp and ZnO-containing particles in the main chitosan matrix that can be used as a scaffold composite or surface coating in dental and medical implants to improve infection and biocompatibility processes have been developed. After adding chitosan/HAp-ZnO biopolymer, a cross-linked triple absorbent composite system was produced using glutaraldehyde simply and practically. Morphological analyzes were examined by FE-SEM analysis, and the changes that occurred with the cross-linking reaction were observed. Elemental analysis of composite materials was analyzed with EDS, and chemical analyzes were analyzed using ART-IR, XPS XRD and Raman analyses. In addition, the thermal properties of the composites were examined by DTA and TGA analysis. As a result of the cross-linking reaction, it was observed that the composite exhibited a more compact structure. The study's primary purpose was to observe the ability of the biodegradable chitosan polymer to form composites with ZnO and HAp structure and examine the changes that occur with the cross-linking reaction. As a result, it was seen that the three components were well distributed among each other, intramolecular and intermolecular bonds were formed between these components, and the composite was restructured with the occurrence of strong interaction.
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spelling doaj.art-62e37203cfe84f7eae58bf0102dc3d4a2023-04-29T14:49:12ZengElsevierArabian Journal of Chemistry1878-53522023-07-01167104838Thermal, chemical, and structural investigation of the usability of Cs/nHAp-ZnO/Glutaraldehyde polymer matrix composite in potential biomaterial applicationsOktay Yigit0Faculty of Technology, Metallurgy and Material Engineering, Fırat University, Elazığ, TURKEYNano-HAp and ZnO-containing particles in the main chitosan matrix that can be used as a scaffold composite or surface coating in dental and medical implants to improve infection and biocompatibility processes have been developed. After adding chitosan/HAp-ZnO biopolymer, a cross-linked triple absorbent composite system was produced using glutaraldehyde simply and practically. Morphological analyzes were examined by FE-SEM analysis, and the changes that occurred with the cross-linking reaction were observed. Elemental analysis of composite materials was analyzed with EDS, and chemical analyzes were analyzed using ART-IR, XPS XRD and Raman analyses. In addition, the thermal properties of the composites were examined by DTA and TGA analysis. As a result of the cross-linking reaction, it was observed that the composite exhibited a more compact structure. The study's primary purpose was to observe the ability of the biodegradable chitosan polymer to form composites with ZnO and HAp structure and examine the changes that occur with the cross-linking reaction. As a result, it was seen that the three components were well distributed among each other, intramolecular and intermolecular bonds were formed between these components, and the composite was restructured with the occurrence of strong interaction.http://www.sciencedirect.com/science/article/pii/S1878535223003003ChitosanHydroxyapatiteZnOPolymeric CompositesCross-linking reaction
spellingShingle Oktay Yigit
Thermal, chemical, and structural investigation of the usability of Cs/nHAp-ZnO/Glutaraldehyde polymer matrix composite in potential biomaterial applications
Arabian Journal of Chemistry
Chitosan
Hydroxyapatite
ZnO
Polymeric Composites
Cross-linking reaction
title Thermal, chemical, and structural investigation of the usability of Cs/nHAp-ZnO/Glutaraldehyde polymer matrix composite in potential biomaterial applications
title_full Thermal, chemical, and structural investigation of the usability of Cs/nHAp-ZnO/Glutaraldehyde polymer matrix composite in potential biomaterial applications
title_fullStr Thermal, chemical, and structural investigation of the usability of Cs/nHAp-ZnO/Glutaraldehyde polymer matrix composite in potential biomaterial applications
title_full_unstemmed Thermal, chemical, and structural investigation of the usability of Cs/nHAp-ZnO/Glutaraldehyde polymer matrix composite in potential biomaterial applications
title_short Thermal, chemical, and structural investigation of the usability of Cs/nHAp-ZnO/Glutaraldehyde polymer matrix composite in potential biomaterial applications
title_sort thermal chemical and structural investigation of the usability of cs nhap zno glutaraldehyde polymer matrix composite in potential biomaterial applications
topic Chitosan
Hydroxyapatite
ZnO
Polymeric Composites
Cross-linking reaction
url http://www.sciencedirect.com/science/article/pii/S1878535223003003
work_keys_str_mv AT oktayyigit thermalchemicalandstructuralinvestigationoftheusabilityofcsnhapznoglutaraldehydepolymermatrixcompositeinpotentialbiomaterialapplications