Easy and Safe Preparations of (Diacetoxyiodo) arenes from Iodoarenes, with Urea-Hydrogen Peroxide Adduct (UHP) as the Oxidant and the Fully Interpreted 1H- and 13C-NMR Spectra of the Products
An easy and safe, though only moderately effective method is presented forpreparing (diacetoxyiodo)arenes, ArI(OAc)2, from iodoarenes, ArI, using thecommercially available and easily handled urea-hydrogen peroxide adduct (UHP) as theoxidant. The reactions take place in anhydrous AcOH/Ac2O/AcONa (a c...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2005-01-01
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| Series: | Molecules |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1420-3049/10/1/190/ |
| _version_ | 1819239856032710656 |
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| author | Lech Skulski Agnieszka Zielinska |
| author_facet | Lech Skulski Agnieszka Zielinska |
| author_sort | Lech Skulski |
| collection | DOAJ |
| description | An easy and safe, though only moderately effective method is presented forpreparing (diacetoxyiodo)arenes, ArI(OAc)2, from iodoarenes, ArI, using thecommercially available and easily handled urea-hydrogen peroxide adduct (UHP) as theoxidant. The reactions take place in anhydrous AcOH/Ac2O/AcONa (a catalyst)mixtures, at 40 oC for 3.5 h to afford the purified ArI(OAc)2 in 37-78% yields. The fullyinterpreted 1H- and 13C-NMR spectra of the ArI(OAc)2 products are reported. |
| first_indexed | 2024-12-23T13:58:46Z |
| format | Article |
| id | doaj.art-62f321d620544f0384e97f568b2d7c11 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-23T13:58:46Z |
| publishDate | 2005-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-62f321d620544f0384e97f568b2d7c112022-12-21T17:44:22ZengMDPI AGMolecules1420-30492005-01-0110119019410.3390/10010190Easy and Safe Preparations of (Diacetoxyiodo) arenes from Iodoarenes, with Urea-Hydrogen Peroxide Adduct (UHP) as the Oxidant and the Fully Interpreted 1H- and 13C-NMR Spectra of the ProductsLech SkulskiAgnieszka ZielinskaAn easy and safe, though only moderately effective method is presented forpreparing (diacetoxyiodo)arenes, ArI(OAc)2, from iodoarenes, ArI, using thecommercially available and easily handled urea-hydrogen peroxide adduct (UHP) as theoxidant. The reactions take place in anhydrous AcOH/Ac2O/AcONa (a catalyst)mixtures, at 40 oC for 3.5 h to afford the purified ArI(OAc)2 in 37-78% yields. The fullyinterpreted 1H- and 13C-NMR spectra of the ArI(OAc)2 products are reported.http://www.mdpi.com/1420-3049/10/1/190/(Diacetoxyiodo)arenesiodoarenesurea-hydrogen peroxide adduct as oxidant1H- and 13C-NMR spectra |
| spellingShingle | Lech Skulski Agnieszka Zielinska Easy and Safe Preparations of (Diacetoxyiodo) arenes from Iodoarenes, with Urea-Hydrogen Peroxide Adduct (UHP) as the Oxidant and the Fully Interpreted 1H- and 13C-NMR Spectra of the Products Molecules (Diacetoxyiodo)arenes iodoarenes urea-hydrogen peroxide adduct as oxidant 1H- and 13C-NMR spectra |
| title | Easy and Safe Preparations of (Diacetoxyiodo) arenes from Iodoarenes, with Urea-Hydrogen Peroxide Adduct (UHP) as the Oxidant and the Fully Interpreted 1H- and 13C-NMR Spectra of the Products |
| title_full | Easy and Safe Preparations of (Diacetoxyiodo) arenes from Iodoarenes, with Urea-Hydrogen Peroxide Adduct (UHP) as the Oxidant and the Fully Interpreted 1H- and 13C-NMR Spectra of the Products |
| title_fullStr | Easy and Safe Preparations of (Diacetoxyiodo) arenes from Iodoarenes, with Urea-Hydrogen Peroxide Adduct (UHP) as the Oxidant and the Fully Interpreted 1H- and 13C-NMR Spectra of the Products |
| title_full_unstemmed | Easy and Safe Preparations of (Diacetoxyiodo) arenes from Iodoarenes, with Urea-Hydrogen Peroxide Adduct (UHP) as the Oxidant and the Fully Interpreted 1H- and 13C-NMR Spectra of the Products |
| title_short | Easy and Safe Preparations of (Diacetoxyiodo) arenes from Iodoarenes, with Urea-Hydrogen Peroxide Adduct (UHP) as the Oxidant and the Fully Interpreted 1H- and 13C-NMR Spectra of the Products |
| title_sort | easy and safe preparations of diacetoxyiodo arenes from iodoarenes with urea hydrogen peroxide adduct uhp as the oxidant and the fully interpreted 1h and 13c nmr spectra of the products |
| topic | (Diacetoxyiodo)arenes iodoarenes urea-hydrogen peroxide adduct as oxidant 1H- and 13C-NMR spectra |
| url | http://www.mdpi.com/1420-3049/10/1/190/ |
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