Synthesis of MIL-100(Fe)@Fe3O4 from Magnetic Zircon Mining Waste Modified by CTAB for Naphthol Dye in Water Removal
The synthesis of MIL-100(Fe)@Fe3O4 composite modified by CTAB has been reported in this study. This research begins with synthesis of magnetite (Fe3O4), using an iron precursor from zircon mining magnetic waste. The MIL-100(Fe)@Fe3O4 was composited with CTAB using a room-temperature in situ synthesi...
| Main Authors: | , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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EDP Sciences
2023-01-01
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| Series: | BIO Web of Conferences |
| Online Access: | https://www.bio-conferences.org/articles/bioconf/pdf/2023/24/bioconf_icome2023_12005.pdf |
| _version_ | 1797353046002368512 |
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| author | Pereiz Zimon Pebriyanto Yunus Naulita Turnip Oktaviani Maya Sylvani Miranti Karelius Karelius Putra Ramdhani Eka Chuchita Chuchita Agnestisia Retno Horale Pasaribu Marvin Prasetya Toepak Erwin |
| author_facet | Pereiz Zimon Pebriyanto Yunus Naulita Turnip Oktaviani Maya Sylvani Miranti Karelius Karelius Putra Ramdhani Eka Chuchita Chuchita Agnestisia Retno Horale Pasaribu Marvin Prasetya Toepak Erwin |
| author_sort | Pereiz Zimon |
| collection | DOAJ |
| description | The synthesis of MIL-100(Fe)@Fe3O4 composite modified by CTAB has been reported in this study. This research begins with synthesis of magnetite (Fe3O4), using an iron precursor from zircon mining magnetic waste. The MIL-100(Fe)@Fe3O4 was composited with CTAB using a room-temperature in situ synthesis method. The MIL-100(Fe)@Fe3O4-CTAB composite obtained was then characterized using Fourier Transform Infrared spectroscopy and X-ray diffraction. The synthesized MIL-100(Fe)@Fe3O4-CTAB was then used to adsorb naphthol dye from the aqueous phase. The maximum naphthol removal was obtained at a concentration of CTAB of 0.4 M and pH of 6. The adsorption kinetics showed that the adsorption followed a pseudo second-order kinetics model, with the rate constant values for MIL-100(Fe)@Fe3O4-CTAB being 1,712 x 10-2 g/mg.menit, respectively. The results also showed that the adsorption isotherm of MIL-100(Fe)@Fe3O4-CTAB follows the Langmuir isotherm for adsorption capacities of 63,036 mg/g, respectively. The results indicate that naphthol dye can be effectively removed from the aqueous phase by using the iron content in the magnetic waste from zircon mining, which was used as a precursor for the manufacture of MIL-100(Fe)@Fe3O4-CTAB composite. |
| first_indexed | 2024-03-08T13:25:29Z |
| format | Article |
| id | doaj.art-62f5565232dc4796a936afb1d44c70c8 |
| institution | Directory Open Access Journal |
| issn | 2117-4458 |
| language | English |
| last_indexed | 2024-03-08T13:25:29Z |
| publishDate | 2023-01-01 |
| publisher | EDP Sciences |
| record_format | Article |
| series | BIO Web of Conferences |
| spelling | doaj.art-62f5565232dc4796a936afb1d44c70c82024-01-17T14:57:21ZengEDP SciencesBIO Web of Conferences2117-44582023-01-01791200510.1051/bioconf/20237912005bioconf_icome2023_12005Synthesis of MIL-100(Fe)@Fe3O4 from Magnetic Zircon Mining Waste Modified by CTAB for Naphthol Dye in Water RemovalPereiz Zimon0Pebriyanto Yunus1Naulita Turnip Oktaviani2Maya Sylvani Miranti3Karelius Karelius4Putra Ramdhani Eka5Chuchita Chuchita6Agnestisia Retno7Horale Pasaribu Marvin8Prasetya Toepak Erwin9Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Palangka RayaDepartment of Physics, Faculty of Mathematics and Natural Sciences, Universitas Palangka RayaDepartment of Microbiology, Faculty of Medicine, UniversitasDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Palangka RayaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Palangka RayaDepartment of Chemistry Education, Faculty of Teacher Training and Education, Raja Ali Haji Maritime UniversityDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Palangka RayaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Palangka RayaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Palangka RayaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Palangka RayaThe synthesis of MIL-100(Fe)@Fe3O4 composite modified by CTAB has been reported in this study. This research begins with synthesis of magnetite (Fe3O4), using an iron precursor from zircon mining magnetic waste. The MIL-100(Fe)@Fe3O4 was composited with CTAB using a room-temperature in situ synthesis method. The MIL-100(Fe)@Fe3O4-CTAB composite obtained was then characterized using Fourier Transform Infrared spectroscopy and X-ray diffraction. The synthesized MIL-100(Fe)@Fe3O4-CTAB was then used to adsorb naphthol dye from the aqueous phase. The maximum naphthol removal was obtained at a concentration of CTAB of 0.4 M and pH of 6. The adsorption kinetics showed that the adsorption followed a pseudo second-order kinetics model, with the rate constant values for MIL-100(Fe)@Fe3O4-CTAB being 1,712 x 10-2 g/mg.menit, respectively. The results also showed that the adsorption isotherm of MIL-100(Fe)@Fe3O4-CTAB follows the Langmuir isotherm for adsorption capacities of 63,036 mg/g, respectively. The results indicate that naphthol dye can be effectively removed from the aqueous phase by using the iron content in the magnetic waste from zircon mining, which was used as a precursor for the manufacture of MIL-100(Fe)@Fe3O4-CTAB composite.https://www.bio-conferences.org/articles/bioconf/pdf/2023/24/bioconf_icome2023_12005.pdf |
| spellingShingle | Pereiz Zimon Pebriyanto Yunus Naulita Turnip Oktaviani Maya Sylvani Miranti Karelius Karelius Putra Ramdhani Eka Chuchita Chuchita Agnestisia Retno Horale Pasaribu Marvin Prasetya Toepak Erwin Synthesis of MIL-100(Fe)@Fe3O4 from Magnetic Zircon Mining Waste Modified by CTAB for Naphthol Dye in Water Removal BIO Web of Conferences |
| title | Synthesis of MIL-100(Fe)@Fe3O4 from Magnetic Zircon Mining Waste Modified by CTAB for Naphthol Dye in Water Removal |
| title_full | Synthesis of MIL-100(Fe)@Fe3O4 from Magnetic Zircon Mining Waste Modified by CTAB for Naphthol Dye in Water Removal |
| title_fullStr | Synthesis of MIL-100(Fe)@Fe3O4 from Magnetic Zircon Mining Waste Modified by CTAB for Naphthol Dye in Water Removal |
| title_full_unstemmed | Synthesis of MIL-100(Fe)@Fe3O4 from Magnetic Zircon Mining Waste Modified by CTAB for Naphthol Dye in Water Removal |
| title_short | Synthesis of MIL-100(Fe)@Fe3O4 from Magnetic Zircon Mining Waste Modified by CTAB for Naphthol Dye in Water Removal |
| title_sort | synthesis of mil 100 fe fe3o4 from magnetic zircon mining waste modified by ctab for naphthol dye in water removal |
| url | https://www.bio-conferences.org/articles/bioconf/pdf/2023/24/bioconf_icome2023_12005.pdf |
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