Aqua(2,2′-bipyridine)bis(4-hydroxybenzoato)zinc(II)

In the title complex, [Zn(C7H5O3)2(C10H8N2)(H2O)], the ZnII ion is coordinated by two 4-hydroxybenzoate anions, one 2,2′-bipyridine molecule and one water molecule and displays a distorted octahedral geometry. One Zn—O bond [2.5300 (15) &am...

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Bibliographic Details
Main Authors: Duan-Jun Xu, Jing-Jing Nie, Bing-Yu Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2009-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809025525
Description
Summary:In the title complex, [Zn(C7H5O3)2(C10H8N2)(H2O)], the ZnII ion is coordinated by two 4-hydroxybenzoate anions, one 2,2′-bipyridine molecule and one water molecule and displays a distorted octahedral geometry. One Zn—O bond [2.5300 (15) Å] is much longer than the others in the molecule. In the crystal structure, the face-to-face separation of 3.547 (9) Å suggests no π–π stacking between parallel bipyridine ring systems, and an extensive O—H...O hydrogen-bonding network between the coordinated water molecule, the phenol group and carboxylate O atoms is present.
ISSN:1600-5368