Extraction of ergotropy: free energy bound and application to open cycle engines

The second law of thermodynamics uses change in free energy of macroscopic systems to set a bound on performed work. Ergotropy plays a similar role in microscopic scenarios, and is defined as the maximum amount of energy that can be extracted from a system by a unitary operation. In this analysis, w...

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Main Authors: Tanmoy Biswas, Marcin Łobejko, Paweł Mazurek, Konrad Jałowiecki, Michał Horodecki
Format: Article
Language:English
Published: Verein zur Förderung des Open Access Publizierens in den Quantenwissenschaften 2022-10-01
Series:Quantum
Online Access:https://quantum-journal.org/papers/q-2022-10-17-841/pdf/
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author Tanmoy Biswas
Marcin Łobejko
Paweł Mazurek
Konrad Jałowiecki
Michał Horodecki
author_facet Tanmoy Biswas
Marcin Łobejko
Paweł Mazurek
Konrad Jałowiecki
Michał Horodecki
author_sort Tanmoy Biswas
collection DOAJ
description The second law of thermodynamics uses change in free energy of macroscopic systems to set a bound on performed work. Ergotropy plays a similar role in microscopic scenarios, and is defined as the maximum amount of energy that can be extracted from a system by a unitary operation. In this analysis, we quantify how much ergotropy can be induced on a system as a result of system's interaction with a thermal bath, with a perspective of using it as a source of work performed by microscopic machines. We provide the fundamental bound on the amount of ergotropy which can be extracted from environment in this way. The bound is expressed in terms of the non-equilibrium free energy difference and can be saturated in the limit of infinite dimension of the system's Hamiltonian. The ergotropy extraction process leading to this saturation is numerically analyzed for finite dimensional systems. Furthermore, we apply the idea of extraction of ergotropy from environment in a design of a new class of stroke heat engines, which we label open-cycle engines. Efficiency and work production of these machines can be completely optimized for systems of dimensions 2 and 3, and numerical analysis is provided for higher dimensions.
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spelling doaj.art-6344c01c18884c4a99b50c87369137522022-12-22T04:06:50ZengVerein zur Förderung des Open Access Publizierens in den QuantenwissenschaftenQuantum2521-327X2022-10-01684110.22331/q-2022-10-17-84110.22331/q-2022-10-17-841Extraction of ergotropy: free energy bound and application to open cycle enginesTanmoy BiswasMarcin ŁobejkoPaweł MazurekKonrad JałowieckiMichał HorodeckiThe second law of thermodynamics uses change in free energy of macroscopic systems to set a bound on performed work. Ergotropy plays a similar role in microscopic scenarios, and is defined as the maximum amount of energy that can be extracted from a system by a unitary operation. In this analysis, we quantify how much ergotropy can be induced on a system as a result of system's interaction with a thermal bath, with a perspective of using it as a source of work performed by microscopic machines. We provide the fundamental bound on the amount of ergotropy which can be extracted from environment in this way. The bound is expressed in terms of the non-equilibrium free energy difference and can be saturated in the limit of infinite dimension of the system's Hamiltonian. The ergotropy extraction process leading to this saturation is numerically analyzed for finite dimensional systems. Furthermore, we apply the idea of extraction of ergotropy from environment in a design of a new class of stroke heat engines, which we label open-cycle engines. Efficiency and work production of these machines can be completely optimized for systems of dimensions 2 and 3, and numerical analysis is provided for higher dimensions.https://quantum-journal.org/papers/q-2022-10-17-841/pdf/
spellingShingle Tanmoy Biswas
Marcin Łobejko
Paweł Mazurek
Konrad Jałowiecki
Michał Horodecki
Extraction of ergotropy: free energy bound and application to open cycle engines
Quantum
title Extraction of ergotropy: free energy bound and application to open cycle engines
title_full Extraction of ergotropy: free energy bound and application to open cycle engines
title_fullStr Extraction of ergotropy: free energy bound and application to open cycle engines
title_full_unstemmed Extraction of ergotropy: free energy bound and application to open cycle engines
title_short Extraction of ergotropy: free energy bound and application to open cycle engines
title_sort extraction of ergotropy free energy bound and application to open cycle engines
url https://quantum-journal.org/papers/q-2022-10-17-841/pdf/
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AT pawełmazurek extractionofergotropyfreeenergyboundandapplicationtoopencycleengines
AT konradjałowiecki extractionofergotropyfreeenergyboundandapplicationtoopencycleengines
AT michałhorodecki extractionofergotropyfreeenergyboundandapplicationtoopencycleengines