Conversion Kinetics and Ionic Conductivity in Na-β”-Alumina + YSZ (Naβ”AY) Sodium Solid Electrolyte via Vapor Phase Conversion Process
Sodium ion batteries have been receiving increasing attention and may see potential revival in the near future, particularly in large-scale grid energy storage coupling with wind and solar power generation, due to the abundant sodium resources, low cost, and sufficiently high energy density. Among t...
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| Format: | Article |
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MDPI AG
2022-05-01
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| Series: | Membranes |
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| Online Access: | https://www.mdpi.com/2077-0375/12/6/567 |
| _version_ | 1797484475281571840 |
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| author | Liangzhu Zhu Anil V. Virkar |
| author_facet | Liangzhu Zhu Anil V. Virkar |
| author_sort | Liangzhu Zhu |
| collection | DOAJ |
| description | Sodium ion batteries have been receiving increasing attention and may see potential revival in the near future, particularly in large-scale grid energy storage coupling with wind and solar power generation, due to the abundant sodium resources, low cost, and sufficiently high energy density. Among the known sodium ion conductors, the Na-β”-alumina electrolyte remains highly attractive because of its high ionic conductivity. This study focuses on the vapor phase synthesis of a Na-β”-Alumina + YSZ (Naβ”AY) composite sodium electrolyte, which has higher mechanical strength and stability than conventional single phase β”-Alumina. The objectives are the measurement of conversion kinetics through a newly developed weight-gain based model and the determination of sodium ionic conductivity in the composite electrolyte. Starting samples contained ~70 vol% α-Alumina and ~30 vol% YSZ (3 mol% Y<sub>2</sub>O<sub>3</sub> stabilized Zirconia) with and without a thin alumina surface layer made by sintering in air at 1600 °C. The sintered samples were placed in a powder of Na-β”-alumina and heat-treated at 1250 °C for various periods. Sample dimensions and weight were measured as a function of heat treatment time. The conversion of α-Alumina in the α-Alumina + YSZ composite into Naβ”AY occurred by coupled diffusion of sodium ions through Na-β”-alumina and of oxygen ions through YSZ, effectively diffusing Na<sub>2</sub>O. From the analysis of the time dependence of sample mass and dimensions, the effective diffusion coefficient of Na<sub>2</sub>O through the sample, <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mi>D</mi><mrow><mi>e</mi><mi>f</mi><mi>f</mi></mrow></msub></mrow></semantics></math></inline-formula>, was estimated to be 1.74 × 10<sup>−7</sup> cm<sup>2</sup> s<sup>−1</sup>, and the effective interface transfer parameter, <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mi>k</mi><mrow><mi>e</mi><mi>f</mi><mi>f</mi></mrow></msub></mrow></semantics></math></inline-formula>, was estimated as 2.33 × 10<sup>−6</sup> cm s<sup>−1</sup>. By depositing a thin alumina coating layer on top of the bulk composite, the chemical diffusion coefficient of oxygen through single phase Na-β”-alumina was estimated as 4.35 × 10<sup>−10</sup> cm<sup>2</sup> s<sup>−1</sup>. An AC impedance measurement was performed on a fully converted Naβ”AY composite, and the conductivity of the composite electrolyte was 1.3 × 10<sup>−1</sup> S cm<sup>−1</sup> at 300 °C and 1.6 × 10<sup>−3</sup> S cm<sup>−1</sup> at 25 °C, indicating promising applications in solid state or molten salt batteries at low to intermediate temperatures. |
| first_indexed | 2024-03-09T23:05:51Z |
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| language | English |
| last_indexed | 2024-03-09T23:05:51Z |
| publishDate | 2022-05-01 |
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| series | Membranes |
| spelling | doaj.art-6361d416aebe4ac5ac4f858c0e4db6702023-11-23T17:54:00ZengMDPI AGMembranes2077-03752022-05-0112656710.3390/membranes12060567Conversion Kinetics and Ionic Conductivity in Na-β”-Alumina + YSZ (Naβ”AY) Sodium Solid Electrolyte via Vapor Phase Conversion ProcessLiangzhu Zhu0Anil V. Virkar1Materials Science & Engineering Department, University of Utah, Salt Lake City, UT 84112, USAMaterials Science & Engineering Department, University of Utah, Salt Lake City, UT 84112, USASodium ion batteries have been receiving increasing attention and may see potential revival in the near future, particularly in large-scale grid energy storage coupling with wind and solar power generation, due to the abundant sodium resources, low cost, and sufficiently high energy density. Among the known sodium ion conductors, the Na-β”-alumina electrolyte remains highly attractive because of its high ionic conductivity. This study focuses on the vapor phase synthesis of a Na-β”-Alumina + YSZ (Naβ”AY) composite sodium electrolyte, which has higher mechanical strength and stability than conventional single phase β”-Alumina. The objectives are the measurement of conversion kinetics through a newly developed weight-gain based model and the determination of sodium ionic conductivity in the composite electrolyte. Starting samples contained ~70 vol% α-Alumina and ~30 vol% YSZ (3 mol% Y<sub>2</sub>O<sub>3</sub> stabilized Zirconia) with and without a thin alumina surface layer made by sintering in air at 1600 °C. The sintered samples were placed in a powder of Na-β”-alumina and heat-treated at 1250 °C for various periods. Sample dimensions and weight were measured as a function of heat treatment time. The conversion of α-Alumina in the α-Alumina + YSZ composite into Naβ”AY occurred by coupled diffusion of sodium ions through Na-β”-alumina and of oxygen ions through YSZ, effectively diffusing Na<sub>2</sub>O. From the analysis of the time dependence of sample mass and dimensions, the effective diffusion coefficient of Na<sub>2</sub>O through the sample, <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mi>D</mi><mrow><mi>e</mi><mi>f</mi><mi>f</mi></mrow></msub></mrow></semantics></math></inline-formula>, was estimated to be 1.74 × 10<sup>−7</sup> cm<sup>2</sup> s<sup>−1</sup>, and the effective interface transfer parameter, <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mi>k</mi><mrow><mi>e</mi><mi>f</mi><mi>f</mi></mrow></msub></mrow></semantics></math></inline-formula>, was estimated as 2.33 × 10<sup>−6</sup> cm s<sup>−1</sup>. By depositing a thin alumina coating layer on top of the bulk composite, the chemical diffusion coefficient of oxygen through single phase Na-β”-alumina was estimated as 4.35 × 10<sup>−10</sup> cm<sup>2</sup> s<sup>−1</sup>. An AC impedance measurement was performed on a fully converted Naβ”AY composite, and the conductivity of the composite electrolyte was 1.3 × 10<sup>−1</sup> S cm<sup>−1</sup> at 300 °C and 1.6 × 10<sup>−3</sup> S cm<sup>−1</sup> at 25 °C, indicating promising applications in solid state or molten salt batteries at low to intermediate temperatures.https://www.mdpi.com/2077-0375/12/6/567sodium β”-aluminaNaβ”AYsodium electrolytesodium solid-state batteryvapor phase processsodium batteries |
| spellingShingle | Liangzhu Zhu Anil V. Virkar Conversion Kinetics and Ionic Conductivity in Na-β”-Alumina + YSZ (Naβ”AY) Sodium Solid Electrolyte via Vapor Phase Conversion Process Membranes sodium β”-alumina Naβ”AY sodium electrolyte sodium solid-state battery vapor phase process sodium batteries |
| title | Conversion Kinetics and Ionic Conductivity in Na-β”-Alumina + YSZ (Naβ”AY) Sodium Solid Electrolyte via Vapor Phase Conversion Process |
| title_full | Conversion Kinetics and Ionic Conductivity in Na-β”-Alumina + YSZ (Naβ”AY) Sodium Solid Electrolyte via Vapor Phase Conversion Process |
| title_fullStr | Conversion Kinetics and Ionic Conductivity in Na-β”-Alumina + YSZ (Naβ”AY) Sodium Solid Electrolyte via Vapor Phase Conversion Process |
| title_full_unstemmed | Conversion Kinetics and Ionic Conductivity in Na-β”-Alumina + YSZ (Naβ”AY) Sodium Solid Electrolyte via Vapor Phase Conversion Process |
| title_short | Conversion Kinetics and Ionic Conductivity in Na-β”-Alumina + YSZ (Naβ”AY) Sodium Solid Electrolyte via Vapor Phase Conversion Process |
| title_sort | conversion kinetics and ionic conductivity in na β alumina ysz naβ ay sodium solid electrolyte via vapor phase conversion process |
| topic | sodium β”-alumina Naβ”AY sodium electrolyte sodium solid-state battery vapor phase process sodium batteries |
| url | https://www.mdpi.com/2077-0375/12/6/567 |
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