Phosphorus removal from swine wastewater using aluminum-based water treatment residuals

Aluminum water treatment residuals (Al-WTR), a waste product created during drinking water treatment, is generated in large quantities globally and typically landfilled; alternative, uses are desperately required. Inorganic phosphorus (P) is proven to be quickly and irreversibly sorbed by Al-WTR, re...

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Main Authors: Travis Banet, Michael S. Massey, Iris Zohar, M. Iggy Litaor, James A. Ippolito
Format: Article
Language:English
Published: Elsevier 2020-05-01
Series:Resources, Conservation & Recycling: X
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2590289X20300104
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author Travis Banet
Michael S. Massey
Iris Zohar
M. Iggy Litaor
James A. Ippolito
author_facet Travis Banet
Michael S. Massey
Iris Zohar
M. Iggy Litaor
James A. Ippolito
author_sort Travis Banet
collection DOAJ
description Aluminum water treatment residuals (Al-WTR), a waste product created during drinking water treatment, is generated in large quantities globally and typically landfilled; alternative, uses are desperately required. Inorganic phosphorus (P) is proven to be quickly and irreversibly sorbed by Al-WTR, rendering P unavailable for subsequent environmental use.However, little work has been done to characterize how Al-WTR interacts with organic P sources (e.g., wastewaters) to both sorb and later release P. Experiments characterized Al-WTR's ability sorb and subsequently desorb swine wastewater organic P, and to ascertain Al-WTR's potential for agricultural wastewater treatment and to return organic P to systems (e.g., soils) for beneficial use. Al-WTRs were shaken with swine wastewater (2.5:1;w/w) and solution total/inorganic/organic P were monitored over 21 days. The Al-WTR sorbed almost 100% (~ 16,500 mg kg−1) of swine wastewater organic P within a 1-h timeframe. X-ray absorption near-edge spectroscopy showed that P was primarily sorbed by Ca phases present in Al-WTR during the initial 1-h sorption phase. In a subsequent study, the newly generated organic P-laden Al-WTR was shaken in 0.01M KCl along with an anion membrane-probe to capture desorbed P. Approximately 17% (~ 3000 mg kg−1) of the organic P sorbed onto Al-WTR was desorbed. Findings suggest that Al-WTR can remove excessive organic P from agricultural waste streams, with the Al-WTR-organic P-containing material potentially having the ability to supplement agricultural soils with P for plant use. By following such an approach, this could provide municipalities with an alternative and beneficial utilization strategy as compared to landfilling.
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spelling doaj.art-637faf160abb4b398dd430a55fbcb1492022-12-22T00:54:27ZengElsevierResources, Conservation & Recycling: X2590-289X2020-05-016Phosphorus removal from swine wastewater using aluminum-based water treatment residualsTravis Banet0Michael S. Massey1Iris Zohar2M. Iggy Litaor3James A. Ippolito4Department of Soil and Crop Sciences, Colorado State University, Fort Collins, CO, United StatesDepartment of Earth and Environmental Sciences, California State University East Bay, Hayward, CA 94542, United StatesMIGAL – Galilee Research Institute, Hydro-Geochemistry Lab. Tel Hai Research Park, and Dep. of Water Sciences, Tel Hai College, Upper Galilee, IsraelMIGAL – Galilee Research Institute, Hydro-Geochemistry Lab. Tel Hai Research Park, and Dep. of Water Sciences, Tel Hai College, Upper Galilee, IsraelDepartment of Soil and Crop Sciences, Colorado State University, Fort Collins, CO, United States; Corresponding author.Aluminum water treatment residuals (Al-WTR), a waste product created during drinking water treatment, is generated in large quantities globally and typically landfilled; alternative, uses are desperately required. Inorganic phosphorus (P) is proven to be quickly and irreversibly sorbed by Al-WTR, rendering P unavailable for subsequent environmental use.However, little work has been done to characterize how Al-WTR interacts with organic P sources (e.g., wastewaters) to both sorb and later release P. Experiments characterized Al-WTR's ability sorb and subsequently desorb swine wastewater organic P, and to ascertain Al-WTR's potential for agricultural wastewater treatment and to return organic P to systems (e.g., soils) for beneficial use. Al-WTRs were shaken with swine wastewater (2.5:1;w/w) and solution total/inorganic/organic P were monitored over 21 days. The Al-WTR sorbed almost 100% (~ 16,500 mg kg−1) of swine wastewater organic P within a 1-h timeframe. X-ray absorption near-edge spectroscopy showed that P was primarily sorbed by Ca phases present in Al-WTR during the initial 1-h sorption phase. In a subsequent study, the newly generated organic P-laden Al-WTR was shaken in 0.01M KCl along with an anion membrane-probe to capture desorbed P. Approximately 17% (~ 3000 mg kg−1) of the organic P sorbed onto Al-WTR was desorbed. Findings suggest that Al-WTR can remove excessive organic P from agricultural waste streams, with the Al-WTR-organic P-containing material potentially having the ability to supplement agricultural soils with P for plant use. By following such an approach, this could provide municipalities with an alternative and beneficial utilization strategy as compared to landfilling.http://www.sciencedirect.com/science/article/pii/S2590289X20300104Agri-wastewater P remediationAluminum water treatment residualsOrganic-P desorption
spellingShingle Travis Banet
Michael S. Massey
Iris Zohar
M. Iggy Litaor
James A. Ippolito
Phosphorus removal from swine wastewater using aluminum-based water treatment residuals
Resources, Conservation & Recycling: X
Agri-wastewater P remediation
Aluminum water treatment residuals
Organic-P desorption
title Phosphorus removal from swine wastewater using aluminum-based water treatment residuals
title_full Phosphorus removal from swine wastewater using aluminum-based water treatment residuals
title_fullStr Phosphorus removal from swine wastewater using aluminum-based water treatment residuals
title_full_unstemmed Phosphorus removal from swine wastewater using aluminum-based water treatment residuals
title_short Phosphorus removal from swine wastewater using aluminum-based water treatment residuals
title_sort phosphorus removal from swine wastewater using aluminum based water treatment residuals
topic Agri-wastewater P remediation
Aluminum water treatment residuals
Organic-P desorption
url http://www.sciencedirect.com/science/article/pii/S2590289X20300104
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