An orthorhombic polymorph of cerium(III) ultraphosphate, CeP5O14
Cerium(III) ultraphosphate, CeP5O14, was synthesized by a high-temperature solution reaction between CeO2 and NH4H2PO4 in a Ce–P molar ratio of 1:12. Colourless crystals of the orthorhombic polymorph were obtained by cooling the melt of the mixture. The structure contains (P5O14)3ͨ...
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Format: | Article |
Language: | English |
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International Union of Crystallography
2008-11-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808032972 |
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author | Jing Zhu Wen-Dan Cheng Hao Zhang |
author_facet | Jing Zhu Wen-Dan Cheng Hao Zhang |
author_sort | Jing Zhu |
collection | DOAJ |
description | Cerium(III) ultraphosphate, CeP5O14, was synthesized by a high-temperature solution reaction between CeO2 and NH4H2PO4 in a Ce–P molar ratio of 1:12. Colourless crystals of the orthorhombic polymorph were obtained by cooling the melt of the mixture. The structure contains (P5O14)3− anionic ribbons linked by distorted CeO8 polyhedra. |
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id | doaj.art-6392c737146b4cb6a185bf6ced4b2f4d |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-04-11T18:03:01Z |
publishDate | 2008-11-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-6392c737146b4cb6a185bf6ced4b2f4d2022-12-22T04:10:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-11-016411i74i7410.1107/S1600536808032972An orthorhombic polymorph of cerium(III) ultraphosphate, CeP5O14Jing ZhuWen-Dan ChengHao ZhangCerium(III) ultraphosphate, CeP5O14, was synthesized by a high-temperature solution reaction between CeO2 and NH4H2PO4 in a Ce–P molar ratio of 1:12. Colourless crystals of the orthorhombic polymorph were obtained by cooling the melt of the mixture. The structure contains (P5O14)3− anionic ribbons linked by distorted CeO8 polyhedra.http://scripts.iucr.org/cgi-bin/paper?S1600536808032972 |
spellingShingle | Jing Zhu Wen-Dan Cheng Hao Zhang An orthorhombic polymorph of cerium(III) ultraphosphate, CeP5O14 Acta Crystallographica Section E |
title | An orthorhombic polymorph of cerium(III) ultraphosphate, CeP5O14 |
title_full | An orthorhombic polymorph of cerium(III) ultraphosphate, CeP5O14 |
title_fullStr | An orthorhombic polymorph of cerium(III) ultraphosphate, CeP5O14 |
title_full_unstemmed | An orthorhombic polymorph of cerium(III) ultraphosphate, CeP5O14 |
title_short | An orthorhombic polymorph of cerium(III) ultraphosphate, CeP5O14 |
title_sort | orthorhombic polymorph of cerium iii ultraphosphate cep5o14 |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536808032972 |
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