Diaquabis(propane-1,3-diamine)nickel(II) bis(propane-1,3-diamine)disulfatonickelate(II)
The ionic NiII title complex, [Ni(C3H10N2)2(H2O)2][Ni(SO4)2(C3H10N2)2], is built up of [Ni(dipr)2(H2O)2]2+ complex cations and [Ni(dipr)2(SO4)2]2− complex anions (dipr is propane-1,3-diamine). Both NiII atoms display a slightly distorted octahedral coordination and are located on inver...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812009750 |
| _version_ | 1818975423362498560 |
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| author | Julia A. Rusanova |
| author_facet | Julia A. Rusanova |
| author_sort | Julia A. Rusanova |
| collection | DOAJ |
| description | The ionic NiII title complex, [Ni(C3H10N2)2(H2O)2][Ni(SO4)2(C3H10N2)2], is built up of [Ni(dipr)2(H2O)2]2+ complex cations and [Ni(dipr)2(SO4)2]2− complex anions (dipr is propane-1,3-diamine). Both NiII atoms display a slightly distorted octahedral coordination and are located on inversion centers. There are several types of hydrogen-bonding interactions, which connect complex cations and anions into a two-dimensional network parallel to (010). Hydrogen bonds formed by the axially coordinated water molecule of the complex cation and one of the O atoms of the sulfate groups of the complex anion (first type) link them into chains along the c axis. These chains are linked to each other through hydrogen bonds formed by an O atom (second type) of the SO4 groups and NH2 groups of the ligand of the complex cations from neighboring chains, forming a two-dimensional hydrogen-bonded net perpendicular to the b axis. The third type of O atoms of the sulfate groups of the complex anion are also linked into chains by a combination of both previously described types of H-atom connections. |
| first_indexed | 2024-12-20T15:55:43Z |
| format | Article |
| id | doaj.art-63c213829b0f47d69ebc9ba40cd6f930 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T15:55:43Z |
| publishDate | 2012-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-63c213829b0f47d69ebc9ba40cd6f9302022-12-21T19:34:29ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m400m40110.1107/S1600536812009750Diaquabis(propane-1,3-diamine)nickel(II) bis(propane-1,3-diamine)disulfatonickelate(II)Julia A. RusanovaThe ionic NiII title complex, [Ni(C3H10N2)2(H2O)2][Ni(SO4)2(C3H10N2)2], is built up of [Ni(dipr)2(H2O)2]2+ complex cations and [Ni(dipr)2(SO4)2]2− complex anions (dipr is propane-1,3-diamine). Both NiII atoms display a slightly distorted octahedral coordination and are located on inversion centers. There are several types of hydrogen-bonding interactions, which connect complex cations and anions into a two-dimensional network parallel to (010). Hydrogen bonds formed by the axially coordinated water molecule of the complex cation and one of the O atoms of the sulfate groups of the complex anion (first type) link them into chains along the c axis. These chains are linked to each other through hydrogen bonds formed by an O atom (second type) of the SO4 groups and NH2 groups of the ligand of the complex cations from neighboring chains, forming a two-dimensional hydrogen-bonded net perpendicular to the b axis. The third type of O atoms of the sulfate groups of the complex anion are also linked into chains by a combination of both previously described types of H-atom connections.http://scripts.iucr.org/cgi-bin/paper?S1600536812009750 |
| spellingShingle | Julia A. Rusanova Diaquabis(propane-1,3-diamine)nickel(II) bis(propane-1,3-diamine)disulfatonickelate(II) Acta Crystallographica Section E |
| title | Diaquabis(propane-1,3-diamine)nickel(II) bis(propane-1,3-diamine)disulfatonickelate(II) |
| title_full | Diaquabis(propane-1,3-diamine)nickel(II) bis(propane-1,3-diamine)disulfatonickelate(II) |
| title_fullStr | Diaquabis(propane-1,3-diamine)nickel(II) bis(propane-1,3-diamine)disulfatonickelate(II) |
| title_full_unstemmed | Diaquabis(propane-1,3-diamine)nickel(II) bis(propane-1,3-diamine)disulfatonickelate(II) |
| title_short | Diaquabis(propane-1,3-diamine)nickel(II) bis(propane-1,3-diamine)disulfatonickelate(II) |
| title_sort | diaquabis propane 1 3 diamine nickel ii bis propane 1 3 diamine disulfatonickelate ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812009750 |
| work_keys_str_mv | AT juliaarusanova diaquabispropane13diaminenickeliibispropane13diaminedisulfatonickelateii |