Crystal structure of silver carbonate iodide Ag10(CO3)3I4
The title silver carbonate iodide, Ag10(CO3)3I4, decasilver(I) tris(carbonate) tetraiodide, was recently reported as a precursor of the new superionic conductor Ag17(CO3)3I11. Ag10(CO3)3I4, was prepared by heating a stoichiometric powder mixture of AgI and Ag2CO3 at 430 K. A single-crystal suitable...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2021-07-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989021006022 |
| _version_ | 1798017981015392256 |
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| author | Ryoji Suzuki Yuta Watanabe Hisanori Yamane Mamoru Kitaura Kento Uchida Yuta Matsushima |
| author_facet | Ryoji Suzuki Yuta Watanabe Hisanori Yamane Mamoru Kitaura Kento Uchida Yuta Matsushima |
| author_sort | Ryoji Suzuki |
| collection | DOAJ |
| description | The title silver carbonate iodide, Ag10(CO3)3I4, decasilver(I) tris(carbonate) tetraiodide, was recently reported as a precursor of the new superionic conductor Ag17(CO3)3I11. Ag10(CO3)3I4, was prepared by heating a stoichiometric powder mixture of AgI and Ag2CO3 at 430 K. A single-crystal suitable for X-ray diffraction analysis was obtained by slow cooling of a melt with an AgI-rich composition down from 453 K. Ag10(CO3)3I4 exhibits a layered crystal structure packed along [10\overline{1}], in which Ag atoms are intercalated between the layers of hexagonally close-packed I atoms, and CO3 groups. Up to now, Cs3Pb2(CO3)3I is the only other compound containing carbonate groups and iodide ions registered in the Inorganic Crystal Structure Database. |
| first_indexed | 2024-04-11T16:16:27Z |
| format | Article |
| id | doaj.art-63ca9894def440238fdeb0730c8ce6c2 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-11T16:16:27Z |
| publishDate | 2021-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-63ca9894def440238fdeb0730c8ce6c22022-12-22T04:14:29ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902021-07-0177773473810.1107/S2056989021006022wm5603Crystal structure of silver carbonate iodide Ag10(CO3)3I4Ryoji Suzuki0Yuta Watanabe1Hisanori Yamane2Mamoru Kitaura3Kento Uchida4Yuta Matsushima5Chemistry and Chemical Engineering, Yamagata University, 4-3-16 Jonan, Yonezawa, 992-8510, JapanChemistry and Chemical Engineering, Yamagata University, 4-3-16 Jonan, Yonezawa, 992-8510, JapanInstitute of Multidisciplinary Research for Advanced Materials, Tohoku, University, 2-1-1 Katahira, Aoba-ku, Sendai, 980- 8577, JapanFaculty of Science, Yamagata University, 1-4-12 Kojirakawa-machi, Yamagata, 990-8560, JapanChemistry and Chemical Engineering, Yamagata University, 4-3-16 Jonan, Yonezawa, 992-8510, JapanChemistry and Chemical Engineering, Yamagata University, 4-3-16 Jonan, Yonezawa, 992-8510, JapanThe title silver carbonate iodide, Ag10(CO3)3I4, decasilver(I) tris(carbonate) tetraiodide, was recently reported as a precursor of the new superionic conductor Ag17(CO3)3I11. Ag10(CO3)3I4, was prepared by heating a stoichiometric powder mixture of AgI and Ag2CO3 at 430 K. A single-crystal suitable for X-ray diffraction analysis was obtained by slow cooling of a melt with an AgI-rich composition down from 453 K. Ag10(CO3)3I4 exhibits a layered crystal structure packed along [10\overline{1}], in which Ag atoms are intercalated between the layers of hexagonally close-packed I atoms, and CO3 groups. Up to now, Cs3Pb2(CO3)3I is the only other compound containing carbonate groups and iodide ions registered in the Inorganic Crystal Structure Database.http://scripts.iucr.org/cgi-bin/paper?S2056989021006022crystal structuresilver carbonate iodidelayered structure |
| spellingShingle | Ryoji Suzuki Yuta Watanabe Hisanori Yamane Mamoru Kitaura Kento Uchida Yuta Matsushima Crystal structure of silver carbonate iodide Ag10(CO3)3I4 Acta Crystallographica Section E: Crystallographic Communications crystal structure silver carbonate iodide layered structure |
| title | Crystal structure of silver carbonate iodide Ag10(CO3)3I4 |
| title_full | Crystal structure of silver carbonate iodide Ag10(CO3)3I4 |
| title_fullStr | Crystal structure of silver carbonate iodide Ag10(CO3)3I4 |
| title_full_unstemmed | Crystal structure of silver carbonate iodide Ag10(CO3)3I4 |
| title_short | Crystal structure of silver carbonate iodide Ag10(CO3)3I4 |
| title_sort | crystal structure of silver carbonate iodide ag10 co3 3i4 |
| topic | crystal structure silver carbonate iodide layered structure |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989021006022 |
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