Experimental study of ceramic coatings on lower-density ceramic substrates

Abstract Adhesion and homogeneity of the coating-substrate were analyzed on the basis of the establishment of coating mineralogy. Substrate raw materials used were kaolin clay and a calcined alumina 4 µm; a series of higher density ceramic coatings were deposited using calcined aluminas 0.5 µm and 4...

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Main Authors: C. I. Torres, C. P. Miquelarena, G. L. Bianchi
Format: Article
Language:English
Published: Associação Brasileira de Cerâmica 2023-07-01
Series:Cerâmica
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132023000200125&lng=en&tlng=en
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author C. I. Torres
C. P. Miquelarena
G. L. Bianchi
author_facet C. I. Torres
C. P. Miquelarena
G. L. Bianchi
author_sort C. I. Torres
collection DOAJ
description Abstract Adhesion and homogeneity of the coating-substrate were analyzed on the basis of the establishment of coating mineralogy. Substrate raw materials used were kaolin clay and a calcined alumina 4 µm; a series of higher density ceramic coatings were deposited using calcined aluminas 0.5 µm and 4 µm, silica fume, and talc. The dip coating technique was applied to all substrates and later sintered at 1300 ºC. Shrinkage and density of coatings mixtures and substrate were separately evaluated. X-ray diffraction was utilized to identify the crystalline phases present in the coatings, while optical and electron microscopy were employed for the structural characterization of the coatings. Coatings exhibited lower shrinkage compared to the substrate. Among the specimens that exhibited good adhesion, cracks were observed to extend parallel to the substrate surface. The presence of cristobalite on the coating indicated that the failure mechanism involved buckling. The crack dimension presented on the coating decreased after adding talc to the mixture.
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spelling doaj.art-63ccb7ed4b364a329e23a5bc8da1dbdc2023-07-18T07:41:51ZengAssociação Brasileira de CerâmicaCerâmica1678-45532023-07-016939012513210.1590/0366-69132023693903375Experimental study of ceramic coatings on lower-density ceramic substratesC. I. Torreshttps://orcid.org/0000-0003-1227-9478C. P. MiquelarenaG. L. BianchiAbstract Adhesion and homogeneity of the coating-substrate were analyzed on the basis of the establishment of coating mineralogy. Substrate raw materials used were kaolin clay and a calcined alumina 4 µm; a series of higher density ceramic coatings were deposited using calcined aluminas 0.5 µm and 4 µm, silica fume, and talc. The dip coating technique was applied to all substrates and later sintered at 1300 ºC. Shrinkage and density of coatings mixtures and substrate were separately evaluated. X-ray diffraction was utilized to identify the crystalline phases present in the coatings, while optical and electron microscopy were employed for the structural characterization of the coatings. Coatings exhibited lower shrinkage compared to the substrate. Among the specimens that exhibited good adhesion, cracks were observed to extend parallel to the substrate surface. The presence of cristobalite on the coating indicated that the failure mechanism involved buckling. The crack dimension presented on the coating decreased after adding talc to the mixture.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132023000200125&lng=en&tlng=enAl2O3-SiO2-MgOdip coatingclay substratesintering effortbrittle fracture
spellingShingle C. I. Torres
C. P. Miquelarena
G. L. Bianchi
Experimental study of ceramic coatings on lower-density ceramic substrates
Cerâmica
Al2O3-SiO2-MgO
dip coating
clay substrate
sintering effort
brittle fracture
title Experimental study of ceramic coatings on lower-density ceramic substrates
title_full Experimental study of ceramic coatings on lower-density ceramic substrates
title_fullStr Experimental study of ceramic coatings on lower-density ceramic substrates
title_full_unstemmed Experimental study of ceramic coatings on lower-density ceramic substrates
title_short Experimental study of ceramic coatings on lower-density ceramic substrates
title_sort experimental study of ceramic coatings on lower density ceramic substrates
topic Al2O3-SiO2-MgO
dip coating
clay substrate
sintering effort
brittle fracture
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132023000200125&lng=en&tlng=en
work_keys_str_mv AT citorres experimentalstudyofceramiccoatingsonlowerdensityceramicsubstrates
AT cpmiquelarena experimentalstudyofceramiccoatingsonlowerdensityceramicsubstrates
AT glbianchi experimentalstudyofceramiccoatingsonlowerdensityceramicsubstrates